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Received January 30, 2017
Accepted April 10, 2017
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Co-processing of heavy oil with wood biomass using supercritical m-xylene and n-dodecane solvents
1Department of Chemical and Biomolecular Engineering, Yonsei University, Seoul 03722, Korea 2R&D Center, SEMES CO., LTD., Hwaseong-si, Gyeonggi-do 18383, Korea 3Carbon Resources Institute, Korea Research Institute of Chemical Technology, Daejeon 34114, Korea
Korean Journal of Chemical Engineering, July 2017, 34(7), 1961-1969(9), 10.1007/s11814-017-0109-y
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Abstract
Heavy oil was co-processed with wood biomass by using supercritical m-xylene and n-dodecane. The effects of the solvent, temperature, hydrogen, and catalyst on vacuum residue (VR) upgrading were evaluated using residue conversion, coke formation, and product distribution as performance parameters. VR was subjected to co-processing with microcrystalline cellulose (cellulose) or oil palm empty fruit bunch fiber (EFB), and the parameters were compared with those obtained from VR upgrading. Co-processing of VR/cellulose using a catalyst and hydrogen led to higher conversion (72.6 wt%) than co-processing of VR/EFB at 400 oC and the highest yield of light product (65.7 wt%). Using the Fe3O4 catalyst with H2 for co-processing positively influenced generation of the light product fraction. VR upgrading and co-processing using supercritical solvents could eliminate a certain amount of sulfur compounds from heavy oil. Co-processing of wood biomass with petroleum feedstocks in existing oil refineries can reduce the capital costs of bulk treatment.
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Zhu Z, Toor SS, Rosendahl L, Yu DH, Chen GY, Energy, 80, 284 (2015)
Nassar NN, Husein MM, Fuel Process. Technol., 91(2), 164 (2010)
Fumoto E, Tago T, Masuda T, Energy Fuels, 20(1), 1 (2006)
Choi WI, Park JY, Lee JP, Oh JK, Park YC, Kim JS, Park JM, Kim CH, Lee JS, Biotechnol. Biofuels, 6, 1 (2013)
Sluiter A, Hames B, Ruiz R, Scarlata C, Sluiter J, Templeton D, Crocker D, Laboratory Analytical Procedure, 1617 (2008)
Kim DW, Koriakin A, Lee CH, Fuel, 181, 895 (2016)
Uddin MA, Tsuda H, Wu SJ, Sasaoka E, Fuel, 87(4-5), 451 (2008)
Karimi E, Teixeira IF, Gomez A, de Resende E, Gissane C, Leitch J, Jollet V, Aigner I, Berruti F, Briens C, Fransham P, Hoff B, Schrier N, Lago RM, Kycia SW, Heck R, Schlaf M, Appl. Catal. B: Environ., 145, 187 (2014)
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Lapuerta M, Hernandez JJ, Pazo A, Lopez J, Fuel Process. Technol., 89(9), 828 (2008)
Brage C, Yu QZ, Chen GX, Sjostrom K, Biomass Bioenerg., 18(1), 87 (2000)
Kaneko T, Tazawa K, Koyama T, Satou K, Shimasaki K, Kageyama Y, Energy Fuels, 12(5), 897 (1998)
Ramselaar WLTM, Craje MWJ, Hadders RH, Gerkema E, de Beer VHJ, van der Kraan AM, Appl. Catal., 65, 69 (1990)
Nassar NN, Husein MM, Pereira-Almao P, Fuel Process. Technol., 91(2), 169 (2010)
Poulton SW, Krom MD, Raiswell R, Geochim. Cosmochim. Acta, 68, 3703 (2004)
Lahav O, Ritvo G, Slijper I, Hearne G, Cochva M, Aquaculture, 238, 263 (2004)
