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Received December 2, 2016
Accepted February 6, 2017
- This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Flux, antifouling and separation characteristics enhancement of nanocomposite polyethersulfone mixed-matrix membrane by embedding synthesized hydrophilic adipate ferroxane nanoparticles
CFD Research Centre, Department of Chemical Engineering, Faculty of Engineering, Razi University, Kermanshah, Iran 1Water and Wastewater Research Center (WWRC), Department of Applied Chemistry, Faculty of Chemistry, Razi University, Kermanshah, Iran 2Department of Biology, Faculty of Science, Razi University, Kermanshah, Iran
Korean Journal of Chemical Engineering, May 2017, 34(5), 1444-1455(12), 10.1007/s11814-017-0031-3
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Abstract
Polyethersulfone (PES) nanofiltration (NF) membranes were prepared by blending of synthesized hydrophilic adipate ferroxane nanoparticles (AFNPs) as a novel multifunctional nanofiller via the phase inversion method. The water contact angle measurement indicated the higher hydrophilicity of the NF membranes. The water flux of the membranes improved significantly after the addition of AFNPs, from 10.4 to 32.2 kg/m2h. Antifouling characteristics of AFNPs/PES membranes were improved by increased hydrophilicity and decreased membrane surface roughness. The 0.6 wt% AFNPs/PES membrane exhibited the highest FRR (96%) and the lowest irreversible fouling resistance (6%). The nanofiltration performance of the prepared membranes was evaluated by dye removal and salt retention. The results proved the high dye removal capability of modified membranes (98% rejection) compared with the unfilled PES membrane (89% rejection). The salt retention sequence for membrane with 0.2 wt% of nanoparticles was Na2SO4 (70%)>MgSO4 (60%)>NaCl (18%).
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References
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Zinadini S, Zinatizadeh AA, Rahimi M, Vatanpour V, Zangeneh H, Beygzadeh M, Desalination, 349, 145 (2014)
Celik E, Liu L, Choi H, Water Res., 45, 274 (2011)
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Maurya SK, Parashuram K, Singh PS, Ray P, Reddy AVR, Desalination, 304, 11 (2012)
Sarkar S, Sengupta AK, Prakash P, Environ. Sci. Technol., 44, 1161 (2010)
Nilsson M, Tragardh G, Ostergren K, J. Membr. Sci., 312(1-2), 97 (2008)
Elimelech M, Chen WH, Waypa JJ, Desalination, 95, 269 (1994)
Peeters JMM, Boom JP, Mulder MHV, Strathmann H, J. Membr. Sci., 145(2), 199 (1998)
Tang ZQ, Li W, Zhou J, Yu HY, Huang L, Yan MG, Gu JS, Wei XW, Sep. Purif. Technol., 64(3), 332 (2009)
Barroso T, Temtem M, Casimiro T, Aguiar-Ricardo A, J. Supercrit. Fluids, 56(3), 312 (2011)
Fane AG, Beatson P, Li H, Water Sci. Technol., 41, 303 (2000)
Luo JQ, Ding LH, Wan YH, Jaffrin MY, Chem. Eng. J., 181, 397 (2012)
Patel TM, Nath K, Desalination, 317, 132 (2013)
Wei XY, Wang Z, Fan FH, Wang JX, Wang SC, Desalination, 251(1-3), 167 (2010)
Liikanen R, Yli-Kuivila J, Laukkanen R, J. Membr. Sci., 195(2), 265 (2002)
Simon A, Price WE, Nghiem LD, Sep. Purif. Technol., 113, 42 (2013)
Rana D, Matsuura T, Chem. Rev., 110(4), 2448 (2010)
Susanti RF, Han YS, Kim J, Lee YH, Carbonell RG, J. Membr. Sci., 440, 88 (2013)
Ba CY, Ladner DA, Economy J, J. Membr. Sci., 347(1-2), 250 (2010)
Wang CC, Feng RR, Yang FL, J. Colloid Interface Sci., 357(2), 273 (2011)
Shi Q, Su YL, Chen WJ, Peng JM, Nie LY, Zhang L, Jiang ZY, J. Membr. Sci., 366(1-2), 398 (2011)
Vatanpour V, Madaeni SS, Rajabi L, Zinadini S, Derakhshan AA, J. Membr. Sci., 401-402, 132 (2012)
Vatanpour V, Madaeni SS, Khataee AR, Salehi E, Zinadini S, Monfared HA, Desalination, 292, 19 (2012)
Zou W, Huang Y, Luo J, Liu J, Zhao CS, J. Membr. Sci., 358(1-2), 76 (2010)
Rahimpour A, Madaeni SS, J. Membr. Sci., 360(1-2), 371 (2010)
Escobar CI, Eric MH, Christopher JG, Francis AD, J. Am. Water. Works. Ass., 97, 79 (2005)
Li JB, Zhu JW, Zheng MS, J. Appl. Polym. Sci., 103(6), 3623 (2007)
Li JF, Xu ZL, Yang H, Yu LY, Liu M, Appl. Surf. Sci., 255, 44725 (2009)
Kim J, der Bruggen BV, Environ. Pollut., 158, 2335 (2010)
Rahimpour A, Jahanshahi M, Rajaeian B, Rahimnejad M, Desalination, 278(1-3), 343 (2011)
Liu F, Abed MRM, Li K, J. Membr. Sci., 366(1-2), 97 (2011)
Yu LY, Xu ZL, Shen HM, Yang H, J. Membr. Sci., 337(1-2), 257 (2009)
Zinadini S, Zinatizadeh AA, Rahimi M, Vatanpour V, Zangeneh H, J. Membr. Sci., 453, 292 (2014)
Vatanpour V, Madaeni SS, Moradian R, Zinadini S, Astinchap B, J. Membr. Sci., 375(1-2), 284 (2011)
Huang ZQ, Chen K, Li SN, Yin XT, Zhang Z, Xu HT, J. Membr. Sci., 315(1-2), 164 (2008)
Xu P, Zeng GM, Huang DL, Feng CL, Hu S, Zhao MH, Lai C, Wei Z, Huang C, Xie GX, Liu ZF, Sci. Total. Environ., 424, 1 (2012)
Ma J, Wang ZH, Pan MB, Guo YF, J. Membr. Sci., 341(1-2), 214 (2009)
Zhang CC, Li X, Yang Y, Wang C, Appl. Phys. A-Mater. Sci. Process., 97, 281 (2009)
Ghaemi N, Madaeni SS, Daraei P, Rajabi H, Zinadini S, Alizadeh A, Heydari R, Beygzadeh M, Ghouzivand S, Chem. Eng. J., 263, 101 (2015)
Daraei , Madaeni SS, Ghaemi N, Salehi E, Khadivi MA, Moradian R, Astinchap B, J. Membr. Sci., 415-416, 250 (2012)
Sabbatini P, Rossi F, Thern G, Marajofsky A, de Cortalezzi MMF, Desalination, 248(1-3), 184 (2009)
Sabbatini P, Yrazu F, Rossi F, Thern G, Marajofsky A, Fidalgo de Cortalezzi M, Water. Res., 44, 5702 (2010)
Maguire-Boyle SJ, Liga MV, Li Q, Barron AR, Nanoscale, 4, 5627 (2012)
Zhang L, Chae SR, Lin S, Wiesner MR, Environ. Eng. Sci., 29, 124 (2012)
Cortalezzi MM, Rose J, Wells GF, Bottero JY, Barron AR, Wiesner MR, J. Membr. Sci., 227(1-2), 207 (2003)
Rahimi S, Moattari RM, Rajabi L, Derakhshan AA, Keyhani M, J. Ind. Eng. Chem., 23, 33 (2015)
Saien J, Asgari M, Soleymani AR, Taghavinia N, Chem. Eng. J., 151(1-3), 295 (2009)
Daneshvar N, Aleboyeh A, Khataee AR, Chemosphere, 59, 761 (2005)
Bagheripour E, Moghadassi A, Hosseini SM, Korean J. Chem. Eng., 33(4), 1462 (2016)
Moochani M, Moghadassi A, Hosseini SM, Bagheripour E, Parvizian F, Korean J. Chem. Eng., 33(9), 2674 (2016)
Bae TH, Tak TM, J. Membr. Sci., 249(1-2), 1 (2005)
Ge L, Zhu ZH, Rudolph V, Sep. Purif. Technol., 78(1), 76 (2011)
Celik E, Liu L, Choi H, Water Res., 45, 5287 (2011)
Zinadini S, Zinatizadeh AA, Rahimi M, Vatanpour V, Zangeneh H, Beygzadeh M, Desalination, 349, 145 (2014)
Celik E, Liu L, Choi H, Water Res., 45, 274 (2011)
Wu HQ, Tang BB, Wu PY, J. Membr. Sci., 362(1-2), 374 (2010)
Han MJ, Nam ST, J. Membr. Sci., 202(1-2), 55 (2002)
Zhao XY, Ma J, Wang ZH, Wen G, Jiang J, Shi FM, Sheng LX, Desalination, 303, 29 (2012)
Qiu S, Wu L, Pan X, Zhang L, Chen H, Gao C, J. Membr. Sci., 342, 1 (2009)
Zhao H, Wu L, Zhou Z, Zhang L, Chen H, Phys. Chem. Chem. Phys., 15, 9084 (2013)
Vrijenhoek EM, Hong S, Elimelech M, J. Membr. Sci., 188(1), 115 (2001)
Maurya SK, Parashuram K, Singh PS, Ray P, Reddy AVR, Desalination, 304, 11 (2012)
Sarkar S, Sengupta AK, Prakash P, Environ. Sci. Technol., 44, 1161 (2010)
Nilsson M, Tragardh G, Ostergren K, J. Membr. Sci., 312(1-2), 97 (2008)
Elimelech M, Chen WH, Waypa JJ, Desalination, 95, 269 (1994)
Peeters JMM, Boom JP, Mulder MHV, Strathmann H, J. Membr. Sci., 145(2), 199 (1998)