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Received August 26, 2016
Accepted November 29, 2016
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Preparation of Cu-MgO catalysts with different copper precursors and precipitating agents for the vapor-phase hydrogenation of furfural
1Gas Conversion Department, Faculty of Petrochemicals, Iran Polymer and Petrochemical Institute, P. O. Box 14975-112, Tehran, Iran 2Biomass Conversion Science and Technology (BCST) Division, Iran Polymer and Petrochemical Institute, P. O. Box 14975-115, Tehran, Iran 3Faculty of Petrochemicals, Iran Polymer and Petrochemical Institute, P. O. Box 14975-112, Tehran, Iran
m.ghashghaee@ippi.ac.ir, ghashghaee.m@gmail.com
Korean Journal of Chemical Engineering, March 2017, 34(3), 692-700(9), 10.1007/s11814-016-0344-7
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Abstract
This article presents the effects of three copper precursors and four precipitating agents on the catalytic performance of the corresponding co-precipitated Cu-MgO catalysts in the vapor-phase hydrogenation of furfural. The chemical and physical properties were analyzed by means of XRD, BET, SEM, and EDX techniques. The nitrate precursor provided the highest performance (conversion of ~89%). Whereas, the catalyst prepared with NaOH was the most efficient (furfuryl alcohol yield of >90%) during 240min; the most durable conversion (~95%) was assured with Na2-CO3, and the highest selectivity to furfuryl alcohol (>97%) was achieved with K2CO3 as the precipitating agent. The least efficient catalyst (prepared with ammonium carbonate) led to 5-methylfurfural and 2,2-methylenebisfuran as the main byproducts. The major byproducts over the rest of the catalysts included tetrahydrofurfuryl alcohol, furfuryl ether, 1-pentanol, and 2-methylfuran. An increasing trend of furfuryl alcohol selectivity with time-on-stream was evident for all of the catalysts.
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Liu H, Hu Q, Fan G, Yang L, Li F, Catal. Sci. Technol., 5(8), 3960 (2015)
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Pachamuthu MP, Srinivasan VV, Maheswari R, Shanthi K, Ramanathan A, Catal. Sci. Technol., 3(12), 3335 (2013)
Jensen JR, Johannessen T, Livbjerg H, Appl. Catal. A: Gen., 266(1), 117 (2004)
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Zhang HB, Canlas C, Kropf AJ, Elam JW, Dumesic JA, Marshall CL, J. Catal., 326, 172 (2015)
