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In relation to this article, we declare that there is no conflict of interest.
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Received July 1, 2016
Accepted November 29, 2016
articles This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Cycloaddition of carbon dioxide with propylene oxide using zeolitic imidazolate framework ZIF-23 as a catalyst

School of Chemical and Biomolecular Engineering, Pusan National University, Busan 46241, Korea 1Korea Research Institute of Chemical Technology, Ulsan 44412, Korea 2Nanotechnology and Catalysis Research Center, University of Malaya, Kuala Lumpur 50603, Malaysia
dwpark@pusan.ac.kr
Korean Journal of Chemical Engineering, March 2017, 34(3), 928-934(7), 10.1007/s11814-016-0339-4
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Abstract

Zeolitic imidazolate framework ZIF-23 was prepared and used as catalyst for the solventless synthesis of cyclic carbonate from CO2 and propylene oxide with or without TBAB co-catalyst. ZIF-23 catalysts were prepared by a solvothermal or microwave method and they were characterized by various physicochemical techniques such as XRD, FT-IR, BET, TGA, and FE-SEM. The effects of reaction parameters such as temperature, reaction time, CO2 pressure, and co-catalyst on the reactivity of catalyst were investigated. ZIF-23 was recyclable up to four times without any considerable loss of its initial activity. Reaction mechanism containing the role of ZIF-23 with TBAB co-catalyst was also proposed.

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