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Received July 22, 2016
Accepted November 10, 2016
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A new approach for modeling of multicomponent gas hydrate formation
Gas Engineering Department, Petroleum University of Technology, Iran 1Chemical Engineering Department, Amirkabir University of Technology, Iran
mohebbi@put.ac.ir
Korean Journal of Chemical Engineering, March 2017, 34(3), 706-716(11), 10.1007/s11814-016-0318-9
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Abstract
Several models have been proposed to investigate the kinetics of gas hydrate formation. The main differences between the proposed models are the definition of the driving force, thermodynamics approach and the number of resistances to study the gas consumption by the hydrate phase. This paper concentrates on gas hydrate formation from multicomponent mixture, which has not been much studied before. In the present research, chemical potential has been considered as the driving force and, consequently, a new resistance coefficient was introduced. A complete discussion and reasonable assumptions has been provided to support this modelling.
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Skovborg P, Rasmussen P, Chem. Eng. Sci., 49(8), 1131 (1994)
Kashchiev D, Firoozabadi A, J. Cryst. Growth, 241(1-2), 220 (2002)
Ribeiro CP, Lage PLC, Chem. Eng. Sci., 63(8), 2007 (2008)
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Lee S, Zhang J, Mehta R, Woo T, Lee W, J. Phys. Chem., 111, 4734 (2007)
Chun MK, Lee H, Korean J. Chem. Eng., 13(6), 620 (1996)
Malegaonkar MB, Dholabhai PD, Bishnoi PR, Can. J. Chem. Eng., 75(6), 1090 (1997)
Bergeron S, Servio P, Fluid Phase Equilib., 265(1-2), 30 (2008)
Bergeron S, Beltran JG, Servio P, Fuel, 89(2), 294 (2010)
Zhang J, Lee JW, Ind. Eng. Chem. Res., 48, 5934 (2008)
Naseh M, Mohebbi V, Behbahani RM, J. Chem. Eng. Data, 59(11), 3710 (2014)
Bergeron S, Servio P, Fluid Phase Equilib., 276(2), 150 (2009)
Najafi M, Mohebbi V, J. Nat. Gas Sci. Eng., 21, 738 (2014)
Izadpand A, Vafaie M, Varaminian F, Iran. J. Chem. Chem. Eng., 26, 61 (2007)
Peng B, J. Phys. Chem., 111, 12485 (2007)
Babaee S, Hashemi H, Mohammadi AH, Naidoo P, Ramjugernath D, J. Chem. Thermodyn., 81, 52 (2015)
Hashemi H, Babaee S, Mohammadi AH, Naidoo P, Ramjugernath D, J. Chem. Thermodyn., 82, 47 (2015)
Christiansen R, Sloan ED, Gas Processors Association, Tulsa (1995).
Mohebbi V, Naderifar A, Behbahani RM, Moshfeghian M, J. Chem. Thermodyn., 51, 8 (2012)
Soave G, Chem. Eng. Sci., 27, 1197 (1972)
Danesh A, PVT and phase behavior of petroleum reservoir fluids, Elsevier (1998).
Mohebbi V, Behbahani R, J. Nat. Gas Sci. Eng., 18, 47 (2014)
Treybal RE, Mass transfer operations, McGraw Hill (1980).
Fogler HS, Elements of chemical reaction engineering, Prentice Hall (1999).
Parrish WR, Prausnitz JM, Ind. Eng. Chem. Process Des. Dev., 11, 26 (1972)
Gas Processors and Suppliers Association Engineering Data Book, Tulsa, Oklahoma, U.S.A. (2004).
Munck J, Skjold-Jorgensen S, Rasmussen P, Chem. Eng. Sci., 43, 2661 (1988)
