Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received July 14, 2016
Accepted January 1, 2017
- This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
Experimental and numerical predictions of ash particle erosion in SCR monolithic catalysts for coal-fired utility boilers
School of Energy and Environment, Southeast University, Nanjing 210096, P. R. China 1Datang Nanjing Environmental Protection Technology Co., Ltd., Nanjing 211111, P. R. China
fqsi@seu.edu.cn
Korean Journal of Chemical Engineering, May 2017, 34(5), 1563-1575(13), 10.1007/s11814-017-0001-9
Download PDF
Abstract
Erosion by particles in monolithic selective catalyst reduction (SCR) processes can reduce the operational life of a catalyst and threaten the performance of the SCR system. We present an integrated approach implemented in two stages to predict the erosion condition of SCR processes. First, a 3D computational fluid dynamics (CFD) model was established for a full-sized SCR reactor to obtain information on the flue gas and ash particles at the entrance of the catalyst layer. Second, the detailed inner catalyst structure layers were simulated using MATLAB and a catalyst erosion model was developed, according to the initial and boundary conditions obtained using the CFD models. Relative cold state tests and erosion measurements were conducted to validate the simulation results. The model was applied to investigate the relationship between the reactor installment, the gas-solid flow field and the catalyst erosion. Moreover, a series of retrofit schemes were implemented to confirm that this method can be used in engineering applications.
References
Forzatti P, Appl. Catal. A: Gen., 222(1-2), 221 (2001)
Shah KV, Cieplik MK, Betrand CI, van de Kamp WL, Vuthaluru HB, Fuel Process. Technol., 91(5), 531 (2010)
Benson SA, Laumb JD, Crocker CR, Pavlish JH, Fuel Process. Technol., 86(5), 577 (2005)
Strege JR, Zygarlicke CJ, Folkedahl BC, McCollor DP, Fuel, 87(7), 1341 (2008)
Bartholomew CH, Appl. Catal. A: Gen., 212, 17 (2001)
Lei ZG, Wen CP, Zhang J, Chen BH, Ind. Eng. Chem. Res., 50(10), 5942 (2011)
Schwammle T, Bertsche F, Hartung A, Brandenstein J, Heidel B, Scheffknecht G, Chem. Eng. J., 222, 274 (2013)
Yao J, Zhong ZP, Zhu L, Chem. Eng. Technol., 38(2), 283 (2015)
Yang J, Ma HT, Yamamoto Y, Yu J, Xu GW, Zhang ZG, Suzuki Y, Chem. Eng. J., 230, 513 (2013)
Gandhi MB, Vuthaluru R, Vuthaluru H, French D, Shah K, Appl. Therm. Eng., 42, 90 (2012)
Pereira GC, de Souza FJ, Martins DAD, Powder Technol., 261, 105 (2014)
Schade KP, Erdmann HJ, Hadrich T, Schneider H, Frank T, Bernert K, Powder Technol., 125(2-3), 242 (2002)
Oka YI, Okamura K, Yoshida T, Wear, 259, 95 (2005)
Oka YI, Yoshid T, Wear, 259, 102 (2005)
Nagarajan R, Ambedkar B, Gowrisankar S, Somasundaram S, Wear, 267, 122 (2009)
Lin Z, Ruan XD, Zhu ZC, Fu X, Powder Technol., 254, 150 (2014)
Mansouri, Arabnejad h, Shirazi SA, McLaury BS, Wear, 332, 1090 (2015)
Budinski KG, Wear, 203, 302 (1997)
Gan L, Lei S, Yu J, Ma H, Yamamoto Y, Suzuki Y, Zhang Z, Front. Environ. Sci. Eng., 9, 979 (2015)
Parsi M, Najmi K, Najafifard F, Hassani S, McLaury BS, Shirazi SA, J. Nat. Gas Sci. Eng., 21, 850 (2014)
Chae HJ, Choo ST, Choi H, Nam IS, Yang HS, Song SL, Ind. Eng. Chem. Res., 39(5), 1159 (2000)
Cho JM, Choi JW, Hong SH, Kim KC, Na JH, Lee JY, Korean J. Chem. Eng., 23(1), 43 (2006)
Xu YY, Zhang Y, Wang JC, Yuan JQ, Comput. Chem. Eng., 49, 50 (2013)
Xu YY, Zhang Y, Liu FN, Shi WF, Yuan JQ, Comput. Chem. Eng., 69, 119 (2014)
Park HC, Choi HS, Choi YS, J. Comput. Fluids Eng., 16, 66 (2011)
Launder BE, Spalding DB, Comput. Meth. Appl. Mech. Eng., 3, 269 (1974)
Li A, Ahmadi G, Aerosol Sci. Technol., 16, 209 (1992)
Sommerfeld M, Huber N, Int. J. Multiph. Flow, 25(6), 1457 (1999)
Kuan B, Rea N, Schwarz MP, Powder Technol., 179(1-2), 65 (2007)
Mezhericher M, Brosh T, Levy A, Part. Sci. Technol., 29(2), 197 (2011)
Shah KV, Cieplik MK, Betrand CI, van de Kamp WL, Vuthaluru HB, Fuel Process. Technol., 91(5), 531 (2010)
Benson SA, Laumb JD, Crocker CR, Pavlish JH, Fuel Process. Technol., 86(5), 577 (2005)
Strege JR, Zygarlicke CJ, Folkedahl BC, McCollor DP, Fuel, 87(7), 1341 (2008)
Bartholomew CH, Appl. Catal. A: Gen., 212, 17 (2001)
Lei ZG, Wen CP, Zhang J, Chen BH, Ind. Eng. Chem. Res., 50(10), 5942 (2011)
Schwammle T, Bertsche F, Hartung A, Brandenstein J, Heidel B, Scheffknecht G, Chem. Eng. J., 222, 274 (2013)
Yao J, Zhong ZP, Zhu L, Chem. Eng. Technol., 38(2), 283 (2015)
Yang J, Ma HT, Yamamoto Y, Yu J, Xu GW, Zhang ZG, Suzuki Y, Chem. Eng. J., 230, 513 (2013)
Gandhi MB, Vuthaluru R, Vuthaluru H, French D, Shah K, Appl. Therm. Eng., 42, 90 (2012)
Pereira GC, de Souza FJ, Martins DAD, Powder Technol., 261, 105 (2014)
Schade KP, Erdmann HJ, Hadrich T, Schneider H, Frank T, Bernert K, Powder Technol., 125(2-3), 242 (2002)
Oka YI, Okamura K, Yoshida T, Wear, 259, 95 (2005)
Oka YI, Yoshid T, Wear, 259, 102 (2005)
Nagarajan R, Ambedkar B, Gowrisankar S, Somasundaram S, Wear, 267, 122 (2009)
Lin Z, Ruan XD, Zhu ZC, Fu X, Powder Technol., 254, 150 (2014)
Mansouri, Arabnejad h, Shirazi SA, McLaury BS, Wear, 332, 1090 (2015)
Budinski KG, Wear, 203, 302 (1997)
Gan L, Lei S, Yu J, Ma H, Yamamoto Y, Suzuki Y, Zhang Z, Front. Environ. Sci. Eng., 9, 979 (2015)
Parsi M, Najmi K, Najafifard F, Hassani S, McLaury BS, Shirazi SA, J. Nat. Gas Sci. Eng., 21, 850 (2014)
Chae HJ, Choo ST, Choi H, Nam IS, Yang HS, Song SL, Ind. Eng. Chem. Res., 39(5), 1159 (2000)
Cho JM, Choi JW, Hong SH, Kim KC, Na JH, Lee JY, Korean J. Chem. Eng., 23(1), 43 (2006)
Xu YY, Zhang Y, Wang JC, Yuan JQ, Comput. Chem. Eng., 49, 50 (2013)
Xu YY, Zhang Y, Liu FN, Shi WF, Yuan JQ, Comput. Chem. Eng., 69, 119 (2014)
Park HC, Choi HS, Choi YS, J. Comput. Fluids Eng., 16, 66 (2011)
Launder BE, Spalding DB, Comput. Meth. Appl. Mech. Eng., 3, 269 (1974)
Li A, Ahmadi G, Aerosol Sci. Technol., 16, 209 (1992)
Sommerfeld M, Huber N, Int. J. Multiph. Flow, 25(6), 1457 (1999)
Kuan B, Rea N, Schwarz MP, Powder Technol., 179(1-2), 65 (2007)
Mezhericher M, Brosh T, Levy A, Part. Sci. Technol., 29(2), 197 (2011)