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- In relation to this article, we declare that there is no conflict of interest.
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Received July 27, 2018
Accepted September 12, 2018
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Continuous methanol synthesis directly from methane and steam over Cu(II)-exchanged mordenite
Department of Chemical Engineering and Department of Energy Systems Research, Ajou University, Suwon 16499, Korea
edpark@ajou.ac.kr
Korean Journal of Chemical Engineering, November 2018, 35(11), 2145-2149(5), 10.1007/s11814-018-0150-5
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Abstract
The formation of methanol directly from methane and steam was observed over Cu ion-exchanged mordenite. Furthermore, the continuous production of methanol was achieved by co-feeding methane and steam over Cumordenite. The methanol production rate was comparable to that reported in the stepwise process in which activation, methane reaction, and extraction of methanol were carried out separately.
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References
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Schwach P, Pan XL, Bao XH, Chem. Rev., 117(13), 8497 (2017)
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Gunsalus NJ, Koppaka A, Park SH, Bischof SM, Hashiguchi BG, Periana RA, Chem. Rev., 117(13), 8521 (2107)
Ravi M, Ranocchiari M, van Bokhoven JA, Angew. Chem.-Int. Edit., 56, 16464 (2017)
Sushkevich VL, Palagin D, Ranocchiari M, van Bokhoven JA, Science, 356(6337), 523 (2017)
Sushkevich VL, Palagin D, van Bokhoven JA, Angew. Chem.-Int. Edit., 57, 8906 (2018)
Kim Y, Kim TY, Lee H, Yi J, Chem. Commun., 53(29), 4116 (2017)
Bozbag SE, Alayon EMC, Pechacek J, Nachtegaal M, Ranocchiari M, van Bokhoven JA, Catal. Sci. Technol., 6(13), 5011 (2016)
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Narsimhan K, Iyoki K, Dinh K, Roman-Leshkov Y, ACS Cent. Sci., 2(6), 424 (2016)
