Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received May 3, 2018
Accepted June 24, 2018
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
Scalable synthesis of carbon-embedded ordered macroporous titania spheres with structural colors
1Department of Chemical Engineering, Sungkyunkwan University, Suwon 16419, Korea 2SKKU Advanced Institute of Nanotechnology (SAINT), Sungkyunkwan University, Suwon 16419, Korea 3Korea Basic Science Institute, Daejeon 34133, Korea
Korean Journal of Chemical Engineering, October 2018, 35(10), 2138-2144(7), 10.1007/s11814-018-0111-z
Download PDF
Abstract
Carbon-embedded ordered macroporous titania (C-MAC TiO2) spheres are prepared in solution by the cooperative self-assembly of polymer beads and a titania precursor within evaporative emulsions and subsequent direct carbonization. Because the highly reactive titania precursors are easily crosslinked to form gels early in evaporation before the polymer beads are self-organized, non-reactive toluene-in-formamide emulsions are used. These non-aqueous emulsions should be stable at relatively high temperatures (~80 °C) for the evaporation process. We found that amphiphilic triblock copolymers of poly(ethylene oxide) (PEO) and poly(phenylene oxide) (PPO) with longer PEO chains (Pluronic® F108 (EO125-b-PO64-b-EO125) are required to stabilize those non-aqueous emulsions, and become more important at higher concentrations used for bulk fabrication. The carbon inside our C-MAC TiO2 significantly suppresses strong multiple scattering from structural defects or imperfections, thus emphasizing their Bragg reflection colors.
Keywords
References
Armstrong E, O’Dwyer C, J. Mater. Chem. C, 3, 6109 (2015)
Dufresne ER, Noh H, Saranathan V, Mochrie SGJ, Cao H, Prum RO, Soft Matter, 5, 1792 (2009)
Xiao M, Hu Z, Wang Z, Li Y, Tormo AD, Le Thomas N, Wang B, Gianneschi NC, Shawkey MD, Dhinojwala A, Sci. Adv., 3, e17011 (2017)
Leung SF, Zhang Q, Xiu F, Yu D, Ho JC, Li D, Fan Z, J. Phys. Chem. Lett., 5, 1479 (2014)
Fenzl C, Hirsch T, Wolfbeis OS, Angew. Chem.-Int. Edit., 53, 3318 (2014)
Arsenault AC, Puzzo DP, Manners I, Ozin GA, Nature Photon., 1, 468 (2007)
Zhang X, Wang F, Wang L, Lin Y, Zhy J, Dyes Pigment., 138, 182 (2017)
Chokpanyarat T, Punsuvon V, Achiwawanich S, Adv. Mater. Sci. Eng., 2018, 1 (2018)
Liu FF, Shan B, Zhang SF, Tang BT, Langmuir, 34(13), 3918 (2018)
Zalfani M, van der Schueren B, Mandouani M, Bourguiga R, Yu WB, Wu M, Deparis O, Li Y, Su BL, Appl. Catal. B: Environ., 199, 187 (2016)
Jiang Q, Wang L, Yan C, Guo Z, Wang N, Eng. Sci., 164, 2018
Chen H, Lou R, Chen Y, Chen L, Lu J, Dong Q, Drug Deliv., 24, 775 (2017)
Cheng C, Karuturi SK, Liu L, Liu J, Li H, Su LT, Tok AI, Fan HJ, Small, 8, 37 (2012)
Yan X, Ye K, Zhang T, Xue C, Zhang D, Ma C, Wei J, Yang G, New J. Chem., 41, 8482 (2017)
Zhao H, Deng W, Li Y, Adv. Com. Hybrid. Mater., 1, 404 (2018)
Manoharan VN, Imhof A, Thorne JD, Pine DJ, Proc. SPIE, 44, 3937 (2000)
Schwarz JP, Spackman JR, Fahey DW, Gao RS, Lohmann U, et al., J. Geophy. Res., 113, D03203 (2008)
Takeoka Y, Yoshioka S, Takano A, Arai S, Nueangnoraj K, Nishihara H, Teshima M, Ohtsuka Y, Seki T, Angew. Chem.-Int. Edit., 52, 7261 (2013)
Wang W, Tang B, Ma W, Zhang J, Ju B, Zhang S, J. Opt. Soc. Am. A., 32, 1109 (2015)
Josephson DP, Miller M, Stein A, Z. Anorg. Allg. Chem., 640, 655 (2014)
Klein SM, Manoharan VN, Pine DJ, Lange FF, Langmuir, 21(15), 6669 (2005)
Imhof A, Pine DJ, J. Colloid Interface Sci., 192(2), 368 (1997)
Bragg WH, Bragg WL, Proc. Royal Soc. A, 88, 428 (1913)
Aguirre CI, Reguera E, Stein A, Adv. Funct. Mater., 20(16), 2565 (2010)
Kim SH, Cho YS, Jeon SJ, Eun TH, Yi GR, Yang SM, Adv. Mater., 20(17), 3268 (2008)
Veerappan G, Jung DW, Kwon J, Choi JM, Heo N, Yi GR, Park JH, Langmuir, 30(11), 3010 (2014)
Kim YB, Tran-Phu T, Kim M, Jung DW, Yi GR, Park JH, ACS. Appl. Mater. Interfaces, 7, 4511 (2015)
Koo HM, Tran-Phu T, Yi GR, Shin CH, Chung CH, Bae JW, Catal. Sci. Technol., 6, 4221 (2016)
Yang X, Liang C, Ma T, Guo Y, Kong J, Gu J, Chen M, Zhu J, Adv. Com. Hybrid. Mater., 1, 207 (2018)
Dufresne ER, Noh H, Saranathan V, Mochrie SGJ, Cao H, Prum RO, Soft Matter, 5, 1792 (2009)
Xiao M, Hu Z, Wang Z, Li Y, Tormo AD, Le Thomas N, Wang B, Gianneschi NC, Shawkey MD, Dhinojwala A, Sci. Adv., 3, e17011 (2017)
Leung SF, Zhang Q, Xiu F, Yu D, Ho JC, Li D, Fan Z, J. Phys. Chem. Lett., 5, 1479 (2014)
Fenzl C, Hirsch T, Wolfbeis OS, Angew. Chem.-Int. Edit., 53, 3318 (2014)
Arsenault AC, Puzzo DP, Manners I, Ozin GA, Nature Photon., 1, 468 (2007)
Zhang X, Wang F, Wang L, Lin Y, Zhy J, Dyes Pigment., 138, 182 (2017)
Chokpanyarat T, Punsuvon V, Achiwawanich S, Adv. Mater. Sci. Eng., 2018, 1 (2018)
Liu FF, Shan B, Zhang SF, Tang BT, Langmuir, 34(13), 3918 (2018)
Zalfani M, van der Schueren B, Mandouani M, Bourguiga R, Yu WB, Wu M, Deparis O, Li Y, Su BL, Appl. Catal. B: Environ., 199, 187 (2016)
Jiang Q, Wang L, Yan C, Guo Z, Wang N, Eng. Sci., 164, 2018
Chen H, Lou R, Chen Y, Chen L, Lu J, Dong Q, Drug Deliv., 24, 775 (2017)
Cheng C, Karuturi SK, Liu L, Liu J, Li H, Su LT, Tok AI, Fan HJ, Small, 8, 37 (2012)
Yan X, Ye K, Zhang T, Xue C, Zhang D, Ma C, Wei J, Yang G, New J. Chem., 41, 8482 (2017)
Zhao H, Deng W, Li Y, Adv. Com. Hybrid. Mater., 1, 404 (2018)
Manoharan VN, Imhof A, Thorne JD, Pine DJ, Proc. SPIE, 44, 3937 (2000)
Schwarz JP, Spackman JR, Fahey DW, Gao RS, Lohmann U, et al., J. Geophy. Res., 113, D03203 (2008)
Takeoka Y, Yoshioka S, Takano A, Arai S, Nueangnoraj K, Nishihara H, Teshima M, Ohtsuka Y, Seki T, Angew. Chem.-Int. Edit., 52, 7261 (2013)
Wang W, Tang B, Ma W, Zhang J, Ju B, Zhang S, J. Opt. Soc. Am. A., 32, 1109 (2015)
Josephson DP, Miller M, Stein A, Z. Anorg. Allg. Chem., 640, 655 (2014)
Klein SM, Manoharan VN, Pine DJ, Lange FF, Langmuir, 21(15), 6669 (2005)
Imhof A, Pine DJ, J. Colloid Interface Sci., 192(2), 368 (1997)
Bragg WH, Bragg WL, Proc. Royal Soc. A, 88, 428 (1913)
Aguirre CI, Reguera E, Stein A, Adv. Funct. Mater., 20(16), 2565 (2010)
Kim SH, Cho YS, Jeon SJ, Eun TH, Yi GR, Yang SM, Adv. Mater., 20(17), 3268 (2008)
Veerappan G, Jung DW, Kwon J, Choi JM, Heo N, Yi GR, Park JH, Langmuir, 30(11), 3010 (2014)
Kim YB, Tran-Phu T, Kim M, Jung DW, Yi GR, Park JH, ACS. Appl. Mater. Interfaces, 7, 4511 (2015)
Koo HM, Tran-Phu T, Yi GR, Shin CH, Chung CH, Bae JW, Catal. Sci. Technol., 6, 4221 (2016)
Yang X, Liang C, Ma T, Guo Y, Kong J, Gu J, Chen M, Zhu J, Adv. Com. Hybrid. Mater., 1, 207 (2018)
