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Received April 12, 2017
Accepted May 29, 2017
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Synthesis and characterization of poly(ether-block-amide) copolymers/multi-walled carbon nanotube nanocomposite membranes for CO2/CH4 separation
Research and Technology Center of Membrane Processes, Chemical Engineering Department, Iran University of Science and Technology (IUST), Narmak, Tehran, Iran
torajmohammadi@iust.ac.ir
Korean Journal of Chemical Engineering, September 2017, 34(9), 2459-2470(12), 10.1007/s11814-017-0152-8
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Abstract
One of the effective techniques for improving separation properties of polymeric membranes is incorporation of suitable nanoparticles into their matrices. This study presents the preparation of three types of nanocomposite membranes comprising three grades of poly (ether-block-amide) (Pebax 1074, Pebax 1657 and Pebax 2533) and modified multi-walled carbon nanotubes (MWCNTs) with different loadings (1, 1.5, 2 and 2.5 wt%). The prepared membranes were characterized by field emission scanning electron microscopy (FESEM), attenuated total reflection-Fourier transfer infrared spectroscopy (ATR-FTIR) and X-ray diffraction (XRD). Permeation of CO2 and CH4 gases through the prepared membranes was measured at the pressure range of 2-8 bars and 25 °C. The results showed that the incorporation of MWCNTs into the polymers matrices improves CO2/CH4 selectivity. Further, Pebax 1074/MWCNT nanocomposite membrane exhibits better performance for CO2/CH4 separation compared to the neat Pebax and the two other nanocomposite membranes.
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Jomekian A, Behbahani RM, Mohammadi T, Kargari A, J. Nat. Gas. Sci. Eng., 31, 562 (2016)
Feng SC, Ren JZ, Hua KS, Li H, Ren XL, Deng MC, Sep. Purif. Technol., 116, 25 (2013)
Mahmoudi A, Asghari M, Zargar V, J. Ind. Eng. Chem., 23, 238 (2015)
Fonseca A, Reijerkerk S, Potreck J, Nijmeijer K, Mekhalif Z, Delhalle J, Desalination, 250(3), 1150 (2010)
Adewole JK, Ahmad AL, Korean J. Chem. Eng., 33(10), 2998 (2016)
Ravanchi MT, Sahebdelfar S, Zangeneh FT, Front. Chem. Sci. Eng., 5, 173 (2011)
Yave W, Car A, Peinemann KV, J. Membr. Sci., 350(1-2), 124 (2010)
Car A, Stropnik C, Yave W, Peinemann KV, Sep. Purif. Technol., 62(1), 110 (2008)
Azizi N, Mohammadi T, Behbahani RM, J. Energy Chem., (2017).
Robeson LM, J. Membr. Sci., 62, 165 (1991)
Robeson LM, J. Membr. Sci., 320(1-2), 390 (2008)
Robeson LM, Freeman BD, Paul DR, Rowe BW, J. Membr. Sci., 341(1-2), 178 (2009)
Semsarzadeh MA, Ghalei B, Fardi M, Esmaeeli M, Vakili E, Korean J. Chem. Eng., 31(5), 841 (2014)
Peng FB, Lu LY, Sun HL, Wang YQ, Wu H, Jiang ZY, J. Membr. Sci., 275(1-2), 97 (2006)
Sadeghi M, Afarani HT, Tarashi Z, Korean J. Chem. Eng., 32(1), 97 (2015)
Zhao D, Ren J, Li H, Hua K, Deng M, J. Energy Chem., 23, 227 (2014)
Lin H, Freeman BD, J. Mol. Struct., 739, 57 (2005)
Azizi N, Mohammadi T, Behbahani RM, J. Nat. Gas. Sci. Eng., 37, 39 (2017)
Jomekian A, Behbahani RM, Mohammadi T, Kargari A, Korean J. Chem. Eng., 34(2), 440 (2017)
Kim S, Chen L, Johnson JK, Marand E, J. Membr. Sci., 294(1-2), 147 (2007)
Akhtar FH, Kumar M, Peinemann KV, J. Membr. Sci., 525, 187 (2017)
Zhao D, Ren JZ, Wang Y, Qiu YT, Li H, Hua KS, Li XX, Ji JM, Deng MC, J. Membr. Sci., 521, 104 (2017)
Jomekian A, Bazooyar B, Behbahani RM, Mohammadi T, Kargari A, J. Membr. Sci., 524, 652 (2017)
Molyanyan E, Aghamiri S, Talaie MR, Iraji N, Int. J. Environ. Sci. Technol., 13, 2001 (2016)
Tsai YC, Huang JD, Electrochem. Commun., 8, 956 (2006)
Es’haghi Z, Golsefidi MA, Saify A, Tanha AA, Rezaeifar Z, Alian-Nezhadi Z, J. Chromatogr. A, 1217, 2768 (2010)
Shen J, Huang W, Wu L, Hu Y, Ye M, Mater. Sci. Eng. A-Struct. Mater. Prop. Microstruct. Process., 464, 151 (2007)
Azizi N, Mohanunadi T, Behbahani RM, Chem. Eng. Res. Des., 117, 177 (2017)
Isanejad M, Azizi N, Mohammadi T, J. Appl. Polym. Sci., 134 (2017)
Mahdavi HR, Azizi N, Mohammadi T, J. Polym. Res., 24 (2017)
Stern SA, J. Polym. Sci. A: Polym. Chem., 6, 1933 (1968)
Kim JH, Lee YM, J. Membr. Sci., 193(2), 209 (2001)
Ismail AF, Khulbe KC, Matsuura T, Gas Separation Membranes: Polymeric and Inorganic, Springer International Publishing, Cham (2015).
Sridhar S, Suryamurali R, Smitha B, Aminabhavi TM, Colloids Surf. A: Physicochem. Eng. Asp., 297, 267 (2007)
Sridhar S, Smitha B, Suryamurali R, Aminabhavi TM, Des. Monomers Polym., 11, 17 (2008)
Murali RS, Ismail AF, Rahman MA, Sridhar S, Sep. Purif. Technol., 129, 1 (2014)
Murali RS, Sridhar S, Sankarshana T, Ravikumar YVL, Ind. Eng. Chem. Res., 49(14), 6530 (2010)
Zaheri P, Mohammadi T, Abolghasemi H, Maraghe MG, Chem. Eng. Res. Des., 100, 81 (2015)
Ghadimi A, Amirilargani M, Mohammadi T, Kasiri N, Sadatnia B, J. Membr. Sci., 458, 14 (2014)
Rabiee H, Ghadimi A, Abbasi S, Mohammadi T, Chem. Eng. Res. Des., 98, 96 (2015)
Ehsani A, Pakizeh M, J. Taiwan. Instit. Chem. Eng., 66, 414 (2016)
Choi MC, Jung JY, Yeom HS, Chang YW, Polym. Eng. Sci., 53(5), 982 (2013)
Nafisi V, Hagg MB, J. Membr. Sci., 459, 244 (2014)
Yu B, Cong HL, Li ZJ, Tang JG, Zhao XS, J. Appl. Polym. Sci., 130(4), 2867 (2013)
Zhao D, Ren JZ, Li H, Li XX, Deng MC, J. Membr. Sci., 467, 41 (2014)
Rezakazemi M, Vatani A, Mohammadi T, RSC Adv., 5, 82460 (2015)
Rabiee H, Alsadat SM, Soltanieh M, Mousavi SA, Ghadimi A, J. Ind. Eng. Chem., 27, 223 (2015)
Cong HL, Zhang JM, Radosz M, Shen YQ, J. Membr. Sci., 294(1-2), 178 (2007)
Wang SF, Liu Y, Huang SX, Wu H, Li YF, Tian ZZ, Jiang ZY, J. Membr. Sci., 460, 62 (2014)
Ge L, Zhu Z, Li F, Liu S, Wang L, Tang X, Rudolph V, J. Phys. Chem., 115, 6661 (2011)
Habibzare S, Asghari M, Djirsarai A, Int. J. Nano. Dimension, 5, 247 (2014)
Rabiee H, Ghadimi A, Mohammadi T, J. Membr. Sci., 476, 286 (2015)
Van Krevelen DW, Nijenhuis KT, Properties of Polymers, Elsevier, Amsterdam (2009).
Jomekian A, Behbahani RM, Mohammadi T, Kargari A, J. Nat. Gas. Sci. Eng., 31, 562 (2016)
Feng SC, Ren JZ, Hua KS, Li H, Ren XL, Deng MC, Sep. Purif. Technol., 116, 25 (2013)
Mahmoudi A, Asghari M, Zargar V, J. Ind. Eng. Chem., 23, 238 (2015)
Fonseca A, Reijerkerk S, Potreck J, Nijmeijer K, Mekhalif Z, Delhalle J, Desalination, 250(3), 1150 (2010)
