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Received September 20, 2016
Accepted April 10, 2017
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Changes of absorption spectra, SUVA254, and color in treating landfill leachate using microwave-assisted persulfate oxidation
Department of Environmental Engineering, College of Engineering, Kangwon National University, Chuncheon, Gangwon-do 24341, Korea
johnghwa@kangwon.ac.kr
Korean Journal of Chemical Engineering, July 2017, 34(7), 1980-1984(5), 10.1007/s11814-017-0104-3
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Abstract
We experimentally determined the effects of microwave-assisted persulfate oxidation (MAPO) on absorbance spectra, specific ultraviolet absorbance at a wavelength of 254 nm (SUVA254), and color in treating landfill leachate. The effects of treatment temperature (60≤T≤90 °C) and sodium persulfate (SPS) concentration (0.05≤[SPS]≤0.3M) were characterized. An absorbance band in the visible region disappeared after MAPO, but the absorbance in UV region remained. SUVA254 of treated leachate varied from 2.3 to 14.7 L/mg.m. Color number (CN) removal of 99% (CN=0.004 cm-1) was achieved within 30min with MAPO at 80 °C and [SPS =0.2M. As T and [SPS] increased, CN and total organic carbon decreased, but SUVA254 increased.
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Yapsakli K, Cecen F, Process Biochem., 45(3), 355 (2010)
Tizaoui C, Bouselmi L, Mansouri L, Ghrabi A, J. Hazard. Mater., 140(1-2), 316 (2007)
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APHA, Standard methods for the examination of water and wastewater, 22nd Ed., American Public Health Association, Washington, D.C. (2012).
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