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Received August 10, 2016
Accepted March 16, 2017
- This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Silver nanoparticle loaded silica adsorbent for wastewater treatment
Bioproducts Lab., Department of Chemical Engineering, A.C. Tech, Anna University, Chennai-25, India
Korean Journal of Chemical Engineering, June 2017, 34(6), 1801-1812(12), 10.1007/s11814-017-0075-4
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Abstract
Our aim was to prepare silver nanoparticle loaded silica adsorbent for the removal of pollutants and pathogens in wastewater. The pathogens were inactivated by silver nanoparticles loaded with silica by wet impregnation method. Fourier transform infrared spectroscopy, energy dispersive X-ray spectroscopy, and X-ray Diffraction studies confirmed the silver nanoparticle loaded on silica. Inductively coupled plasma atomic emission spectroscopy showed 0.6mg/g silver nanoparticle in the prepared adsorbent. The prepared adsorbent has potential against Escherichia coli and was described through Chick, Chick-Watson and Homs inactivation kinetic models. Five-hundred (500) ppm concentration of the prepared adsorbent showed complete inhibition with the shouldering or lag curve of inactivation and the k' values of 0.019 min-1. After treatment, tannery, dairy and canteen effluents showed significant COD reduction with maximum adsorption capacity of 145, 142 and 69mg/g visa versa. Regeneration of the spent adsorbent used alkali washing and reused up to three cycles.
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Rafie MHE, Shaheen TI, Mohamed AA, Hebeish A, Carbohydr. Polym., 90, 915 (2012)
Rai M, Posten C, Green Biosynthesis of Nanoparticles Mechanisms and Applications, CABI Publishers, UK (2013).
Okafor F, Janen A, Kukhtareva T, Edwards V, Curley M, Int. J. Environ. Res. Public Health, 10, 5221 (2013)
Lv YH, Liu H, Wang Z, Liu SJ, Hao LJ, Sang YH, Liu D, Wang JY, Boughton RI, J. Membr. Sci., 331(1-2), 50 (2009)
Pal J, Deb MK, Deshmukh DK, Verma D, Appl. Water Sci., 3, 367 (2013)
Vimala K, Mohan YM, Varaprasad K, Reddy NN, Ravindra S, Naidu NS, Raju KM, J. Biomater. Nanobiotechnol., 2, 55 (2011)
Tuan TQ, Son NV, Hoang TKD, Luong NH, Thuy BT, Nguyen TVA, Hoa ND, Hai NH, J. Hazard. Mater., 192(3), 1321 (2011)
Jana NR, Earhart C, Ying JY, Chem. Mater., 19, 5074 (2007)
Li F, Du P, Chen W, Zhang S, Anal. Chim. Acta, 585, 211 (2007)
Compagnini G, Fragala ME, DUrso LD, Spinella C, Puglisi O, J. Mater. Res., 16, 2934 (2001)
Quang DV, Sarawade PB, Hilonga A, Park SD, Kim JK, Kim HT, Appl. Surf. Sci., 257(9), 4250 (2011)
Thamilselvi V, Radha KV, Dig. J. Nanomater Bios., 8, 1101 (2013)
Chick H, J. Hygiene, 8, 92 (1908)
Eaton D, Clesceri LS, Greenberg AE, Franson MAH, American Public Health Association, 19th Ed. Washington (1995) DC.
Aber S, Sheydaei M, Clean - Soil, Air, Water, 40(1), 87 (2012)
Teoh YP, Khan MA, Choong TSY, Chem. Eng. J., 217, 248 (2013)
dos Santos AB, Cervantes FJ, van Lier JB, Bioresour. Technol., 98(12), 2369 (2007)
Sumesh E, Bootharaju MS, Pradeep AT, J. Hazard. Mater., 189(1-2), 450 (2011)
Das SK, Khan MMR, Parandhaman T, Laffir F, Guha, AK, Sekarana G, Mandal AB, Nanoscale, 5, 5549 (2014)
Li WR, Xie XB, Shi QS, Zeng HY, Ou-Yang YS, Chen YB, Appl. Microbiol. Biotechnol., 85(4), 1115 (2010)
Jain P, Pradeep T, Biotechnol. Bioeng., 90(1), 59 (2005)
Jung WH, Koo HC, Kim KW, Shin S, Kim SH, Park YH, Appl. Environ. Microbiol., 74(7), 2171 (2008)
Lee YJ, Nam SH, J. Microbiol., 40, 119 (2002)
Sheet I, Holail H, Olama Z, Kabbani A, Hines M, Int. J. Current Microbiol. Appl. Sci., 2(4), 1 (2013)
Somani SB, Ingole NW, Int. J. Environ. Sci., 2, 1344 (2012)
Kist LT, Albrecht C, Machado EL, Clean-soil, Air, Water, 36(9), 775 (2008)
Jessen AL, ProQuest, Ann Arbor, U.S.A. (2006).
Calvete T, Lima EC, Cardoso NF, Dias SLP, Ribeir ES, Clean - Soil, Air, Water, 38, 521 (2010)
Low LW, Teng TT, Ahmad A, Morad N, Wong YS, Water Air Soil Pollut., 218, 293 (2011)
Mohan D, Singh KR, Singh VK, J. Hazard. Mater., 152(3), 1045 (2008)
Ahmad AA, Hameed BH, J. Hazard. Mater., 172(2-3), 1538 (2009)
Liu R, Shen X, Yang X, Wang Q, Yang F, J. Nanopart. Res., 15, 1679 (2013)
Zheng LC, Dang Z, Yi XY, Zhang H, J. Hazard. Mater., 176(1-3), 650 (2010)
El-Nass MH, Al-Zuhair S, Ahaija MA, J. Hazard. Mater., 173, 1750 (2010)
Sivakumar D, Global J. Environ. Sci. Manage., 1(1), 27 (2015)
NurFatinah AA, Rajesh N, Masniroszaime MZ, J. Eng. Sci. Technol., 1, 8 (2015)
Mendez-Conteras JM, Atenodoro J, Champion FA, Vallejo-Cantu NA, Alvardo-Lassman A, Water SA., 35(4), 371 (2009)
Al-Hakami SM, Khalil AB, Laoui T, Atieh MA, Bioinorg Chem. Appl., 2013, 1 (2013)
Ansari R, Mohammad-khah A, Nazmi M, Current Chem. Lett., 2, 215 (2013)
Surchi KMS, Int. J. Chem., 3(3), 103 (2011)
Watson HE, J. Hygiene, 536, 536 (1908)
Hom LW, Journal of the Sanitary Engineering Division, ASCE, 98, 183 (1972)
Langmuir I, J. Am. Chem. Soc., 38(11), 2221 (1916)
Freundlich HMF, J. Phys. Chem., 57, 385 (1906)
Redlich O, Peterson DL, J. Phys. Chem., 63, 1024 (1959)
Sips R, J. Chem. Phys., 16, 490 (1948)
Thajeel AS, Aqua. Sci. Technol., 1, 53 (2013)
Idris S, Yisa J, Itodo AU, Popoola KA, Resource and Environment, 2(2), 51 (2012)
Pakiari AH, Jamshidi Z, J. Phys. Chem. A, 111(20), 4391 (2007)
Schmid FX, Biological Macromolecules:UV-visible Spectrophotometry, Macmillan Publishers Ltd., Nature Publishing Group, Germany (2001).
Solomon SD, Bahadory M, Jeyarajasingam AV, Rutkowsky SA, Boritz C, J. Chem. Educ., 84(2), 332 (2007)