Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received February 8, 2017
Accepted October 2, 2017
- This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
High performance removal of methyl mercaptan on metal modified activated carbon
College of Science, China University of Petroleum (Beijing), Beijing 102249, China
keming@cup.edu.cn
Korean Journal of Chemical Engineering, January 2018, 35(1), 137-146(10), 10.1007/s11814-017-0272-1
Download PDF
Abstract
A series of coconut shell activated carbon catalysts, modified by metal oxides, were prepared by an ultrasound- assisted incipient wetness method for the removal of methyl mercaptan (CH3SH). The catalysts were investigated using XRD, BET, XPS, TEM and TA.The results showed that the catalyst combined with 2wt% Fe loading and iron (Fe) : copper (Cu) (mole ratio) 10 : 3, and calcination at 300 °C had a superior removal efficiency. The high activity could be attributed to the generation of highly dispersed Fe-Cu nanocomposites. The results revealed that calcination temperature not only influenced the chemical states and nanocomposite size of iron and copper, but also affected the pore structures of the catalysts. Compared with Fe/AC, the interaction between the iron and copper oxides resulted in smaller nanoparticles and high dispersion for Fe-Cu/AC. Product analysis results suggested dimethyl disulfide, metal methanesulfonates and methyl thiolates were the oxidation products which adsorbed on the activated carbon.
References
Ding L, Liu TX, Li XZ, J. Chem. Technol. Biotechnol., 89(3), 455 (2014)
Iliuta MC, Larachi F, J. Chem. Data, 52, 2 (2007)
Whelan ME, Min D, Rhew RC, Atmos. Environ., 73, 131 (2013)
Wu T, Wang X, Li D, Yi Z, Atmos. Environ., 44, 5065 (2010)
Liu ZT, Zhou JL, Zhang BJ, J. Mol. Catal., 94, 255 (1994)
Cai W, Lu G, He J, Lan Y, Ceram. Int., 38, 3167 (2012)
Cammarano C, Huguet E, Cadours R, Leroi C, Coq B, Hulea V, Appl. Catal. B: Environ., 156-157, 128 (2014)
Conti-Ramsden MG, Nkrumah-Amoako K, Brown NW, Roberts EPL, Adsorption, 19, 989 (2013)
Huguet E, Coq B, Durand R, Leroi C, Cadours R, Hulea V, Appl. Catal. B: Environ., 134-135, 344 (2013)
van Leerdam RC, van den Bosch PLF, Lens PNL, Janssen AJH, Environ. Sci. Technol., 45, 1320 (2011)
Bagreev A, Menendez JA, Dukhno I, Tarasenko Y, Bandosz TJ, Carbon, 43, 208 (2005)
Bashkova S, Bagreev A, Bandosz TJ, Environ. Sci. Technol., 36, 2777 (2002)
Katoh H, Kuniyoshi I, Hirai M, Shoda M, Appl. Catal. B: Environ., 6(3), 255 (1995)
Cui H, Turn SQ, Appl. Catal. B: Environ., 88(1-2), 25 (2009)
Liu XL, Guo JX, Chu YH, Luo DM, Yin HQ, Sun MC, Yavuz R, Fuel, 123, 93 (2014)
Bashkova S, Bagreev A, Bandosz TJ, Langmuir, 19(15), 6115 (2003)
Kim DJ, Yie JE, J. Colloid Interface Sci., 283(2), 311 (2005)
Laosiripojana N, Sutthisripok W, Charojrochkul S, Assabumrungrat S, Appl. Catal. A: Gen., 478, 9 (2014)
Lee SW, Daud WMAW, Lee MG, J. Ind. Eng. Chem., 16(6), 973 (2010)
Tamai H, Nagoya H, Shiono T, J. Colloid Interface Sci., 300(2), 814 (2006)
Vega E, Lemus J, Anfruns A, Gonzalez-Olmos R, Palomar J, Martin MJ, J. Hazard. Mater., 258-259, 77 (2013)
Zhao S, Yi H, Tang X, Gao F, Zhang B, Wang Z, Zuo Y, J. Clean Prod., 87, 856 (2015)
Wang X, Qiu J, Ning P, Ren X, Li Z, Yin Z, Chen W, Liu W, J. Hazard. Mater., 229-230, 128 (2012)
Yi H, Li K, Tang X, Ning P, Peng J, Wang C, He D, J. Chem. Eng., 230, 220 (2013)
Zhang T, Liu J, Wang D, Zhao Z, Wei Y, Cheng K, Jiang G, Duan A, Appl. Catal. B: Environ., 148-149, 520 (2014)
Bashkova S, Bagreev A, Bandosz TJ, Catal. Today, 99(3-4), 323 (2005)
He D, Yi HH, Tang XL, Ning P, Li K, Wang HY, Zhao SZ, J. Mol. Catal. A-Chem., 357, 44 (2012)
Guo JX, Liu XL, Luo DM, Yin HQ, Li JJ, Chu YH, Ind. Eng. Chem. Res., 54(4), 1261 (2015)
Cui Z, Fan J, Duan H, Zhang J, Xue Y, Tan Y, Korean J. Chem. Eng., 34(1), 29 (2017)
Rey A, Faraldos M, Casas JA, Zazo JA, Bahamonde A, Rodriguez JJ, Appl. Catal. B: Environ., 86(1-2), 69 (2009)
Descostes M, Mercier F, Thromat N, Beaucaire C, Gautier-Soyer M, Appl. Surf. Sci., 165(4), 288 (2000)
Zhang GQ, Li Z, Zheng HY, Fu TJ, Ju YB, Wang YC, Appl. Catal. B: Environ., 179, 95 (2015)
Hu Zhong-Pan, Zhu Yun-Pei, Gao Ze-Min, Wang Guoxiong, Liu Yuping, Liu Xinying, Yuan Zhong-Yong, Chem. Eng. J., 302, 23 (2016)
Benassi R, Theor. Chem. Acc., 112, 95 (2004)
Castner DG, Hinds K, Grainger DW, Langmuir, 12(21), 5083 (1996)
Mullins DR, McDonald TS, Surf. Sci., 602, 1280 (2008)
Rufael TS, Huntley DR, Mullins DR, Gland JL, J. Phys. Chem. B, 102(18), 3431 (1998)
Lin YH, Tseng TK, Chu H, Appl. Catal. A: Gen., 469, 221 (2014)
Adib F, Bagreev A, Bandosz TJ, J. Colloid Interface Sci., 214(2), 407 (1999)
Adib F, Bagreev A, Bandosz TJ, Environ. Sci. Technol., 34, 686 (2000)
Bagreev A, Menendez JA, Dukhno I, Tarasenko Y, Bandosz TJ, Carbon, 42, 469 (2004)
Wang M, Wang ZC, Sun ZL, Jiang H, React. Kinet. Catal. Lett., 84(2), 223 (2005)
Wang M, Song ZG, Jiang H, Gong H, J. Therm. Anal. Calorim., 98, 801 (2009)
Wu Z, Dreisinger DB, Urch H, Fassbender S, Hydrometallurgy, 142, 121 (2014)
Iliuta MC, Larachi F, J. Chem. Data, 52, 2 (2007)
Whelan ME, Min D, Rhew RC, Atmos. Environ., 73, 131 (2013)
Wu T, Wang X, Li D, Yi Z, Atmos. Environ., 44, 5065 (2010)
Liu ZT, Zhou JL, Zhang BJ, J. Mol. Catal., 94, 255 (1994)
Cai W, Lu G, He J, Lan Y, Ceram. Int., 38, 3167 (2012)
Cammarano C, Huguet E, Cadours R, Leroi C, Coq B, Hulea V, Appl. Catal. B: Environ., 156-157, 128 (2014)
Conti-Ramsden MG, Nkrumah-Amoako K, Brown NW, Roberts EPL, Adsorption, 19, 989 (2013)
Huguet E, Coq B, Durand R, Leroi C, Cadours R, Hulea V, Appl. Catal. B: Environ., 134-135, 344 (2013)
van Leerdam RC, van den Bosch PLF, Lens PNL, Janssen AJH, Environ. Sci. Technol., 45, 1320 (2011)
Bagreev A, Menendez JA, Dukhno I, Tarasenko Y, Bandosz TJ, Carbon, 43, 208 (2005)
Bashkova S, Bagreev A, Bandosz TJ, Environ. Sci. Technol., 36, 2777 (2002)
Katoh H, Kuniyoshi I, Hirai M, Shoda M, Appl. Catal. B: Environ., 6(3), 255 (1995)
Cui H, Turn SQ, Appl. Catal. B: Environ., 88(1-2), 25 (2009)
Liu XL, Guo JX, Chu YH, Luo DM, Yin HQ, Sun MC, Yavuz R, Fuel, 123, 93 (2014)
Bashkova S, Bagreev A, Bandosz TJ, Langmuir, 19(15), 6115 (2003)
Kim DJ, Yie JE, J. Colloid Interface Sci., 283(2), 311 (2005)
Laosiripojana N, Sutthisripok W, Charojrochkul S, Assabumrungrat S, Appl. Catal. A: Gen., 478, 9 (2014)
Lee SW, Daud WMAW, Lee MG, J. Ind. Eng. Chem., 16(6), 973 (2010)
Tamai H, Nagoya H, Shiono T, J. Colloid Interface Sci., 300(2), 814 (2006)
Vega E, Lemus J, Anfruns A, Gonzalez-Olmos R, Palomar J, Martin MJ, J. Hazard. Mater., 258-259, 77 (2013)
Zhao S, Yi H, Tang X, Gao F, Zhang B, Wang Z, Zuo Y, J. Clean Prod., 87, 856 (2015)
Wang X, Qiu J, Ning P, Ren X, Li Z, Yin Z, Chen W, Liu W, J. Hazard. Mater., 229-230, 128 (2012)
Yi H, Li K, Tang X, Ning P, Peng J, Wang C, He D, J. Chem. Eng., 230, 220 (2013)
Zhang T, Liu J, Wang D, Zhao Z, Wei Y, Cheng K, Jiang G, Duan A, Appl. Catal. B: Environ., 148-149, 520 (2014)
Bashkova S, Bagreev A, Bandosz TJ, Catal. Today, 99(3-4), 323 (2005)
He D, Yi HH, Tang XL, Ning P, Li K, Wang HY, Zhao SZ, J. Mol. Catal. A-Chem., 357, 44 (2012)
Guo JX, Liu XL, Luo DM, Yin HQ, Li JJ, Chu YH, Ind. Eng. Chem. Res., 54(4), 1261 (2015)
Cui Z, Fan J, Duan H, Zhang J, Xue Y, Tan Y, Korean J. Chem. Eng., 34(1), 29 (2017)
Rey A, Faraldos M, Casas JA, Zazo JA, Bahamonde A, Rodriguez JJ, Appl. Catal. B: Environ., 86(1-2), 69 (2009)
Descostes M, Mercier F, Thromat N, Beaucaire C, Gautier-Soyer M, Appl. Surf. Sci., 165(4), 288 (2000)
Zhang GQ, Li Z, Zheng HY, Fu TJ, Ju YB, Wang YC, Appl. Catal. B: Environ., 179, 95 (2015)
Hu Zhong-Pan, Zhu Yun-Pei, Gao Ze-Min, Wang Guoxiong, Liu Yuping, Liu Xinying, Yuan Zhong-Yong, Chem. Eng. J., 302, 23 (2016)
Benassi R, Theor. Chem. Acc., 112, 95 (2004)
Castner DG, Hinds K, Grainger DW, Langmuir, 12(21), 5083 (1996)
Mullins DR, McDonald TS, Surf. Sci., 602, 1280 (2008)
Rufael TS, Huntley DR, Mullins DR, Gland JL, J. Phys. Chem. B, 102(18), 3431 (1998)
Lin YH, Tseng TK, Chu H, Appl. Catal. A: Gen., 469, 221 (2014)
Adib F, Bagreev A, Bandosz TJ, J. Colloid Interface Sci., 214(2), 407 (1999)
Adib F, Bagreev A, Bandosz TJ, Environ. Sci. Technol., 34, 686 (2000)
Bagreev A, Menendez JA, Dukhno I, Tarasenko Y, Bandosz TJ, Carbon, 42, 469 (2004)
Wang M, Wang ZC, Sun ZL, Jiang H, React. Kinet. Catal. Lett., 84(2), 223 (2005)
Wang M, Song ZG, Jiang H, Gong H, J. Therm. Anal. Calorim., 98, 801 (2009)
Wu Z, Dreisinger DB, Urch H, Fassbender S, Hydrometallurgy, 142, 121 (2014)