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Received March 14, 2017
Accepted September 6, 2017
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Surface functionalized carbon microspheres for the recovery of copper ion from refinery wastewater
1Department of Chemical Engineering, The Petroleum Institute, Abu Dhabi, United Arab Emirates 2Department of Mechanical Engineering, National Institute of Technical Teachers’ Training and Research (NITTTR) Kolkata, Sector III, Block FC, Salt Lake City, Kolkata 700106, West Bengal, India 3Department of Chemical Engineering, Khalifa University of Science & Technology, Abu Dhabi, United Arab Emirates
Korean Journal of Chemical Engineering, January 2018, 35(1), 147-152(6), 10.1007/s11814-017-0245-4
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Abstract
Micro-sized carbon spheres (CNS) were synthesized by hydrothermal process from glucose solution at 443.15 K and two different reaction times. The synthesized CNS samples were surface functionalized with hydroxyl (- OH) functional groups using NaOH treatment, and were tested in batch adsorption to remove heavy metal ion (Cu2+) from aqueous solutions. Experimental results revealed that CNS contains mostly amorphous carbon. NaOH functionalized CNS had significantly higher adsorption capacity of copper ~170×10 -3 Kg Cu2+/Kg-CNS as compared to the untreated CNS. The adsorption isotherms were well fitted by the Langmuir isotherm equation. The surface morphology of the native and functionalized CNS samples was characterized by a number of techniques and based on which the adsorption of copper ion was discussed.
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Jia YF, Steele CJ, Hayward IP, Thomas KM, Carbon, 36, 1299 (1998)
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Demir-Cakan R, Baccile N, Antonietti M, Titirici MM, Chem. Mater., 21, 484 (2009)
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Barakat MA, Arabian J. Chem, 4, 361 (2011)
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Dos Santos VCG, De Souza J, Tarley CRT, Caetano J, Dragunski DC, Water Air Soil Pollut., 216, 351 (2011)
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Lopez-Delgado A, Perez C, Lopez F, Water Res., 32, 989 (1998)
Song X, Li C, Xu R, Wang K, Ind. Eng. Chem. Res., 51(34), 11261 (2012)
Peric J, Trgo M, Medvidovic NV, Water Res., 38, 1893 (2004)
