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Received December 16, 2015
Accepted October 2, 2016
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Study of UV aging on the performance characteristics of vegetable oil and palm oil derived isocyanate based polyurethane
Laboratory for Advanced Research in Polymeric Materials, Central Institute of Plastics Engineering and Technology, Bhubaneswar, Odisha-751024, India
das.sonalee31@gmail.com
Korean Journal of Chemical Engineering, February 2017, 34(2), 523-538(16), 10.1007/s11814-016-0273-5
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Abstract
The impact of UV aging on the characteristic properties of synthesized polyurethane (PUs) from castor oil and transesterified castor oil with palm oil based isocyanate and 1,4 butanediol was investigated at different exposure time of 0, 250, 500, 750 and 1,000 h, respectively. The aging properties of the PU films were analyzed through differential scanning calorimetry (DSC), Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), Scanning electron microscopy (SEM) and Tensile tests. The PU films derived from castor oil showed noticeable changes in chemical structure after 250 h of UV exposure owing to chain scission of the urethane group. A considerable decrease in the thermal and tensile properties of the developed PU films was observed due to the plasticization phenomenon. SEM micrographs revealed morphological changes through the appearance of cracks and blisters composed of primary amines on the surface of exposed PU films. However, PUs derived from transesterified castor oil with a higher hydroxyl value exhibited improved UV resistance characteristics due to higher crosslinking and degrade only after 750 h of exposure. Thus, the synthesized green PUs based on transesterified castor oil with palm oil based isocyanate compositions can be candidate materials for developing UV resistant coating material.
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Azevedo EC, Nascimento EM, Chierice GO, Neto SC, Lepienski CM, Polimery, 23, 305 (2013)
Rosu D, Rosu L, Cascaval CN, Polym. Degrad. Stabil., 94, 591 (2009)
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Zhang Y, Mexted J, Barber A, Lowe C, Smith R, Polym. Degrad. Stabil., 98, 527 (2013)
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Owens DK, Wendt RC, J. Appl. Polym. Sci., 13, 1741 (1969)
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Somani K, Kansara S, Parmar R, Patel N, Int. J. Polym. Mater., 53, 282 (2004)
Valero M, Pulido J, Ramirez A, Zhendong Z, J. Am. Oil Chem. Soc., 86, 383 (2009)
Kaushik A, Singh P, Int. J. Polym. Anal. Charact., 10, 373 (2005)
Valero MF, Pulido JE, Ramirez A, Cheng Z, Qimica Nova., 31, 2076 (2008)
Gurunathanan T, Mohanty S, Nayak SK, POC, 80, 39 (2015)
de Luca MA, Martinelli M, Jacobi MM, Becker PL, Ferrao MF, J. Am. Oil Chem. Soc., 83, 147 (2006)
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Lligadas G, Ronda JC, Galia M, Cadiz V, Biomacromolecules, 8(2), 686 (2007)
Yang XF, Vang C, Tallman DE, Bierwagen GP, Croll SG, Rohlik S, Polym. Degrad. Stabil., 74, 341 (2001)
Jana RN, Bhunia H, High Perform. Polym., 22, 3 (2010)
Romanova V, Begishev V, Karmanov V, Kondyurin A, Maitz MF, J. Raman Spectrosc., 33, 769 (2002)
Wilhelm C, Gardette JL, Polymer, 39(24), 5973 (1998)
Claude B, Gonon L, Verney V, Gardette JL, Polym. Test, 20, 771 (2011)
Irusta L, Fernandez-Berridi MJ, Polym. Degrad. Stabil., 63, 113 (1999)
Kim H, Urban MW, Langmuir, 16(12), 5382 (2000)
Das G, Trivedi RK, Vasishtha AK, JAOCS, 66, 938 (1989)
Zlatanic A, Lava C, Zhang W, Petrovic ZS, J. Polym. Sci. B: Polym. Phys., 42(5), 809 (2004)
Harris DJ, Assink RA, Celina M, Macromolecules, 34(19), 6695 (2001)
Wong CS, Badri KH, Mater. Sci. Appl., 3, 78 (2012)
Yuhan L, Yuxi L, Shazou L, Huifeng T, J. Wuhan University of Technology-Mater. Sci. Ed., 29, 1270 (2014)
Wang ZY, Liu FC, Han EH, Wie KE, SuZhen L, Chin. Sci. Bull., 54, 3464 (2009)
Deslandes Y, Pleizier G, Alexander D, Santerre P, Polymer, 39(11), 2361 (1998)
Gulmine JV, Akcelrud L, Eur. Polym. J., 42, 553 (2006)
Cascaval CN, Ciobanu C, Rosu D, Rosu L, J. Appl. Polym. Sci., 83(1), 138 (2002)
Yang XF, Lib J, Croll SG, Tallman DE, Bierwagen GP, Polym. Degrad. Stabil., 80, 51 (2003)
Lemaire J, Arnaud R, Gardette J, Pure Appl. Chem., 55, 1603 (1983)
Wicks ZW, Jones FN, Pappas SP, Organic coatings science and technology, 2nd Ed., Wiley New Jersey (1994).
Prisacariu C, Polyurethane Elastomers: From Morphology to Mechanical Aspects, Springer Science & Business Media, New York (2011).
Tidjani A, J. Appl. Polym. Sci., 64(13), 2497 (1997)
Boubakri A, Haddar N, Elleuch K, Bienvenu Y, Mater. Des., 31, 4194 (2010)
Foulc MP, Bergeret A, Ferry L, Ienny P, Crespy A, Polym. Degrad. Stabil., 89, 461 (2005)
Ghermezcheshme H, Mohseni M, Yahyaei H, Tribol. Int., 88, 66 (2015)
Yahyaei H, Mohseni M, Tribol. Int., 57, 147 (2013)
Wypych G, Handbook of material weathering, ChemTec Publishing, Toronto (1995).
Signor AW, VanLandingham MR, Chin JW, Polym. Degrad. Stabil., 79, 359 (2003)
Skaja A, Fernando D, Croll S, JCT Res., 3, 41 (2006)
Wanga HH, Mou J, Ni YH, Fei GQ, Si CL, Zou J, Express. Polym. Lett., 7, 443 (2013)
Kuang P, Constant K, Increased Wettability and Surface Free Energy of Polyurethane by Ultraviolet Ozone Treatment, In Tech Publishing, US (2015).
Nuraje N, Khan SI, Misak H, Asmatulu R, ISRN Polym. Sci., DOI:10.1155/2013/514617., 8 (2013)
Rabea AM, Mohseni M, Mirabedini SM, Tabatabaei MH, Appl. Surf. Sci., 258(10), 4391 (2012)
