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Received February 14, 2017
Accepted May 29, 2017
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Synthesis and characterization of physicochemical properties of hydrophilic imidazolium-based ionic liquids
Department of Chemistry, Amirkabir University of Technology, Tehran, Iran 1Research Institute of Petroleum Industry, Tehran, Iran
Korean Journal of Chemical Engineering, September 2017, 34(9), 2527-2535(9), 10.1007/s11814-017-0150-x
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Abstract
A series of ionic liquids based on Octyl and Decyl methylimidazolium with different anions such as chloride, glycinate, dihydrogen phosphate and trihydrogen diphosphate, were synthesized and characterized by 1HNMR and elemental analysis. IL containing trihydrogen diphosphate anion, was synthesized for the first time. Physicochemical properties, including density, viscosity, surface tension, refractive index, and pH, were measured in temperature range 283.15 to 363.15 K and atmospheric pressure. The effects of temperature, alkyl chain, and anion type on physicochemical properties were investigated. The results revealed that the physicochemical properties decreased as a function of temperature. Unlike viscosity, other properties, such as density, surface tension, refractive index and pH values, decreased, while alkyl chain length increased. Understanding ILs properties and determining their unique abilities helps researchers to use them in new applications. These long alkyl chain ILs, are being used as surfactants to reduce Oil/Water interfacial tension in EOR process.
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References
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Hou YC, Ren YH, Peng W, Ren SH, Wu WZ, Ind. Eng. Chem. Res., 52(50), 18071 (2013)
Torimoto T, Tsuda T, Okazaki K, Kuwabata S, Adv. Mater., 22(11), 1196 (2010)
Smiglak M, Pringle JM, Lu X, Han L, Zhang S, Gao H, MacFarlane DR, Rogers RD, Chem. Commun., 50, 9228 (2014)
Plechkova NV, Seddon KR, Chem. Soc. Rev., 37, 123 (2008)
Wei1 D, Ivaska A, Anal. Chim. Acta, 607, 126 (2008)
Armand M, Endres F, MacFarlane DR, Ohno H, Scrosati B, Nat. Mater., 8(8), 621 (2009)
Hallett JP, Welton T, Chem. Rev., 111(5), 3508 (2011)
Han D, Row KH, Molecules, 15, 2405 (2010)
Olivier-Bourbigou H, Magna L, Morvan D, Appl. Catal. A: Gen., 373(1-2), 1 (2010)
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Demir S, Damarhan Y, Ozdemir I, J. Mol. Liq., 204, 210 (2015)
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Claros M, Galleguillos HR, Brito I, Graber TA, J. Chem. Eng. Data, 57(8), 2147 (2012)
Seddon KR, Stark A, Torr MJ, ACS Symp. Ser., 819, 34 (2002)
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Sanchez LG, Espel JR, Onink F, Meindersma GW, de Haan AB, J. Chem. Eng. Data, 54(10), 2803 (2009)
Moosavi M, Khashei F, Sharifi A, Mirzaei M, J. Chem. Thermodyn., 107, 1 (2017)
Ghatee MH, Zolghadr AR, Fluid Phase Equilib., 263(2), 168 (2008)
