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Received February 20, 2017
Accepted April 18, 2017
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Response surface approach for optimization of Hg(II) adsorption by 3-mercaptopropyl trimethoxysilane-modified kaolin minerals from aqueous solution
Department of Chemical Engineering, Faculty of Engineering, Yuzuncu Yil University, 65080, Van, Turkey 1Department of Chemistry, Faculty of Science, Hacettepe University, 06800, Ankara, Turkey
tsahan@gmail.com
Korean Journal of Chemical Engineering, August 2017, 34(8), 2225-2235(11), 10.1007/s11814-017-0116-z
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Abstract
The optimization of Hg(II) adsorption conditions from aqueous solutions with 3-mercaptopropyl trimethoxysilane- modified kaolin (MMK) used as a new adsorbent was analyzed by response surface methodology (RSM) approach. The MMK adsorbent was characterized by means of energy-dispersive X-ray spectroscopy (EDX), Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD). According to the quadratic model obtained from central composite design (CCD) in RSM, the optimal conditions for adsorption were found to be 30.83mg/L, 0.1 g, 7.44 and 31.41 °C for Co, adsorbent dosage, initial pH, and T (°C), respectively. With the obtained model, the maximum amount of adsorbed Hg(II) and %Hg(II) removed was calculated to be 30.10mg/g and 98.01%, respectively. Langmuir and Dubinin-Radushkevich isotherms fitted well the experimental results. Thermodynamic studies revealed that the adsorption was physical, exothermic, spontaneous. The results indicate that MMK a new adsorbent has great potential for the removal of Hg(II) from aqueous media.
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Fernandez-Nava Y, Ulmanu M, Anger I, Maranon E, Castrillon L, Water Air Soil Pollut., 215, 239 (2011)
Singh J, Huang PM, Hammer UT, Liaw WK, Clay Clay Min., 44, 41 (1996)
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Bezerra MA, Santelli RE, Oliveira EP, Villar LS, Escaleira LA, Talanta, 76, 965 (2008)
Chi GY, Hu SQ, Yang YH, Chen T, Chem. Eng. Res. Des., 90(9), 1235 (2012)
Myers RH, Montgomery DC, Response surface methodology, Wiley, New York (2002).
Murugesan S, Rajiv S, Thanapalan M, Korean J. Chem. Eng., 26(2), 364 (2009)
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Amir MJ, Abedi-Koupai J, Eslamian SS, Arshadi M, Desalin. Water Treat., 57, 16522 (2016)
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Langmuir I, J. Am. Chem. Soc., 40, 1361 (1918)
Freundlich HMF, J. Phys. Chem. A, 57, 385 (1906)
Dubinin MM, Radushkevich LV, Proc. Acad. Sci. Phys. Chem. Sec., 55, 331 (1947)
Yardim MF, Budinova T, Ekinci E, Petrov N, Razvigorova M, Minkova V, Chemosphere, 52, 835 (2003)
Senel S, Kara A, Karabakan A, Denizli A, J. Appl. Polym. Sci., 100(2), 1222 (2006)
Cheng X, Huang XR, Wang XZ, Sun DZ, J. Hazard. Mater., 177(1-3), 516 (2010)
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Shan C, Ma Z, Tong M, Ni J, Water Res., 69, 252 (2015)
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Tran L, Wu PX, Zhu YJ, Liu S, Zhu NW, Appl. Surf. Sci., 356, 91 (2015)
