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Received September 9, 2016
Accepted November 1, 2016
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Quantitative analysis of carbon nanotube cross-linking reactions
Department of Chemical Engineering, Pohang University of Science and Technology, 77, Cheongam-ro, Nam-gu, Pohang, Gyeongsangbuk-do 37673, Korea 1Department of Organic Materials & Fiber Engineering, Chonbuk National University, 567 Baekje-daero, Deokjin-gu, Jeonju-si, Jellabuk-do 54896, Korea 2Carbon Convergence Materials Research Center, Korea Institute of Science and Technology, 92, Chudong-ro, Bongdong-eup, Wanju-gun, Jeollabuk-do 55324, Korea
Korean Journal of Chemical Engineering, March 2017, 34(3), 898-902(5), 10.1007/s11814-016-0309-x
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Abstract
Covalent cross-linking of carbon nanotubes (CNTs) is a useful way of transferring the unique properties of individual CNTs to macroscopic structures for a wide variety of applications. For elaborate engineering of the crosslinking reaction of CNTs, quantitative analysis of cross-linking reaction is imperative. We report here a universally applicable method to quantitatively analyze the cross-linking of CNTs by esterification. To distinguish the cross-linking reaction from the one-side reaction, where only one end of the linker reacts with a CNT, mass and molar balances were established based on thermogravimetric analysis data. This analysis revealed that approximately one in five linkers was involved in the cross-linking reaction. Qualitative characterizations such as Fourier transform infrared and Raman spectroscopy were also used to confirm the cross-linking reaction.
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