Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received December 6, 2016
Accepted February 12, 2017
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
Effects of polyolefin elastomer on physico-mechanical and thermal properties of HDPE/CaCO3/LDPE-g-MA/POE composites
Department of Chemical Engineering, Kwangwoon University, 20 Gwangun-ro, Nowon-gu, Seoul 01897, Korea 1Mineral Resources Research Division, Korea Institute of Geoscience and Mineral Resources, 124 Gwahak-ro, Yuseong-gu, Daejeon 34132, Korea
chan@kw.ac.kr
Korean Journal of Chemical Engineering, May 2017, 34(5), 1531-1540(10), 10.1007/s11814-017-0040-2
Download PDF
Abstract
The HDPE/CaCO3/LDPE-g-MA/POE composite was prepared by blending high density polyethylene (HDPE) filled calcium carbonate (CaCO3), with maleic anhydride grafted low density polyethylene (LDPE-g-MA) as a compatibilizer, and a polyolefin elastomer (POE). The composites exhibited improved tensile strength than composites without POE. The addition of POE led to a decrease in the d-spacing of CaCO3, indicating that core-shell structure was formed between POE and CaCO3. Because of good dispersion of CaCO3, this improved thermal stability and decreased crystallinity (Xc) and conformational change (ΔSc). The composites contributed to improved mechanical property and good dispersion of CaCO3, and efficient activation energy by accelerating the crystallization rate.
References
Holden G, Legge NR, Quirk RP, In Thermoplastic Elastomers: A comprehensive Review, Hanser, New York (1996).
Honeker CC, Thomas EL, Chem. Mater., 8, 1702 (1996)
Petcharoen K, Sirivat A, Curr. Appl. Phys., 13(6), 1119 (2013)
Tunc S, Duman O, Polat TG, Carbohydr. Polym., 150, 259 (2016)
Tunc S, Duman O, Appl. Clay Sci., 48, 414 (2010)
Tunc S, Duman O, LWT-Food Sci. Technol, 44, 465 (2011)
Yang H, Zhang XQ, Qu C, Li B, Zhang LJ, Zhang Q, Fu Q, Polymer, 48(3), 860 (2007)
Valera-Zaragoza M, Ramirez-Vargas E, Medellin-Rodriguez FJ. Huerta-Martinez BM, Polym. Degrad. Stabil., 91, 1319 (2006)
Guo M, Zhou X, Dai G, Hu F, Polym. Polym. Compos., 13, 173 (2005)
Tsai Y, Wu JH, Wu YT, Li CH, Leu T, Sci. Technol. Adv. Mater., 9, 1 (2008)
Su FH, Huang HX, J. Appl. Polym. Sci., 112(5), 3016 (2009)
Ma CG, Mai YL, Rong MZ, Ruan WH, Zhang MQ, Compos. Sci. Technol., 67, 2997 (2007)
Ahn Y, Jeon JH, Park JH, Thenepalli T, Ahn JW, Han C, Korean J. Chem. Eng., 33(11), 3258 (2016)
Wang K, Addiego F, Bahlouli N, Ahzi S, Remond Y, Toniazzo V, Compos. Sci. Technol., 95, 89 (2014)
Alimardani M, Razzaghi-Kashani M, Ghoreishy MHR, Mater. Des., 115, 348 (2017)
Wunderlich B, Dole M, J. Polym. Sci., 24, 201 (1957)
Elleithy RH, Ali I, Ali MA, Al-Zahrani SM, J. Appl. Polym. Sci., 117(4), 2413 (2010)
Avrami M, J. Chem. Phys., 7, 1103 (1939)
Jeziorny A, Polymer, 19, 1142 (1978)
Kissinger HE, Anal. Chem., 29, 1702 (1957)
Liang JZ, Zhu B, Ma WY, Polym. Compos., 37, 539 (2016)
Xie TX, Liu HZ, Ou YC, Yang GS, J. Appl. Polym. Sci., 101(5), 3361 (2006)
Sampath WDM, Edirisingle DG, Egodage SM, DOI:10. 1109/MERCon.2015.7112350 (2015).
Seavey KC, Liu YA, Khare NP, Bremner T, Chen CC, Ind. Eng. Chem. Res., 42(21), 5354 (2003)
Svoboda P, Poongavalappil S, Theravalappil R, Svobodova D, Mokrejs P, Polym. Int., 62, 184 (2013)
Yang H, Zhang XQ, Qu C, Li B, Zhang LJ, Zhang Q, Fu Q, Polymer, 48(3), 860 (2007)
Ma CG, Mai YL, Rong MZ, Ruan WH, Zhang MQ, Compos. Sci. Technol., 67, 2997 (2007)
Long Y, Shanks RA, J. Appl. Polym. Sci., 61(11), 1877 (1996)
Mirabella FM, J. Polym. Sci. B: Polym. Phys., 32(7), 1205 (1994)
Sun NX, Liu XD, Lu K, Scr. Mater., 34, 1201 (1996)
Li J, Zhou C, Gang W, Polym. Test, 22, 217 (2003)
Kim YC, Lee SJ, Kim JC, Cho H, Polym. J., 37, 206 (2005)
Michael JS, Abdulwahab SA, Kurt FS, Anongnat S, Priya V, Macromolecules, 34, 1864 (2001)
Honeker CC, Thomas EL, Chem. Mater., 8, 1702 (1996)
Petcharoen K, Sirivat A, Curr. Appl. Phys., 13(6), 1119 (2013)
Tunc S, Duman O, Polat TG, Carbohydr. Polym., 150, 259 (2016)
Tunc S, Duman O, Appl. Clay Sci., 48, 414 (2010)
Tunc S, Duman O, LWT-Food Sci. Technol, 44, 465 (2011)
Yang H, Zhang XQ, Qu C, Li B, Zhang LJ, Zhang Q, Fu Q, Polymer, 48(3), 860 (2007)
Valera-Zaragoza M, Ramirez-Vargas E, Medellin-Rodriguez FJ. Huerta-Martinez BM, Polym. Degrad. Stabil., 91, 1319 (2006)
Guo M, Zhou X, Dai G, Hu F, Polym. Polym. Compos., 13, 173 (2005)
Tsai Y, Wu JH, Wu YT, Li CH, Leu T, Sci. Technol. Adv. Mater., 9, 1 (2008)
Su FH, Huang HX, J. Appl. Polym. Sci., 112(5), 3016 (2009)
Ma CG, Mai YL, Rong MZ, Ruan WH, Zhang MQ, Compos. Sci. Technol., 67, 2997 (2007)
Ahn Y, Jeon JH, Park JH, Thenepalli T, Ahn JW, Han C, Korean J. Chem. Eng., 33(11), 3258 (2016)
Wang K, Addiego F, Bahlouli N, Ahzi S, Remond Y, Toniazzo V, Compos. Sci. Technol., 95, 89 (2014)
Alimardani M, Razzaghi-Kashani M, Ghoreishy MHR, Mater. Des., 115, 348 (2017)
Wunderlich B, Dole M, J. Polym. Sci., 24, 201 (1957)
Elleithy RH, Ali I, Ali MA, Al-Zahrani SM, J. Appl. Polym. Sci., 117(4), 2413 (2010)
Avrami M, J. Chem. Phys., 7, 1103 (1939)
Jeziorny A, Polymer, 19, 1142 (1978)
Kissinger HE, Anal. Chem., 29, 1702 (1957)
Liang JZ, Zhu B, Ma WY, Polym. Compos., 37, 539 (2016)
Xie TX, Liu HZ, Ou YC, Yang GS, J. Appl. Polym. Sci., 101(5), 3361 (2006)
Sampath WDM, Edirisingle DG, Egodage SM, DOI:10. 1109/MERCon.2015.7112350 (2015).
Seavey KC, Liu YA, Khare NP, Bremner T, Chen CC, Ind. Eng. Chem. Res., 42(21), 5354 (2003)
Svoboda P, Poongavalappil S, Theravalappil R, Svobodova D, Mokrejs P, Polym. Int., 62, 184 (2013)
Yang H, Zhang XQ, Qu C, Li B, Zhang LJ, Zhang Q, Fu Q, Polymer, 48(3), 860 (2007)
Ma CG, Mai YL, Rong MZ, Ruan WH, Zhang MQ, Compos. Sci. Technol., 67, 2997 (2007)
Long Y, Shanks RA, J. Appl. Polym. Sci., 61(11), 1877 (1996)
Mirabella FM, J. Polym. Sci. B: Polym. Phys., 32(7), 1205 (1994)
Sun NX, Liu XD, Lu K, Scr. Mater., 34, 1201 (1996)
Li J, Zhou C, Gang W, Polym. Test, 22, 217 (2003)
Kim YC, Lee SJ, Kim JC, Cho H, Polym. J., 37, 206 (2005)
Michael JS, Abdulwahab SA, Kurt FS, Anongnat S, Priya V, Macromolecules, 34, 1864 (2001)
