Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received November 20, 2016
Accepted February 6, 2017
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
CO2/O2-oxidative dehydrogenation of ethane to ethylene over highly dispersed vanadium oxide on MgO-promoted sulfated-zirconia nanocatalyst: Effect of sulfation on catalytic properties and performance
1Chemical Engineering Faculty, Sahand University of Technology, P. O. Box 51335-1996, Sahand New Town, Tabriz, Iran 2Reactor and Catalysis Research Center (RCRC), Sahand University of Technology, P. O. Box 51335-1996, Sahand New Town, Tabriz, Iran
haghighi@sut.ac.ir
Korean Journal of Chemical Engineering, May 2017, 34(5), 1346-1357(12), 10.1007/s11814-017-0026-0
Download PDF
Abstract
The ZrO2 was treated by various molarities of H2SO4 solution (0, 0.5, 1 and 2) then mixed by MgO and impregnated with 5 wt% of V2O5. The synthesized catalysts were characterized by XRD, FESEM, PSD, EDX, BET and FTIR techniques. According to the results obtained by characterization studies, the modification of MgO-ZrO2 support by various molarities of H2SO4 solution had a great impact on the crystallinity, morphology and functional groups of prepared nanocatalysts. On the other hand, the catalytic activity of synthesized nanocatalysts in the oxidative dehydrogenation of ethane to ethylene is affected by the sulfur content on the support. The crystalline structures of MgO and ZrO2 were confirmed by XRD analysis. The crystallinity of tetragonal ZrO2 was decreased by increasing H2SO4 molarity used in ZrO2 (Sx) synthesising. The highest catalytic performance and ethylene productivity (C2H4 yield of 48% and ethane conversion of 79% at 700 °C) were obtained on the V2O5/MgO-ZrO2 (S1) nanocatalyst. This could be related to the superior acid-base property, smaller particles, better dispersion of active phase and uniform morphology of V2O5/MgO-ZrO2 (S1).
References
Zhu HB, Dong HL, Laveille P, Saih Y, Caps V, Basset JM, Catal. Today, 228, 58 (2014)
Yu F, Wu X, Zhang Q, Wang Y, Chin. J. Catal., 35, 1260 (2014)
Bortolozzi JP, Weiss T, Gutierrez LB, Ulla MA, Chem. Eng. J., 246, 343 (2014)
Talati A, Haghighi M, Rahmani F, RSC Adv., 6, 44195 (2016)
Rahmani F, Haghighi M, Amini M, J. Ind. Eng. Chem., 31, 142 (2015)
Rahmani F, Haghighi M, Korean J. Chem. Eng., 33(9), 2555 (2016)
Rahmani F, Haghighi M, J. Natural Gas Sci. Eng., 27(Part 3), 1684 (2015)
Nezhad PDK, Haghighi M, Jodeiri N, Rahmani F, J. Sol-Gel Sci. Technol., 80, 436 (2016)
Asghari E, Haghighi M, Rahmani F, J. Mol. Catal. A-Chem., 418-419, 115 (2016)
Shylesh S, Singh AP, J. Catal., 233(2), 359 (2005)
Kondratenko EV, Ovsitser O, Radnik J, Schneider M, Kraehnert R, Dingerdissen U, Appl. Catal. A: Gen., 319, 98 (2007)
Sokolov S, Stoyanova M, Rodemerck U, Linke D, Kondratenko EV, J. Catal., 293, 67 (2012)
Zhang Z, Han L, Chai R, Zhang Q, Li Y, Zhao G, Liu Y, Lu Y, Catal. Commun., 88, 90 (2017)
Casaletto MP, Lisi L, Mattogno G, Patrono P, Ruoppolo G, Russo G, Appl. Catal. A: Gen., 226(1-2), 41 (2002)
Ciambelli P, Galli P, Lisi L, Massucci MA, Patrono P, Pirone R, Ruoppolo G, Russo G, Appl. Catal. A: Gen., 203(1), 133 (2000)
Gounder R, Iglesia E, J. Catal., 277(1), 36 (2011)
Casaletto MP, Lisi L, Mattogno G, Patrono P, Ruoppolo G, Appl. Catal. A: Gen., 267(1-2), 157 (2004)
Tanimu G, Jermy BR, Asaoka S, Al-Khattaf S, J. Ind. Eng. Chem., 45, 111 (2017)
Elbadawi AH, Ba-Shammakh MS, Al-Ghamdi S, Razzak SA, Hossain MM, de Lasa HI, Chem. Eng. Res. Des., 117, 733 (2017)
Camacho-Bunquin J, Aich P, Ferrandon M, Getsoian A, Das U, Dogan F, Curtiss LA, Miller JT, Marshall CL, Hock AS, Stair PC, J. Catal., 345, 170 (2017)
Khoshbin R, Haghighi M, Catal. Sci. Technol., 4, 1779 (2014)
Piumetti M, Bonelli B, Armandi M, Gaberova L, Casale S, Massiani P, Garrone E, Microporous Mesoporous Mater., 133, 36 (2010)
Rossetti I, Fabbrini L, Ballarini N, Oliva C, Cavani F, Cericola A, Bonelli B, Piumetti M, Garrone E, Dyrbeck H, Blekkan EA, Forni L, J. Catal., 256(1), 45 (2008)
Nieto JML, Coenraads R, Dejoz A, Vazquez MI, Grasselli STOAMGRK, Lyons JE, The role of metal oxides as promoters of V2O5/I3-Al2O3 catalysts in the oxidative dehydrogenation of propane. In Studies in Surface Science and Catalysis, Elsevier, 110, 443 (1997).
Demirci UB, Garin F, J. Mol. Catal. A-Chem., 188(1-2), 233 (2002)
Fofrcaiu D, Li JQ, Kogelbauer A, J. Mol. Catal. A-Chem., 124, 67 (1997)
Lee H, Lee JK, Hong UG, Yoo Y, Cho YJ, Lee J, Jang HS, Jung JC, Song IK, J. Ind. Eng. Chem., 18(2), 808 (2012)
Chen G, Guo CY, Qiao H, Ye M, Qiu X, Yue C, Catal. Commun., 41, 70 (2013)
Bensitel M, Saur O, Lavalley JC, Morrow BA, Mater. Chem. Phys., 19, 147 (1988)
Corma A, Fornes V, Juanrajadell MI, Nieto JM, Appl. Catal. A: Gen., 116(1-2), 151 (1994)
Arata K, Hino M, Appl. Catal., 59, 197 (1990)
Arata K, Matsuhashi H, Hino M, Nakamura H, Catal. Today, 81(1), 17 (2003)
Morterra C, Cerrato G, Pinna F, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 55, 95 (1998)
Martra G, Arena F, Coluccia S, Frusteri F, Parmaliana A, Catal. Today, 63(2-4), 197 (2000)
Deshmane VG, Adewuyi YG, Fuel, 107, 474 (2013)
Tanabe K, Yamaguchi T, Inui T, Design of Sulfur-Promoted Solid Superacid Catalyst, In Studies in Surface Science and Catalysis, Elsevier, 44, 99 (1989).
Corma A, Chem. Rev., 95(3), 559 (1995)
Wachs IE, Jehng JM, Deo G, Weckhuysen BM, Guliants VV, Benziger JB, Sundaresan S, J. Catal., 170(1), 75 (1997)
Le Bars J, Vedrine JC, Auroux A, Trautmann S, Baerns M, Appl. Catal. A: Gen., 88, 179 (1992)
Blasco T, Galli A, Nieto JM, Trifiro F, J. Catal., 169(1), 203 (1997)
Dhak D, Pramanik P, J. Am. Ceram. Soc., 89(3), 1014 (2006)
Rahmani F, Haghighi M, Vafaeian Y, Estifaee P, J. Power Sources, 272, 816 (2014)
Talkhoncheh SK, Haghighi M, J. Natural Gas Sci. Eng., 23, 16 (2015)
Aghamohammadi S, Haghighi M, Chem. Eng. J., 264, 359 (2015)
Aghaei E, Haghighi M, Powder Technol., 269, 358 (2015)
Lisi L, Marchese L, Pastore HO, Frache A, Ruoppolo G, Russo G, Topics in Catalysis, 22, 95 (2003)
Marchese L, Frache A, Gatti G, Coluccia S, Lisi L, Ruoppolo G, Russo G, Pastore HO, J. Catal., 208(2), 479 (2002)
Goula MA, Lemonidou AA, Efstathiou AM, J. Catal., 161(2), 626 (1996)
Yadav GD, Nair JJ, Microporous Mesoporous Mater., 33, 1 (1999)
Saravanan K, Tyagi B, Bajaj HC, Catal. Sci. Technol., 2, 2512 (2012)
Ejtemaei M, Tavakoli A, Charchi N, Bayati B, Babaluo AA, Bayat Y, Adv. Powder Technol., 25(3), 840 (2014)
Talati A, Haghighi M, Rahmani F, Adv. Powder Technol., 27(4), 1195 (2016)
Rahmani F, Haghighi M, Mahboob S, Ultrason. Sonochem., 33, 150 (2016)
Rahmani F, Haghighi M, RSC Adv., 6, 89551 (2016)
Banares MA, Catal. Today, 51(2), 319 (1999)
Busca G, Finocchio E, Ramis G, Ricchiardi G, Catal. Today, 32(1-4), 133 (1996)
Sun G, Huang Q, Huang S, Wang Q, Li H, Liu H, Wan S, Zhang X, Wang J, Catalysts, 6, 1 (2016)
Fu H, Liu ZP, Li ZH, Wang WN, Fan KN, J. Am. Chem. Soc., 128(34), 11114 (2006)
Chen KD, Iglesia E, Bell AT, J. Catal., 192(1), 197 (2000)
Kutzelnigg W, Atoms in Molecules. A Quantum Theory. (Reihe:International Series of Monographs on Chemistry, Vol. 22.) Von R.F.W. Bader. Clarendon Press, Oxford, 1990. XVIII, 438 S., geb. ￡ 50.00. - ISBN 0-19-855168-1. WILEY-VCH Verlag GmbH, 22, 104 (1992).
Yu F, Wu X, Zhang Q, Wang Y, Chin. J. Catal., 35, 1260 (2014)
Bortolozzi JP, Weiss T, Gutierrez LB, Ulla MA, Chem. Eng. J., 246, 343 (2014)
Talati A, Haghighi M, Rahmani F, RSC Adv., 6, 44195 (2016)
Rahmani F, Haghighi M, Amini M, J. Ind. Eng. Chem., 31, 142 (2015)
Rahmani F, Haghighi M, Korean J. Chem. Eng., 33(9), 2555 (2016)
Rahmani F, Haghighi M, J. Natural Gas Sci. Eng., 27(Part 3), 1684 (2015)
Nezhad PDK, Haghighi M, Jodeiri N, Rahmani F, J. Sol-Gel Sci. Technol., 80, 436 (2016)
Asghari E, Haghighi M, Rahmani F, J. Mol. Catal. A-Chem., 418-419, 115 (2016)
Shylesh S, Singh AP, J. Catal., 233(2), 359 (2005)
Kondratenko EV, Ovsitser O, Radnik J, Schneider M, Kraehnert R, Dingerdissen U, Appl. Catal. A: Gen., 319, 98 (2007)
Sokolov S, Stoyanova M, Rodemerck U, Linke D, Kondratenko EV, J. Catal., 293, 67 (2012)
Zhang Z, Han L, Chai R, Zhang Q, Li Y, Zhao G, Liu Y, Lu Y, Catal. Commun., 88, 90 (2017)
Casaletto MP, Lisi L, Mattogno G, Patrono P, Ruoppolo G, Russo G, Appl. Catal. A: Gen., 226(1-2), 41 (2002)
Ciambelli P, Galli P, Lisi L, Massucci MA, Patrono P, Pirone R, Ruoppolo G, Russo G, Appl. Catal. A: Gen., 203(1), 133 (2000)
Gounder R, Iglesia E, J. Catal., 277(1), 36 (2011)
Casaletto MP, Lisi L, Mattogno G, Patrono P, Ruoppolo G, Appl. Catal. A: Gen., 267(1-2), 157 (2004)
Tanimu G, Jermy BR, Asaoka S, Al-Khattaf S, J. Ind. Eng. Chem., 45, 111 (2017)
Elbadawi AH, Ba-Shammakh MS, Al-Ghamdi S, Razzak SA, Hossain MM, de Lasa HI, Chem. Eng. Res. Des., 117, 733 (2017)
Camacho-Bunquin J, Aich P, Ferrandon M, Getsoian A, Das U, Dogan F, Curtiss LA, Miller JT, Marshall CL, Hock AS, Stair PC, J. Catal., 345, 170 (2017)
Khoshbin R, Haghighi M, Catal. Sci. Technol., 4, 1779 (2014)
Piumetti M, Bonelli B, Armandi M, Gaberova L, Casale S, Massiani P, Garrone E, Microporous Mesoporous Mater., 133, 36 (2010)
Rossetti I, Fabbrini L, Ballarini N, Oliva C, Cavani F, Cericola A, Bonelli B, Piumetti M, Garrone E, Dyrbeck H, Blekkan EA, Forni L, J. Catal., 256(1), 45 (2008)
Nieto JML, Coenraads R, Dejoz A, Vazquez MI, Grasselli STOAMGRK, Lyons JE, The role of metal oxides as promoters of V2O5/I3-Al2O3 catalysts in the oxidative dehydrogenation of propane. In Studies in Surface Science and Catalysis, Elsevier, 110, 443 (1997).
Demirci UB, Garin F, J. Mol. Catal. A-Chem., 188(1-2), 233 (2002)
Fofrcaiu D, Li JQ, Kogelbauer A, J. Mol. Catal. A-Chem., 124, 67 (1997)
Lee H, Lee JK, Hong UG, Yoo Y, Cho YJ, Lee J, Jang HS, Jung JC, Song IK, J. Ind. Eng. Chem., 18(2), 808 (2012)
Chen G, Guo CY, Qiao H, Ye M, Qiu X, Yue C, Catal. Commun., 41, 70 (2013)
Bensitel M, Saur O, Lavalley JC, Morrow BA, Mater. Chem. Phys., 19, 147 (1988)
Corma A, Fornes V, Juanrajadell MI, Nieto JM, Appl. Catal. A: Gen., 116(1-2), 151 (1994)
Arata K, Hino M, Appl. Catal., 59, 197 (1990)
Arata K, Matsuhashi H, Hino M, Nakamura H, Catal. Today, 81(1), 17 (2003)
Morterra C, Cerrato G, Pinna F, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 55, 95 (1998)
Martra G, Arena F, Coluccia S, Frusteri F, Parmaliana A, Catal. Today, 63(2-4), 197 (2000)
Deshmane VG, Adewuyi YG, Fuel, 107, 474 (2013)
Tanabe K, Yamaguchi T, Inui T, Design of Sulfur-Promoted Solid Superacid Catalyst, In Studies in Surface Science and Catalysis, Elsevier, 44, 99 (1989).
Corma A, Chem. Rev., 95(3), 559 (1995)
Wachs IE, Jehng JM, Deo G, Weckhuysen BM, Guliants VV, Benziger JB, Sundaresan S, J. Catal., 170(1), 75 (1997)
Le Bars J, Vedrine JC, Auroux A, Trautmann S, Baerns M, Appl. Catal. A: Gen., 88, 179 (1992)
Blasco T, Galli A, Nieto JM, Trifiro F, J. Catal., 169(1), 203 (1997)
Dhak D, Pramanik P, J. Am. Ceram. Soc., 89(3), 1014 (2006)
Rahmani F, Haghighi M, Vafaeian Y, Estifaee P, J. Power Sources, 272, 816 (2014)
Talkhoncheh SK, Haghighi M, J. Natural Gas Sci. Eng., 23, 16 (2015)
Aghamohammadi S, Haghighi M, Chem. Eng. J., 264, 359 (2015)
Aghaei E, Haghighi M, Powder Technol., 269, 358 (2015)
Lisi L, Marchese L, Pastore HO, Frache A, Ruoppolo G, Russo G, Topics in Catalysis, 22, 95 (2003)
Marchese L, Frache A, Gatti G, Coluccia S, Lisi L, Ruoppolo G, Russo G, Pastore HO, J. Catal., 208(2), 479 (2002)
Goula MA, Lemonidou AA, Efstathiou AM, J. Catal., 161(2), 626 (1996)
Yadav GD, Nair JJ, Microporous Mesoporous Mater., 33, 1 (1999)
Saravanan K, Tyagi B, Bajaj HC, Catal. Sci. Technol., 2, 2512 (2012)
Ejtemaei M, Tavakoli A, Charchi N, Bayati B, Babaluo AA, Bayat Y, Adv. Powder Technol., 25(3), 840 (2014)
Talati A, Haghighi M, Rahmani F, Adv. Powder Technol., 27(4), 1195 (2016)
Rahmani F, Haghighi M, Mahboob S, Ultrason. Sonochem., 33, 150 (2016)
Rahmani F, Haghighi M, RSC Adv., 6, 89551 (2016)
Banares MA, Catal. Today, 51(2), 319 (1999)
Busca G, Finocchio E, Ramis G, Ricchiardi G, Catal. Today, 32(1-4), 133 (1996)
Sun G, Huang Q, Huang S, Wang Q, Li H, Liu H, Wan S, Zhang X, Wang J, Catalysts, 6, 1 (2016)
Fu H, Liu ZP, Li ZH, Wang WN, Fan KN, J. Am. Chem. Soc., 128(34), 11114 (2006)
Chen KD, Iglesia E, Bell AT, J. Catal., 192(1), 197 (2000)
Kutzelnigg W, Atoms in Molecules. A Quantum Theory. (Reihe:International Series of Monographs on Chemistry, Vol. 22.) Von R.F.W. Bader. Clarendon Press, Oxford, 1990. XVIII, 438 S., geb. ￡ 50.00. - ISBN 0-19-855168-1. WILEY-VCH Verlag GmbH, 22, 104 (1992).
