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Received December 31, 2017
Accepted May 27, 2018
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Sublayer assisted by hydrophilic and hydrophobic ZnO nanoparticles toward engineered osmosis process
Sina Mansouri
Soodabeh Khalili1
Majid Peyravi1
Mohsen Jahanshahi1†
Rezvaneh Ramezani Darabi1
Fatemeh Ardeshiri2
Ali Shokuhi Rad3
School of Chemical Engineering, Kavosh Institute of Higher Education, Mahmood Abad, Iran 1Membrane Research Group, Nanotechnology Institute, Babol Noshirvani University of Technology, Shariati Ave., Babol, 47148-71167, Iran 2Institute of Nanoscience and Nanotechnology, University of Kashan, Kashan, Iran 3Department of Chemical Engineering, Qaemshahr Branch, Islamic Azad University, Qaemshahr, Iran
Korean Journal of Chemical Engineering, November 2018, 35(11), 2256-2268(13), 10.1007/s11814-018-0086-9
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Abstract
Hydrophilic and hydrophobic polyethersulfone (PES)-zinc oxide (ZnO) sublayers were prepared by loading of ZnO nanoparticles into PES matrix. Both porosity and hydrophilicity of the hydrophilic sublayer were increased upon addition of hydrophilic ZnO, while these were decreased for the hydrophobic sublayer. In addition, the results demonstrated that the hydrophilic membrane exhibited smaller structural parameter (S value or S parameter or S), which is beneficial for improving pure water permeability and decreasing mass transfer resistance. In contrast, a higher S parameter was obtained for the hydrophobic membrane. With a 2M NaCl as DS and DI water as FS, the pure water flux of hydrophilic TFN0.5 membrane was increased from 21.02 L/m2 h to 30.06 L/m2 h and decreased for hydrophobic TFN0.5 membrane to 14.98 L/m2 h, while the salt flux of hydrophilic membrane increased from 10.12 g/m2 h to 17.31 g/m2 h and decreased for hydrophobic TFN0.5 membrane to 3.12 g/m2 h. The increment in pure water permeability can be ascribed to reduction in S parameter, which resulted in reduced internal concentration polarization (ICP). The current study provides a feasible and low cost procedure to decrease the ICP in FO processes.
Keywords
References
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Kuang W, Liu Z, Kang G, Liu D, Zhou M, Cao Y, J. Appl. Polym. Sci., 133, 1 (2016)
Kong FX, Yang HW, Wu YQ, Wang XM, Xie YFF, J. Membr. Sci., 476, 410 (2015)
Shaffer DL, Werber JR, Jaramillo H, Lin SH, Elimelech M, Desalination, 356, 271 (2015)
Zirehpour A, Rahimpour A, Ulbricht M, J. Membr. Sci., 531, 59 (2017)
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Esfandian F, Peyravi M, Ghoreyshi AA, Jahanshahi M, Rad AS, Arab. J. Chem (2017).
Peyravi M, Jahanshahi M, Rahimpour A, Javadi A, Hajavi S, Chem. Eng. J., 241, 155 (2014)
Khajouei M, Peyravi M, Jahanshahi M, J. Membr. Sci. Res., 3, 2 (2017)
Peyravi M, Rahimpour A, Jahanshahi M, J. Membr. Sci., 423, 225 (2012)
Morales-Torres S, Esteves CMP, Figueiredo JL, Silva AMT, J. Membr. Sci., 520, 326 (2016)
Li D, Yan Y, Wa H, Prog. Polym. Sci, 61, 104 (2016)
Lin SH, J. Membr. Sci., 514, 176 (2016)
Dabaghian Z, Rahimpour A, Chem. Eng. Res. Des., 104, 647 (2015)
Hawari AH, Kamal N, Altaee A, Desalination, 398, 98 (2016)
Liu X, Ng HY, J. Membr. Sci., 469, 112 (2014)
Park M, Lee JJ, Lee S, Kim JH, J. Membr. Sci., 375(1-2), 241 (2011)
Chou SR, Wang R, Shi L, She QH, Tang CY, Fane AG, J. Membr. Sci., 389, 25 (2012)
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Liu Z, Yu H, Kang G, Jie X, Jin Y, Cao Y, J. Membr. Sci., 497, 485 (2016)
Xiao PP, Nghiem LD, Yin Y, Li XM, Zhang MX, Chen G, Song JF, He T, J. Membr. Sci., 481, 106 (2015)
She QH, Jin X, Tang CYY, J. Membr. Sci., 401, 262 (2012)
Boo C, Lee S, Elimelech M, Meng ZY, Hong S, J. Membr. Sci., 390, 277 (2012)
Suh C, Lee S, J. Membr. Sci., 427, 365 (2013)
Jimenez-Solomon MF, Gorgojo P, Munoz-Ibanez M, Livingston AG, J. Membr. Sci., 448, 102 (2013)
Ma N, Wei J, Qi SR, Zhao Y, Gao YB, Tang CYY, J. Membr. Sci., 441, 54 (2013)
Yin J, Deng BL, J. Membr. Sci., 479, 256 (2015)
Ghanbari M, Emadzadeh D, Lau WJ, Riazi H, Almasi D, Ismail AF, Desalination, 377, 152 (2016)
Tian M, Wang YN, Wang R, Fane AG, Desalination, 401, 142 (2017)
Feng XH, Guo HJ, Patel K, Zhou H, Lou X, Chem. Eng. J., 244, 327 (2014)
Abbasian M, Aali NK, Shoja SE, J. Macromol. Sci.-Phys., 50, 966 (2013)
Liu P, Wang TM, Curr. Appl. Phys., 8(1), 66 (2008)
Darabi RR, Peyravi M, Jahanshahi M, Amiri AAQ, Korean J. Chem. Eng., 34(8), 2311 (2017)
Baig MI, Ingole PG, Choi WK, Jeon JD, Jang B, Moon JH, Lee HK, Chem. Eng. J., 308, 27 (2017)
Amini M, Jahanshahi M, Rahimpour A, J. Membr. Sci., 435, 233 (2013)
Shafaei N, Peyravi M, Jahanshahi M, Polym. Adv. Technol., 27, 1325 (2016)
Ma S, Shi L, Feng X, Yu W, Lu B, J. Shan. Uni., 12, 278 (2008)
Anzlovar A, Orel ZC, Zigon M, Eur. Polym. J., 46, 1216 (2010)
Khaled SM, Sui R, Charpentier PA, Rizkalla AS, Langmuir, 23(7), 3988 (2007)
McCutcheon JR, Elimelech M, J. Membr. Sci., 318(1-2), 458 (2008)
Saffar A, Carreau PJ, Ajji A, Kamal MR, J. Membr. Sci., 462, 50 (2014)
Peyravi M, Rahimpour A, Jahanshahi M, Javadi A, Shockravi A, Microporous Mesoporous Mater., 160, 114 (2012)
Tian EL, Zhou H, Ren YW, Mirza ZA, Wang XZ, Xiong SW, Desalination, 347, 207 (2014)
Peyravi M, Rahimpour A, Jahanshahi M, J. Membr. Sci., 473, 72 (2015)
Emadzadeh D, Lau WJ, Ismail AF, Desalination, 330, 90 (2013)
Misdan N, Lau WJ, Ismail AF, Matsuura T, Desalination, 329, 9 (2013)
Zhu S, Zhao S, Wang Z, Tian XX, Shi MQ, Wang JX, Wang SC, J. Membr. Sci., 493, 263 (2015)
Xia SJ, Yao LJ, Zhao Y, Li NN, Zheng Y, Chem. Eng. J., 280, 720 (2015)
Hoseinpour H, Jahanshahi M, Peyravi M, Nozad A, J. Ind. Eng. Chem., 46, 244 (2017)
Wei J, Qiu CQ, Tang CYY, Wang R, Fane AG, J. Membr. Sci., 372(1-2), 292 (2011)
Emadzadeh D, Lau WJ, Rahbari-Sisakht M, Ilbeygi H, Rana D, Matsuura T, Ismail AF, Chem. Eng. J., 281, 243 (2015)
Emadzadeh D, Lau WJ, Matsuura T, Ismail AF, Rahbari-Sisakht M, J. Membr. Sci., 449, 74 (2014)
Liu X, Ng HY, J. Membr. Sci., 469, 112 (2014)
Akin O, Temelli F, Desalination, 278(1-3), 387 (2011)
Kuang W, Liu Z, Kang G, Liu D, Zhou M, Cao Y, J. Appl. Polym. Sci., 133, 1 (2016)
