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Received February 24, 2017
Accepted April 12, 2017
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Multifunctional human-hair nanocomposites for oxidation of alcohols, aza-Michael reactions and reduction of 2-nitrophenol
Department of Applied Bioscience, College of Life & Environment Science, Konkuk University, 120, Neungdong-ro, Gwangjin-gu, Seoul 05029, Korea
imcim@konkuk.ac.kr, illminchung@gmail.com
Korean Journal of Chemical Engineering, August 2017, 34(8), 2169-2179(11), 10.1007/s11814-017-0113-2
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Abstract
Novel nanocatalysts (Ni/HHP and Ru/HHP) were prepared by a very simple chemical reduction method. Fine human hair powder (HHp) was obtained from raw human hair (HH) by ball milling method. Readily leachable constituents were removed from HHp to obtain HHP. The HHP was employed as support for the decoration Ni and Ru nanoparticles (NPs). Strong interaction between ultrafine NPs and HHP was revealed. Weight percentage of Ru in Ru/HHP and Ni in Ni/HHP was determined to be 39.65% and 26.36%, respectively. Chemical state of nanocatalysts was studied by XPS and XRD analyses. Merit of Ru/HHP and Ni/HHP was realized from its excellent catalytic activity. The Ru/HHP and Ni/HHP worked well for the oxidation and aza-Michael reactions, respectively. Moreover, both Ni/ HHP and Ru/HHP were found to be excellent for the reduction of 2-nitrophenol (2-NP). Reusability, stability and heterogeneity of the catalysts were demonstrated. A mechanism has been proposed for catalytic systems.
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Deng D, Gopiraman M, Kim SH, Chung IM, Kim IS, ACS Sustainable Chem. Eng., 4, 5409 (2016)
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Jin GP, Ding YF, Zheng PP, J. Power Sources, 166(1), 80 (2007)
Velusamy S, Punniyamurthy T, Org. Lett., 6, 217 (2004)
Kockritz A, Sebek M, Dittmar A, Radnik J, Bruckner A, Bentrup U, Pohl MM, Hugl H, Magerlein W, J. Mol. Catal. A-Chem., 246(1-2), 85 (2006)
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Yamaguchi K, Mizuno N, New J. Chem., 26, 972 (2002)
Kantam ML, Laha S, Yadav J, Jha S, Tetrahedron Lett., 50, 4467 (2009)
Ma Z, Wu R, Han Q, Chen R, Gu Z, Korean J. Chem. Eng., 28(3), 717 (2011)
Du Y, Chen R, Korean J. Chem. Eng., 32(9), 1759 (2015)
Hareesh K, Joshi RP, Sunitha DV, Bhoraskar VN, Dhole SD, Appl. Surf. Sci., 389, 1050 (2016)
Yang Y, Ren Y, Sun C, Hao S, Green Chem., 16, 2273 (2014)
Tian Y, Liu Y, Pang F, Wang F, Zhang X, Colloids Surf. A: Physicochem. Eng. Asp., 464, 96 (2015)
Lv JJ, Wang AJ, Ma X, Xiang RY, Chen JR, Feng JJ, J. Mater. Chem., 3, 290 (2015)
