ISSN: 0256-1115 (print version) ISSN: 1975-7220 (electronic version)
Copyright © 2024 KICHE. All rights reserved

Articles & Issues

Language
English
Conflict of Interest
In relation to this article, we declare that there is no conflict of interest.
Publication history
Received March 14, 2017
Accepted September 6, 2017
articles This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.

All issues

Surface functionalized carbon microspheres for the recovery of copper ion from refinery wastewater

1Department of Chemical Engineering, The Petroleum Institute, Abu Dhabi, United Arab Emirates 2Department of Mechanical Engineering, National Institute of Technical Teachers’ Training and Research (NITTTR) Kolkata, Sector III, Block FC, Salt Lake City, Kolkata 700106, West Bengal, India 3Department of Chemical Engineering, Khalifa University of Science & Technology, Abu Dhabi, United Arab Emirates
Korean Journal of Chemical Engineering, January 2018, 35(1), 147-152(6), 10.1007/s11814-017-0245-4
downloadDownload PDF

Abstract

Micro-sized carbon spheres (CNS) were synthesized by hydrothermal process from glucose solution at 443.15 K and two different reaction times. The synthesized CNS samples were surface functionalized with hydroxyl (- OH) functional groups using NaOH treatment, and were tested in batch adsorption to remove heavy metal ion (Cu2+) from aqueous solutions. Experimental results revealed that CNS contains mostly amorphous carbon. NaOH functionalized CNS had significantly higher adsorption capacity of copper ~170×10 -3 Kg Cu2+/Kg-CNS as compared to the untreated CNS. The adsorption isotherms were well fitted by the Langmuir isotherm equation. The surface morphology of the native and functionalized CNS samples was characterized by a number of techniques and based on which the adsorption of copper ion was discussed.

References

Agrawal A, Sahu KK, Pandey BD, AIChE J., 50(10), 2430 (2004)
Cay S, Uyanik A, Ozasik A, Sep. Purif. Technol., 38(3), 273 (2004)
Bayat B, J. Hazard. Mater., 95(3), 251 (2002)
Alslaibi TM, Abustan I, Ahmad MA, Abu Foul A, Desalination Water Treatment, 52, 7887 (2014)
Araujo DM, Yoshida MI, Stapelfeldt F, Carvalho CF, Donnici CL, Kastner GF, Rem-Revista Escola De Minas, 62, 463 (2009)
Biniak S, Pakula M, Szymanski GS, Swiatkowski A, Langmuir, 15(18), 6117 (1999)
Chen JP, Wu S, J. Colloid Interface Sci., 280(2), 334 (2004)
Chen JP, Wu SN, Chong KH, Carbon, 41, 1979 (2003)
Chen XC, Chen GC, Chen LG, Chen YX, Lehmann J, McBride MB, Hay AG, Bioresour. Technol., 102(19), 8877 (2011)
Chowdhury ZZ, Zain SM, Khan RA, Islam MS, Korean J. Chem. Eng., 29(9), 1187 (2012)
Han RP, Zhang LJ, Song C, Zhang MM, Zhu HM, Carbohydr. Polym., 79, 1140 (2010)
Aydın H, Bulut Y, Yerlikaya C, J. Environ. Manage., 87, 37 (2008)
Demiral H, Gungor C, J. Clean Prod., 124, 103 (2016)
Divrikli U, Kartal AA, Soylak M, Elci L, J. Hazard. Mater., 145(3), 459 (2007)
Jia YF, Steele CJ, Hayward IP, Thomas KM, Carbon, 36, 1299 (1998)
Cantuaria ML, Neto AFD, Nascimento ES, Vieira MGA, J. Clean Prod., 112, 1112 (2016)
Ozdes D, Gundogdu A, Kemer B, Duran C, Senturk HB, Soylak M, J. Hazard. Mater., 166(2-3), 1480 (2009)
Tuzen M, Soylak M, J. Hazard. Mater., 164(2-3), 1428 (2009)
Song XH, Wang YB, Wang KA, Xu R, Ind. Eng. Chem. Res., 51(41), 13438 (2012)
Frusteri L, Cannilla C, Bonura G, Chuvilin AL, Perathoner S, Centi G, Frusteri F, Catal. Today, 277, 68 (2016)
Frusteri L, Cannilla C, Barbera K, Perathoner S, Centi G, Frusteri F, Carbon, 59, 296 (2013)
Sun X, Sun XM, Li YD, Angew. Chem.-Int. Edit., 43, 597 (2004)
Song XH, Gunawan P, Jiang RR, Leong SSJ, Wang KA, Xu R, J. Hazard. Mater., 194, 162 (2011)
Wang K. Mondal S, Derebe AT, J. Chem. Eng. Res. Updates, 1, 35 (2014)
Puvvada N, Kumar BP, Konar S, Kalita H, Mandal M, Pathak A, Sci. Technol. Adv. Mater., 13, 045008 (2012)
Ilie A, Durkan C, Milne WI, Welland ME, Phys. Rev. B, 66, 045412 (2002)
Do DD, Adsorption analysis: Equilibria and kinetics, Imperial College Press (1998).
Colthup NB, Daly LH, Wiberley SE, Introduction to infrared and Raman spectroscopy, Elsevier (1990).
Novak I, Sysel P, Zemek J, Spirkova M, Velic D, Aranyosiova M, Florian S, Pollak V, Kleinova A, Lednicky F, Janigova I, European Polym. J., 45, 57 (2009)
Xuguang S, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 62, 557 (2005)
Yao C, Shin Y, Wang LQ, Windisch CF, Samuels WD, Arey BW, Wang C, Risen WM, Exarhos GJ, J. Phys. Chem., 111, 15141 (2007)
Shin S, Jang J, Yoon SH, Mochida I, Carbon, 35, 1739 (1997)
Joule JA, Mills K, Heterocyclic Chemistry, Wiley (2010).
Atamanenko I, Kryvoruchko A, Yurlova L, Tsapiuk E, Desalination, 147(1-3), 257 (2002)
Guan XH, Chen GH, Shang C, J. Environ. Sci., 19, 438 (2007)
Demir-Cakan R, Baccile N, Antonietti M, Titirici MM, Chem. Mater., 21, 484 (2009)
Afkhami A, Madrakian T, Karimi Z, Amini A, Colloids Surf. A: Physicochem. Eng. Asp., 304, 36 (2007)
Pendleton P, Wu SH, Badalyan A, J. Colloid Interface Sci., 246(2), 235 (2002)
Wang J, Yin X, Tang W, Ma H, Korean J. Chem. Eng., 32(9), 1889 (2015)
Barakat MA, Arabian J. Chem, 4, 361 (2011)
Wang XB, Liu J, Xu WZ, Colloids Surf. A: Physicochem. Eng. Asp., 415, 288 (2012)
Dos Santos VCG, De Souza J, Tarley CRT, Caetano J, Dragunski DC, Water Air Soil Pollut., 216, 351 (2011)
Ulmanu M, Maranon E, Fernandez Y, Castrillon L, Anger I, Dumitriu D, Water Air Soil Pollut., 142, 357 (2003)
Lopez F, Martın M, Perez C, Lopez-Delgado A, Alguacil F, Water Res., 37, 3883 (2003)
Karabulut S, Karabakan A, Denizli A, Yurum Y, Sep. Purif. Technol., 18(3), 177 (2000)
Lopez-Delgado A, Perez C, Lopez F, Water Res., 32, 989 (1998)
Song X, Li C, Xu R, Wang K, Ind. Eng. Chem. Res., 51(34), 11261 (2012)
Peric J, Trgo M, Medvidovic NV, Water Res., 38, 1893 (2004)

The Korean Institute of Chemical Engineers. F5, 119, Anam-ro, Seongbuk-gu, 233 Spring Street Seoul 02856, South Korea.
TEL. No. +82-2-458-3078FAX No. +82-507-804-0669E-mail : kiche@kiche.or.kr

Copyright (C) KICHE.all rights reserved.

- Korean Journal of Chemical Engineering 상단으로