Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received December 25, 2016
Accepted April 4, 2017
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
One-pot synthesis of high fructose corn syrup directly from starch with SO42./USY solid catalyst
*Xiamen Key Laboratory of High-valued Conversion Technology of Agricultural Biomass, College of Energy, Xiamen University, Xiamen 361102, China 1Henan Key Laboratory of Biomass Energy, Huayuan Road 29, Zhengzhou, Henan 450008, China
Korean Journal of Chemical Engineering, July 2017, 34(7), 1924-1929(6), 10.1007/s11814-017-0098-x
Download PDF
Abstract
An efficient process was developed for the conversion of starch directly into high fructose corn syrup (HFCS) by using SO4 2-/USY solid catalyst in water. The SO4 2-/USY catalyst was found to act as a bifunctional catalyst with high activity for both hydrolysis of starch and isomerization of glucose, achieving a one-step preparation path of HFCS from starch. An optimal HFCS yield, containing 58.34% glucose and 27.84% fructose (mass fraction), was obtained at 150 °C for only 1 h.
Keywords
References
Tordoff MG, Alleva AM, Am. J. Clin. Nutr., 51, 963 (1990)
Duffey KJ, Popkin BM, Am. J. Clin. Nutr., 88, 1722 (2008)
Zhang Y, Hidajat K, Ray AK, Biochem. Eng. J., 21, 111 (2004)
Oh YH, Eom IY, Joo JC, Yu JH, Song BK, Lee SH, Hong SH, Park SJ, Korean J. Chem. Eng., 32(10), 1945 (2015)
Jeong J, Antonyraj CA, Shin S, Kim S, Kim B, Lee KY, Cho JK, J. Ind. Eng. Chem., 19(4), 1106 (2013)
Buchholz K, Seibel J, Carbohydr. Res., 343, 1966 (2008)
Corma A, Iborra S, Velty A, Chem. Rev., 107(6), 2411 (2007)
Thananatthanachon T, Rauchfuss TB, Angew. Chem.-Int. Edit., 49, 6616 (2010)
Son PA, Nishimura S, Ebitani K, React. Kinet. Mech. Cata., 106, 185 (2012)
Song YS, Kim JE, Park C, Kim SW, Korean J. Chem. Eng., 28(4), 1096 (2011)
Roman-Leshkov Y, Moliner M, Labinger JA. Davis ME, Angew. Chem.-Int. Edit., 49, 8954 (2010)
Kooyman C, Vellenga K, De Wilt H, Carbohydr. Res., 54, 33 (1977)
Moliner M, Roman-Leshkov Y, Davis ME, Proc. Natl. Acad. Sci. U.S.A., 107, 6164 (2010)
Yang BY, Montgomery R, Carbohydr. Res., 280, 27 (1996)
Knill CJ, Kennedy JF, Carbohydr. Polym., 51, 281 (2003)
Yang BY, Montgomery R, Carbohydr. Res., 280, 27 (1996)
Vuorinen T, Sjostrom E, Carbohydr. Res., 108, 23 (1982)
Mao DS, Lu GZ, Chen QL, Lu WK, Petrochem. Technol., 30, 152 (2001)
Liu HP, Zhou P, Lv LH, Petrochem. Technol., 32, 108 (2003)
Vekariya RH, Prajapati NP, Patel HD, Synth. Commun., 46, 1713 (2016)
Qin X, Zhao W, Han B, Liu B, Lian B, Wu S, Korean J. Chem. Eng., 32(6), 1064 (2015)
Testova N, Paukshtis E, Ione K, React. Kinet. Catal. Lett., 44, 243 (1991)
Zhou P, Wang XP, Cai TX, Chin. Chem. Lett., 13, 1013 (2002)
Won KY, Um BH, Kim SW, Oh KK, Korean J. Chem. Eng., 29(5), 614 (2012)
Esmaeili N, Zohuriaan-Mehr MJ, Bouhendi H, Bagheri-Marandi G, Korean J. Chem. Eng., 33(6), 1964 (2016)
Dee SJ, Bell AT, ChemSusChem, 4, 1166 (2011)
Fan YZ, Cao FH, J. Chem. Eng. Chin. Univ., 25, 341 (2011)
Duffey KJ, Popkin BM, Am. J. Clin. Nutr., 88, 1722 (2008)
Zhang Y, Hidajat K, Ray AK, Biochem. Eng. J., 21, 111 (2004)
Oh YH, Eom IY, Joo JC, Yu JH, Song BK, Lee SH, Hong SH, Park SJ, Korean J. Chem. Eng., 32(10), 1945 (2015)
Jeong J, Antonyraj CA, Shin S, Kim S, Kim B, Lee KY, Cho JK, J. Ind. Eng. Chem., 19(4), 1106 (2013)
Buchholz K, Seibel J, Carbohydr. Res., 343, 1966 (2008)
Corma A, Iborra S, Velty A, Chem. Rev., 107(6), 2411 (2007)
Thananatthanachon T, Rauchfuss TB, Angew. Chem.-Int. Edit., 49, 6616 (2010)
Son PA, Nishimura S, Ebitani K, React. Kinet. Mech. Cata., 106, 185 (2012)
Song YS, Kim JE, Park C, Kim SW, Korean J. Chem. Eng., 28(4), 1096 (2011)
Roman-Leshkov Y, Moliner M, Labinger JA. Davis ME, Angew. Chem.-Int. Edit., 49, 8954 (2010)
Kooyman C, Vellenga K, De Wilt H, Carbohydr. Res., 54, 33 (1977)
Moliner M, Roman-Leshkov Y, Davis ME, Proc. Natl. Acad. Sci. U.S.A., 107, 6164 (2010)
Yang BY, Montgomery R, Carbohydr. Res., 280, 27 (1996)
Knill CJ, Kennedy JF, Carbohydr. Polym., 51, 281 (2003)
Yang BY, Montgomery R, Carbohydr. Res., 280, 27 (1996)
Vuorinen T, Sjostrom E, Carbohydr. Res., 108, 23 (1982)
Mao DS, Lu GZ, Chen QL, Lu WK, Petrochem. Technol., 30, 152 (2001)
Liu HP, Zhou P, Lv LH, Petrochem. Technol., 32, 108 (2003)
Vekariya RH, Prajapati NP, Patel HD, Synth. Commun., 46, 1713 (2016)
Qin X, Zhao W, Han B, Liu B, Lian B, Wu S, Korean J. Chem. Eng., 32(6), 1064 (2015)
Testova N, Paukshtis E, Ione K, React. Kinet. Catal. Lett., 44, 243 (1991)
Zhou P, Wang XP, Cai TX, Chin. Chem. Lett., 13, 1013 (2002)
Won KY, Um BH, Kim SW, Oh KK, Korean J. Chem. Eng., 29(5), 614 (2012)
Esmaeili N, Zohuriaan-Mehr MJ, Bouhendi H, Bagheri-Marandi G, Korean J. Chem. Eng., 33(6), 1964 (2016)
Dee SJ, Bell AT, ChemSusChem, 4, 1166 (2011)
Fan YZ, Cao FH, J. Chem. Eng. Chin. Univ., 25, 341 (2011)
