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Received February 7, 2017
Accepted April 4, 2017
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Synthesis of colloidal plasmonic microspheres via spontaneous formation and three-dimensional assembly of metal nanoparticles
Department of Chemical and Biomolecular Engineering, Sogang University, Seoul 04107, Korea 1Department of Mechanical Engineering, Sogang University, Seoul 04107, Korea
twkang@sogang.ac.kr
Korean Journal of Chemical Engineering, July 2017, 34(7), 2086-2091(6), 10.1007/s11814-017-0099-9
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Abstract
We report the synthesis of colloidal plasmonic microspheres by taking advantage of emulsions of polydimethylsiloxane (PDMS) in metal precursor solution. Within the emulsion, both the spontaneous formation and threedimensional (3D) assembly of metal nanoparticles take place at room temperature. The number of the nanoparticles being assembled in the microsphere is controllable according to the concentration of a metal precursor. In addition, owing to the surface charge and porosity of PDMS, positively charged and neutral molecules can be more concentrated in the plasmonic microsphere. We use this plasmonic microsphere for the detection of environmentally and biologically important molecules via surface-enhanced Raman spectroscopy, since 3D assembly of metal nanoparticles in the microsphere is size-comparable to a probed volume of incident light.
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O'Brien MN, Jones MR, Lee B, Mirkin CA, Nat. Mater., 14(8), 833 (2015)
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Fan DH, Yuan S, Shen Y, Colloids Surf. B: Biointerfaces, 75, 608 (2010)
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Kim YN, Yoo SH, Cho SO, J. Phys. Chem. C, 113, 618 (2009)
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