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Received April 18, 2017
Accepted August 15, 2017
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Cu/ZnO/AlOOH catalyst for methanol synthesis through CO2 hydrogenation
EunGyoung Choi1 2
KyoungHo Song1 2
SoRa An1 2
KwanYoung Lee2
MinHyeh Youn1
KiTae Park1
SoonKwan Jeong1
HakJoo Kim1†
1Greenhouse Gas Research Laboratory, Korea Institute of Energy Research, Daejeon 34129, Korea 2Department of Chemical and Biological Engineering, Korea University, Seoul 02841, Korea
hakjukim@kier.re.kr
Korean Journal of Chemical Engineering, January 2018, 35(1), 73-81(9), 10.1007/s11814-017-0230-y
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Abstract
Catalytic conversion of CO2 to methanol is gaining attention as a promising route to using carbon dioxide as a new carbon feedstock. AlOOH supported copper-based methanol synthesis catalyst was investigated for direct hydrogenation of CO2 to methanol. The bare AlOOH catalyst support was found to have increased adsorption capacity of CO2 compared to conventional Al2O3 support by CO2 temperature-programmed desorption (TPD) and FT-IR analysis. The catalytic activity measurement was carried out in a fixed bed reactor at 523 K, 30 atm and GHSV 6,000 hr.1 with the feed gas of CO2/H2 ratio of 1/3. The surface basicity of the AlOOH supported Cu-based catalysts increased linearly according to the amount of AlOOH. The optimum catalyst composition was found to be Cu : Zn : Al=40 : 30 : 30 at%. A decrease of methanol productivity was observed by further increasing the amount of AlOOH due to the limitation of hydrogenation rate on Cu sites. The AlOOH supported catalyst with optimum catalyst compositions was slightly more active than the conventional Al2O3 supported Cu-based catalyst.
Keywords
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Li D, Ichikuni N, Shimazu S, Uematsu T, Appl. Catal. A: Gen., 17, 2351 (1998)
Heracleous E, Liakakou ET, Lappas AA, Lemonidou AA, Appl. Catal. A: Gen., 455, 145 (2013)
Raybaud P, Digne M, Iftimie R, Wellens W, Euzen P, Toulhoat H, J. Catal., 201(2), 236 (2001)
Farkas L, Gad P, Werner PE, Mater. Res. Bull., 12, 1213 (1977)
Priya GK, Padmaja P, Warrier KG, Damodaran AD, Aruldhas G, J. Mater. Sci. Lett., 16(19), 1584 (1997)
Morterra C, Emanuel C, Cerrato G, Magnacca G, J. Chem. Soc.-Faraday Trans., 88, 339 (1992)
Wickersheim KA, Korpi GK, J. Chem. Phys., 42, 579 (1965)
Fripiat JJ, Bosmans HJ, Rouxhet PG, J. Phys. Chem., 71, 1097 (1967)
Mazza D, Vallino M, Busca G, J. Amer. Ceram. Soc., 75, 1929 (1992)
McMillan P, Piriou B, J. Non-Cryst. Solids, 53, 279 (1982)
Morterra C, Ghiotti G, Boccuzzi F, Coluccia S, J. Catal., 51, 299 (1978)
Philipp R, Fujimoto K, J. Phys. Chem., 96, 9035 (1992)
Di Cosimo JI, Diez VK, Xu M, Iglesia E, Apesteguia CR, J. Catal., 178(2), 499 (1998)
Pakharukova VP, Shalygin AS, Gerasimov EY, Tsybulya SV, Martyanov ON, J. Sol. State Chem, 233, 294 (2016)
Burch R, Golunski SE, Spencer MS, J. Chem. Soc.-Faraday Trans., 86, 2683 (1990)
Wu GD, Wang XL, Wei W, Sun YH, Appl. Catal. A: Gen., 377(1-2), 107 (2010)
Liu Y, Sun K, Ma H, Xu X, Wang X, Catal. Commun., 11, 880 (2010)
Gao P, Li F, Zhao N, Xiao FK, Wei W, Zhong LS, Sun YH, Appl. Catal. A: Gen., 468, 442 (2013)
Le Valant A, Comminges C, Tisseraud C, Canaff C, Pinard L, Pouilloux Y, J. Catal., 324, 41 (2015)
Tisseraud C, Comminges C, Belin T, Ahouari H, Soualah A, Pouilloux Y, Le Valant A, J. Catal., 330, 533 (2015)
