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Received June 20, 2016
Accepted November 20, 2016
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Efficient oxidative removal of 4-tert-octylphenol and 17α-ethynylestradiol from aqueous solutions using ferrate(VI)
Department of Chemistry, School of Physical Sciences, Mizoram University, Aizawl-796004, India 1Department of Environmental Engineering, Kwangwoon University, Seoul 01897, Korea 2Department of Health and the Environment, Catholic Kwandong University, 522 Naegok-dong, Gangneung, Gangwondo 25601, Korea
leesm@cku.ac.kr
Korean Journal of Chemical Engineering, March 2017, 34(3), 734-740(7), 10.1007/s11814-016-0324-y
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Abstract
Ferrate(VI) was utilized to treat micro-pollutants--4-tert-octylphenol (TOP) and 17α ethynylestradiol (EE2)--from aqueous solutions. Batch studies were conducted at various pHs (7.0 to 12.0) and concentrations of TOP/or EE2 (0.03 to 0.3mmol/L) using 0.1mmol/L ferrate(VI). Time-dependent degradation of TOP and EE2 was assessed as a function of pH and micro-pollutant concentrations and we found that significant mineralization of micro-pollutants was achieved by ferrate(VI) treatment. Second-order kinetics showed 1 : 1 stoichiometry was obtained between the ferrate(VI) and TOP/or EE2. Further, the effect of several background electrolytes on degradation of TOP and EE2 by ferrate(VI) was evaluated, showing insignificant effect of degradation.
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References
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Snyder SA, Westerhoff P, Yoon Y, Sedlak DL, Environ. Eng. Sci., 20, 449 (2003)
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Nowotny N, Epp B, von Sonntag C, Fahlenkamp H, Environ. Sci. Technol., 41, 2050 (2007)
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Yang B, Ying GG, Zhao JL, Liu S, Zhou LJ, Chen F, Water Res., 46, 2194 (2012)
Aoki M, Kurasaki M, Saito T, Seki S, Hosokawa T, Takahashi Y, Fujita H, Iwakura T, Life Sci., 741, 2301 (2004)
Hawrelak M, Bennett E, Metcalfe C, Chemosphere, 39, 745 (1999)
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White R, Jobling S, Hoare SA, Sumpter JP, Parker MG, Endocrinology, 135, 175 (1994)
Kwak HI, Bae MO, Lee MH, Lee YS, Lee BJ, Kang KS, Chae CH, Sung HJ, Shin JS, Kim JH, Mar WC, Sheen YY, Cho MH, Environ. Toxicol. Chem., 20, 787 (2001)
Lech JJ, Lewis SK, Ren L, Fundamental Appl. Toxicol., 30, 229 (1996)
Yang X, Liu M, Wang Z, Li Q, Zhang Z, J. Environ. Sci., 25, 1712 (2013)
Zhou JL, Environ. Sci. Technol., 40, 2225 (2006)
Ferreira-Leach AMR, Hill EM, Marine Environ. Res., 51, 75 (2001)
Gadzala-Kopciuch R, Filipiak A, Buszewski B, Talanta, 74, 655 (2008)
Snyder SA, Keith TL, Verbrugge DA, Snyder EM, Gross TS, Kannan K, Giesy JP, Environ. Sci. Technol., 33, 2814 (1999)
Li C, Li XZ, Graham N, Gao NY, Water Res., 42, 109 (2008)
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Tiwari D, Yang JK, Lee SM, Env. Eng. Res., 10, 269 (2005)
Pachuau L, Lee SM, Tiwari D, Chem. Eng. J., 230, 141 (2013)
Jiang JQ, J. Hazard. Mater., 146(3), 617 (2007)
Sharma VK, Adv. Environ. Res., 6, 143 (2002)
Graham N, Jiang CC, Li XZ, Jiang JQ, Ma J, Chemosphere, 56, 949 (2004)
Tiwari D, Sailo L, Pachuau L, Sep. Purif. Technol., 132, 77 (2014)
Jiang JQ, J. Hazard. Mater., 146(3), 617 (2007)
Tiwari D, Kim HU, Choi BJ, Lee SM, Kwon OH, Choi KM, Yang JK, J. Environ. Sci. Health Part A-Toxic/Hazard. Subst. Environ. Eng., 42, 803 (2007)
Lee YH, Yoon J, Gunten UV, Environ. Sci. Technol., 39, 8978 (2005)
Jiang JQ, Yin Q, Zhou JL, Pearce P, Chemosphere, 61, 544 (2005)
Tiwari D, Lalhriatpuia C, Lee SM, J. Ind. Eng. Chem., 30, 167 (2015)
Li C, Li XZ, Graham N, Gao NY, Water Res., 42, 109 (2008)
Zhang PY, Zhang GM, Dong JH, Fan MH, Zeng GM, Sep. Purif. Technol., 84, 46 (2012)
Sharma VK, Mishra SK, Ray AK, Chemosphere, 62, 128 (2006)
Sharma VK, Ill GWL, Millero FJ, Chemosphere, 82, 1083 (2011)
Anquandah GAK, Sharma VK, Panditi VR, Gardinali PR, Kim H, Oturan MA, Chemosphere, 91, 105 (2013)
Yang B, Ying GG, Zhang LJ, Zhou LJ, Liu S, Fang YX, Water Res., 45, 2261 (2011)
Jiang JQ, Zhou ZW, Pahl O, Sep. Purif. Technol., 88, 95 (2012)
Zhang ZH, Feng YJ, Liu Y, Sun QF, Gao P, Ren NQ, J. Hazard. Mater., 181(1-3), 1127 (2010)
Environment Agency UK: Environmental Risk Evaluation Report:4-tert-octylphenol (2005).
MITI-List: Biodegradation and Bioaccumulation of Existing Chemical Substances under the Chemical Substance Control Law. National Institute of Technology and Evaluation, Japan (2002).
Garcia-Araya JF, Beltran FJ, Aguinaco A, J. Chem. Technol. Biotechnol., 85(6), 798 (2010)
Sharma VK, Zboril R, Varma RS, Acc. Chem. Res., 48, 182 (2015)
Sharma VK, Chen L, Zboril R, ACS Sustain. Chem. Eng., 4, 18 (2016)
Rush JD, Zhao Z, Bielski BHJ, Free Rad. Res., 24, 187 (1996)
Ohta T, Kamachi T, Shiota Y, Yoshizawa K, J. Org. Chem., 66, 4122 (2001)
Sharma VK, O’Connor DB, Cabelli D, Inorg. Chim. Acta., 357, 4587 (2004)
Sharma VK, Mishra SK, Nesnas N, Environ. Sci. Technol., 40, 7222 (2006)
Kamachi T, Nakayama N, Yoshizawa K, Bull. Chem. Soc. Jpn., 81, 1212 (2008)
Noorhasan N, Patel B, Sharma VK, Water Res., 44, 927 (2010)
Yang J, Tiwari D, Yu M, Pachuau L, Kim W, Lee S, Environ. Technol., 31, 791 (2010)