Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received January 17, 2017
Accepted May 17, 2017
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
Preparation and photocatalytic activity of composite metal oxides derived from Salen-Cu(II) intercalated layered double hydroxides
1College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China 2School of Life Sciences, Huzhou University, Huzhou 313000, China 3School of Engineering, Huzhou University, Huzhou 313000, China
nzm@zjut.edu.cn
Korean Journal of Chemical Engineering, August 2017, 34(8), 2331-2341(11), 10.1007/s11814-017-0135-9
Download PDF
Abstract
Copper(II) Schiff-base Complexes (Salen-Cu(II)) intercalated zinc-chromium layered double hydroxides (ZnSBCuCr-LDHs) were successfully prepared via coprecipitation. Then, a novel photocatalytic material Zn-Cu-Cr composite oxides (ZnSBCuCr-MO) was prepared after calcination at 500 °C with ZnSBCuCr-LDHs as precursor. The structure and properties of the materials were thoroughly characterized by powder X-ray diffraction (XRD), inductively coupled plasma atomic emission spectrometry (ICP-AES), ultraviolet visible diffuse reflectance spectroscopy (UV-Vis DRS), scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). The photocatalytic activities of the materials were investigated by photodegradation of a cationic dye Rhodamin B (RhB), which was hard to adsorb by LDHs. The effects of the photocatalyst dosage, the initial pH and temperature of RhB solution on the photocatalytic efficiency were discussed. The results showed that ZnSBCuCr-MO displayed higher photocatalytic activity for RhB than calcined ZnCr-LDHs (ZnCr-MO) and calcined ZnCuCr-LDHs (ZnCuCr-MO). Meanwhile, ZnSBCuCr- MO exhibited better stability and reusability. In addition, the possible photocatalytic mechanism and degradation pathway for RhB were studied through density functional theory (DFT) calculation of the RhB molecule, UV-vis absorption variation and LC-MS analyses of the RhB solution.
Keywords
References
Sommella A, Caporale AG, Denecke MA, Mangold S, Pigna M, Santoro A, Terzano R, Violante A, J. Hazard. Mater., 300, 504 (2015)
Baliarsingh N, Mohapatra L, Parida K, J. Mater. Chem., 1, 4236 (2013)
Pan GX, Xia XH, Luo JS, Cao F, Yang ZH, Fan HJ, Appl. Clay Sci., 102, 28 (2014)
Timofeeva MN, Kapustin AE, Panchenko VN, Butenko EO, Krupskaya VV, Gil A, Vicente MA, J. Mol. Catal. A-Chem., 423, 22 (2016)
Xu S, Yu JY, Sun YB, Wu SP, Mater. Chem. Phys., 152, 54 (2015)
Shen Y, Zhao X, Zhang X, Li S, Liu D, Fan L, Korean J. Chem. Eng., 33(1), 159 (2016)
Singha S, Sahoo M, Parida KM, Dalton T., 40, 11838 (2011)
Wang YL, Wu PX, Hou YK, Zhu NW, Dang Z, Ind. Eng. Chem. Res., 51(34), 11128 (2012)
Parida KM, Baliarsingh N, Patra BS, Das J, J. Mol. Catal. A-Chem., 267(1-2), 202 (2007)
Schneider J, Matsuoka M, Takeuchi M, Zhang JL, Horiuchi Y, Anpo M, Bahnemann DW, Chem. Rev., 114(19), 9919 (2014)
Yu JG, Wang SH, Low JX, Xiao W, Phys. Chem. Chem. Phys., 15, 16883 (2013)
Yasui K, Isobe T, Nakajima A, Mater. Lett., 64, 2036 (2010)
Zhang LH, Xiong ZG, Li L, Burt R, Zhao XS, J. Colloid Interface Sci., 469, 224 (2016)
Alanis C, Natividad R, Barrera-Diaz C, Martinez-Miranda V, Prince J, Valente JS, Appl. Catal. B: Environ., 140-141, 546 (2013)
Tang XX, Liu Y, Li SH, RSC Adv., 6, 80501 (2016)
Lu NY, Li BJ, Fan BB, Guo WY, Li RF, Mater. Chem. Phys., 167, 219 (2015)
Varga G, Kukovecz A, Konya Z, Korecz L, Murath S, Csendes Z, Peintler G, Carlson S, Sipos P, Palinko I, J. Catal., 335, 125 (2016)
Zhang LJ, Chen YC, Zhang ZM, Lu C, Sens. Actuators B-Chem., 193, 752 (2014)
Xia SJ, Meng Y, Zhou XB, Xue JL, Pan GX, Ni ZM, Appl. Catal. B: Environ., 187, 122 (2016)
Xia SJ, Zhang LY, Zhou XB, Shao MM, Pan GX, Ni ZM, Appl. Catal. B: Environ., 266, 176 (2015)
Yan LG, Yang K, Shan RR, Yan T, Wei J, Yu SJ, Yu HQ, Du B, J. Colloid Interface Sci., 448, 508 (2015)
Li MJ, Yu ZB, Liu Q, Sun L, Huang WY, Chem. Eng. J., 286, 232 (2016)
Xia SJ, Zhang LY, Pan GX, Qian PP, Ni ZM, Phys. Chem. Chem. Phys., 17, 5345 (2015)
Pirzada BM, Mir NA, Qutub N, Mehraj O, Sabir S, Muneer M, Mater. Sci. Eng. B-Solid State Mater. Adv. Technol., 193, 137 (2015)
Li HP, Deng QH, Liu JY, Hou WG, Du N, Zhang RJ, Tao XT, Catal. Sci. Technol., 4, 1028 (2014)
Li F, Yin Y, Jiang DM, J. Mater. Sci., 52(11), 6415 (2017)
Hastir A, Kohli N, Kang OS, Singh RC, J. Electrochem. Soc., 37, 170 (2016)
Lamba R, Umar A, Mehta SK, Kansal SK, Alloys Compd., 653, 327 (2015)
Luo J, Zhou XS, Ma L, Xu XY, J. Mol. Catal. A-Chem., 410, 168 (2015)
Khanchandani S, Kundu S, Patra A, Ganguli AK, J. Phys. Chem. C, 117, 5558 (2013)
Wang SB, Zhu ZH, Dyes Pigm., 75, 306 (2007)
Zhang ZH, Zhai SY, Wang MH, Ji HF, He LH, Ye CM, Wang CB, Fang SM, Zhang HZ, J. Alloy. Compd., 659, 101 (2016)
Hu LX, Chen FY, Hu PF, Zou LP, Hu X, J. Mol. Catal. A-Chem., 411, 203 (2016)
Fang JM, Huang XY, Zhang Q, Chen JH, Wang X, Appl. Surf. Sci., 360, 994 (2016)
Yang XX, Cao CD, Erickson L, Hohn K, Maghirang R, Klabunde K, Appl. Catal. B: Environ., 91(3-4), 657 (2009)
Chen GX, Qian SM, Tu XM, Wei XY, Zou JP, Leng LH, Luo SL, Appl. Surf. Sci., 293, 345 (2014)
Watanabe N, Horikoshi X, Kawabe H, Sugie Y, Zhao JC, Hidaka H, Chemosphere, 52, 851 (2013)
Ohko Y, Iuchi KI, Niwa C, atsuma T, Nakashima T, Lguchi T, Kubota N, Fujishima A, Environ. Sci. Technol., 36, 4175 (2002)
Lee BD, Iso M, Hosomi M, Chemosphere, 42, 431 (2001)
An TC, Yang H, Li GY, Song WH, Cooper WJ, Nie XP, Appl. Catal. B: Environ., 94(3-4), 288 (2010)
He Z, Sun C, Yang SG, Ding YC, He H, Wang ZL, J. Hazard. Mater., 162(2-3), 1477 (2009)
Baliarsingh N, Mohapatra L, Parida K, J. Mater. Chem., 1, 4236 (2013)
Pan GX, Xia XH, Luo JS, Cao F, Yang ZH, Fan HJ, Appl. Clay Sci., 102, 28 (2014)
Timofeeva MN, Kapustin AE, Panchenko VN, Butenko EO, Krupskaya VV, Gil A, Vicente MA, J. Mol. Catal. A-Chem., 423, 22 (2016)
Xu S, Yu JY, Sun YB, Wu SP, Mater. Chem. Phys., 152, 54 (2015)
Shen Y, Zhao X, Zhang X, Li S, Liu D, Fan L, Korean J. Chem. Eng., 33(1), 159 (2016)
Singha S, Sahoo M, Parida KM, Dalton T., 40, 11838 (2011)
Wang YL, Wu PX, Hou YK, Zhu NW, Dang Z, Ind. Eng. Chem. Res., 51(34), 11128 (2012)
Parida KM, Baliarsingh N, Patra BS, Das J, J. Mol. Catal. A-Chem., 267(1-2), 202 (2007)
Schneider J, Matsuoka M, Takeuchi M, Zhang JL, Horiuchi Y, Anpo M, Bahnemann DW, Chem. Rev., 114(19), 9919 (2014)
Yu JG, Wang SH, Low JX, Xiao W, Phys. Chem. Chem. Phys., 15, 16883 (2013)
Yasui K, Isobe T, Nakajima A, Mater. Lett., 64, 2036 (2010)
Zhang LH, Xiong ZG, Li L, Burt R, Zhao XS, J. Colloid Interface Sci., 469, 224 (2016)
Alanis C, Natividad R, Barrera-Diaz C, Martinez-Miranda V, Prince J, Valente JS, Appl. Catal. B: Environ., 140-141, 546 (2013)
Tang XX, Liu Y, Li SH, RSC Adv., 6, 80501 (2016)
Lu NY, Li BJ, Fan BB, Guo WY, Li RF, Mater. Chem. Phys., 167, 219 (2015)
Varga G, Kukovecz A, Konya Z, Korecz L, Murath S, Csendes Z, Peintler G, Carlson S, Sipos P, Palinko I, J. Catal., 335, 125 (2016)
Zhang LJ, Chen YC, Zhang ZM, Lu C, Sens. Actuators B-Chem., 193, 752 (2014)
Xia SJ, Meng Y, Zhou XB, Xue JL, Pan GX, Ni ZM, Appl. Catal. B: Environ., 187, 122 (2016)
Xia SJ, Zhang LY, Zhou XB, Shao MM, Pan GX, Ni ZM, Appl. Catal. B: Environ., 266, 176 (2015)
Yan LG, Yang K, Shan RR, Yan T, Wei J, Yu SJ, Yu HQ, Du B, J. Colloid Interface Sci., 448, 508 (2015)
Li MJ, Yu ZB, Liu Q, Sun L, Huang WY, Chem. Eng. J., 286, 232 (2016)
Xia SJ, Zhang LY, Pan GX, Qian PP, Ni ZM, Phys. Chem. Chem. Phys., 17, 5345 (2015)
Pirzada BM, Mir NA, Qutub N, Mehraj O, Sabir S, Muneer M, Mater. Sci. Eng. B-Solid State Mater. Adv. Technol., 193, 137 (2015)
Li HP, Deng QH, Liu JY, Hou WG, Du N, Zhang RJ, Tao XT, Catal. Sci. Technol., 4, 1028 (2014)
Li F, Yin Y, Jiang DM, J. Mater. Sci., 52(11), 6415 (2017)
Hastir A, Kohli N, Kang OS, Singh RC, J. Electrochem. Soc., 37, 170 (2016)
Lamba R, Umar A, Mehta SK, Kansal SK, Alloys Compd., 653, 327 (2015)
Luo J, Zhou XS, Ma L, Xu XY, J. Mol. Catal. A-Chem., 410, 168 (2015)
Khanchandani S, Kundu S, Patra A, Ganguli AK, J. Phys. Chem. C, 117, 5558 (2013)
Wang SB, Zhu ZH, Dyes Pigm., 75, 306 (2007)
Zhang ZH, Zhai SY, Wang MH, Ji HF, He LH, Ye CM, Wang CB, Fang SM, Zhang HZ, J. Alloy. Compd., 659, 101 (2016)
Hu LX, Chen FY, Hu PF, Zou LP, Hu X, J. Mol. Catal. A-Chem., 411, 203 (2016)
Fang JM, Huang XY, Zhang Q, Chen JH, Wang X, Appl. Surf. Sci., 360, 994 (2016)
Yang XX, Cao CD, Erickson L, Hohn K, Maghirang R, Klabunde K, Appl. Catal. B: Environ., 91(3-4), 657 (2009)
Chen GX, Qian SM, Tu XM, Wei XY, Zou JP, Leng LH, Luo SL, Appl. Surf. Sci., 293, 345 (2014)
Watanabe N, Horikoshi X, Kawabe H, Sugie Y, Zhao JC, Hidaka H, Chemosphere, 52, 851 (2013)
Ohko Y, Iuchi KI, Niwa C, atsuma T, Nakashima T, Lguchi T, Kubota N, Fujishima A, Environ. Sci. Technol., 36, 4175 (2002)
Lee BD, Iso M, Hosomi M, Chemosphere, 42, 431 (2001)
An TC, Yang H, Li GY, Song WH, Cooper WJ, Nie XP, Appl. Catal. B: Environ., 94(3-4), 288 (2010)
He Z, Sun C, Yang SG, Ding YC, He H, Wang ZL, J. Hazard. Mater., 162(2-3), 1477 (2009)
