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Received March 22, 2018
Accepted July 17, 2018
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Experimental and theoretical investigation of micellization behavior of sodium dodecyl sulfate with cetyltrimethylammonium bromide in aqueous/urea solution at various temperatures
1Department of Chemistry, Jahangirnagar University, Savar, Dhaka- 1342, Bangladesh 2Chemistry Department, Faculty of Science, King Abdulaziz University, Jeddah-21589, Saudi Arabia 3Center of Excellence for Advanced Materials Research, King Abdulaziz University, Jeddah-21589, Saudi Arabia
Korean Journal of Chemical Engineering, November 2018, 35(11), 2269-2282(14), 10.1007/s11814-018-0120-y
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Abstract
Mixed micelle formation behavior of cationic surfactant-cetyltrimethylammonium bromide (CTAB) and anionic surfactant sodium dodecyl sulfate (SDS) in aqueous as well as in urea medium from 303.15 K to 323.15 K at 5 K interval was carried out by conductometric method. The differences between the experimental values of critical micelle concentrations (cmc) and ideal critical micelle concentrations (cmcid) illustrate the interaction between the amphiphiles studied. The values of micellar mole fraction (X1 Rub (Rubingh), X1 M (Motomura), X1 Rod (Rodenas) and X1 id (ideal) of surfactant CTAB determined by different proposed models and outcome indicate high involvement of CTAB in SDS-CTAB mixed micellization, which enhance by means of the augment of mole fraction of CTAB. The negative value of interaction parameter (β) showed an attractive interaction involving CTAB and SDS. Activity coefficients were less than unity in all case, which also reveals the presence of interaction between CTAB & SDS. The negative ΔG0 m values imply the spontaneous mixed micellization phenomenon. The attained values of ΔH0 m were positive at inferior temperature, while negative at superior temperature. The negative ΔH0 m values in urea (NH2CONH2) medium illustrate exothermic micellization process. The magnitudes of ΔS0 m were positive in almost all cases. The excess free energy of mixed micelle formation (ΔGex) was found to be negative, which indicates the stability of mixed micelle as compared to the individual…s components micelles.
Keywords
References
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Rub MA, Azum N, Khan F, Asiri AM, J. Chem. Thermodyn., 121, 199 (2018)
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Rub MA, Khan F, Kumar D, Asiri AM, Tenside Surf. Deterg., 52, 236 (2015)
Azum N, Rub MA, Asiri AM, Bawazeer WA, Colloids Surf. A: Physicochem. Eng. Asp., 522, 183 (2017)
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Paria S, Colloids Surf. A: Physicochem. Eng. Asp., 281, 113 (2006)
Clint JH, J. Chem. Soc.-Faraday Trans., 71, 1327 (1975)
Molla MR, Rub MA, Ahmad A, Hoque MA, J. Mol. Liq., 238, 62 (2017)
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Kale KM, Cussler EL, Evans DF, J. Phys. Chem., 84, 593 (1980)
Bandhopadhyay A, Moulik SP, Colloid Polym. Sci., 266, 455 (1988)
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Rub MA, Asiri AM, Khan JM, Khan RH, Kabir-ud-Din, J. Mol. Struct., 1050, 35 (2013)
Soldi V, Keiper J, Romsted LS, Cuccovia IM, Chaimovich H, Langmuir, 16(1), 59 (2000)
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Lange H, Beck KH, Kolloid Z. Z. Polym., 251, 424 (1973).
Hoque MA, Patoary MOF, Rashid MM, Molla MR, Rub MA, J. Solution Chem., 46, 682 (2017)
Joshi T, Bharatiya B, Kuperkar K, J. Dispersion Sci. Technol., 29, 351 (2008)
Moroi Y, J. Colloid Interface Sci., 122, 308 (1988)
van Os NM, Smit B, Karaborni S, Red. Trav. Chim. Pays-Bas, 113, 181 (1994)
Tanford C, Proceedings of the National Academy of Science, 71, 1811 (1974)..
Ali A, Uzair S, Malik NA, Ali M, J. Mol. Liq., 196, 395 (2014)
Nusselder JJH, Engberts JBFN, J. Colloid Interface Sci., 148, 353 (1992)
Kumar D, Rub MA, Tenside Surf. Deterg., 52, 464 (2015)
Ren ZH, Luo Y, Shi DP, Colloids Surf. A: Physicochem. Eng. Asp., 428, 18 (2013)
Ren ZH, Luo Y, Zheng YC, Shi DP, Mei P, Li FS, J. Solution Chem., 43, 853 (2014)
Ren ZH, J. Ind. Eng. Chem., 20(5), 3649 (2014)
Clint JH, Walker TJ, J. Chem. Soc.-Faraday Trans., 71, 946 (1975)
Azum N, Rub MA, Asiri AM, J. Dispersion Sci. Technol., 38, 96 (2017)
Azum N, Rub MA, Asiri AM, J. Dispersion Sci. Technol., 38, 1785 (2017)
Rub MA, Azum N, Asiri AM, Zayed MEM, Al-Youbi AO, J. Phys. Org. Chem., 29, 476 (2016)
Rub MA, Azum N, Asiri AM, Russian J. Phys. Chem. B, 10, 1007 (2016)
Li GH, Cho CG, Korean J. Chem. Eng., 1444, 25 (2008)
Roy S, Dey J, J. Colloid Interface Sci., 290(2), 526 (2005)
Cutler WG, Kissa E, Detergency: Theory and practice, Marcel Dekker, New York (1987).
Kim JC, Korean J. Chem. Eng., 26(6), 1821 (2009)
Friberg SE, Food emulsions, vol. 5, Marcel Dekker, New York (1976).
Rosen MJ, Surfactants and interfacial phenomena, 3rd Ed., Wiley, New York (2004).
Kumar D, Rub MA, J. Mol. Liq., 240, 253 (2017)
Rub MA, Azum N, Khan F, Asiri AM, J. Chem. Thermodyn., 121, 199 (2018)
Robinson DR, Jencks WP, J. Am. Chem. Soc., 87, 2462 (1965)
Wetlaufer DB, Malik SK, Stoller L, Coffin RL, J. Am. Ceram. Soc., 86, 508 (1964)
Enea O, Jolicoeur C, J. Phys. Chem., 86, 3870 (1982)
Chakraborty A, Sarkar M, Basak S, J. Colloid Interface Sci., 287(1), 312 (2005)
Rub MA, Khan F, Kumar D, Asiri AM, Tenside Surf. Deterg., 52, 236 (2015)
Azum N, Rub MA, Asiri AM, Bawazeer WA, Colloids Surf. A: Physicochem. Eng. Asp., 522, 183 (2017)
Rub MA, Azum N, Asiri AM, J. Mol. Liq., 218, 595 (2016)
Azum N, Rub MA, Asiri AM, Chinese J. Chem. Eng., 26, 566 (2018)
Treiner C, Makayssi A, Langmuir, 8, 794 (1992)
Kumar D, Rub MA, Azum N, Asiri AM, J. Phys. Org. Chem., 31, e3730 (208)
Desai TR, Dixit SG, J. Colloid Interface Sci., 177(2), 471 (1996)
Rub MA, Azum N, Khan F, Asiri AM, J. Phys. Org. Chem., 30, e3676 (2017)
Rub MA, Azum N, Asiri AM, J. Chem. Eng. Data, 62(10), 3216 (2017)
Azum N, Rub MA, Asiri AM, Colloids Surf. B: Biointerfaces, 121, 158 (2014)
Jana PK, Moulik SP, J. Phys. Chem., 95, 9525 (1991)
Roden MJ, Zhu H, Gao T, J. Colloid Interface Sci., 157, 254 (1993)
Clint JH, Surfactant aggregation, Blackie/Chapman and Hall, Glasgow, New York (1992).
Haque ME, Das AR, Rakshit AK, Moulik SP, Langmuir, 12(17), 4084 (1996)
Palous JL, Turmine M, Letellier P, J. Phys. Chem. B, 102(30), 5886 (1998)
Rosen MJ, Murphy D, J. Colloid Interface Sci., 110, 224 (1986)
Attwood D, Florence AT, Surfactant systems: Their chemistry, pharmacy and biology, Chapman & Hall, New York (1983).
Elworthy PH, Florence AT, Macfarlane GB, Solubilization by surface-active agents and its application in chemistry and biological sciences, Chapman and Hall, Suffolk (1968).
Rub MA, Azum N, Khan SB, Marwani HM, Asiri AM, J. Mol. Liq., 212, 532 (2015)
Motin MA, Mia MAAH, Islam AKMN, J. Saudi Chem. Soc., 19, 172 (2015)
Niraula TP, Shah SK, Chatterjee SK, Bhattarai A, Karbala Int. J. Modern Sci., 4, 26 (2018)
Ruiz CC, Colloids Surf. A: Physicochem. Eng. Asp., 147, 349 (1999)
Kumar D, Rub MA, Akram M, Kabir-ud-Din, Tenside Surf. Deterg., 51, 157 (2014)
Akhtar F, Hoque MA, Khan MA, J. Chem. Thermodyn., 40(7), 1082 (2008)
Rahman M, Khan MA, Rub MA, Hoque MA, J. Mol. Liq., 223, 716 (2016)
Kumar D, Rub MA, Akram M, Kabir-ud-Din, J. Colloid Interface Sci., 418, 324 (201)
Jha R, Ahluwalia JC, J. Chem. Soc.-Faraday Trans., 89, 3465 (1993)
Han SK, Lee SM, Schott H, J. Colloid Interface Sci., 126, 393 (1988)
Kresheck GC, Water: A comprehensive treatise, vol. 4,(Ed.), Plenum, New York (1975).
Menguro K, Takasawa Y, Kawahashi N, Tabata Y, Ueno M, J. Colloid Interface Sci., 83, 50 (1981)
Kabir-ud-Din, Siddique US, Sanjeev S, Dar AA, Colloid Polym. Sci., 384, 807 (2006)
Ruiz CC, Diaz-Lopez L, Aguiar J, J. Colloid Interface Sci., 305(2), 293 (2007)
Das C, Das B, J. Chem. Eng. Data, 54(2), 559 (2009)
Paria S, Colloids Surf. A: Physicochem. Eng. Asp., 281, 113 (2006)
Clint JH, J. Chem. Soc.-Faraday Trans., 71, 1327 (1975)
Molla MR, Rub MA, Ahmad A, Hoque MA, J. Mol. Liq., 238, 62 (2017)
Kumar D, Rub MA, J. Mol. Liq., 238, 389 (2017)
Buckingham A, Garve CJ, Warr GG, J. Phys. Chem., 97, 10236 (1993)
Kale KM, Cussler EL, Evans DF, J. Phys. Chem., 84, 593 (1980)
Bandhopadhyay A, Moulik SP, Colloid Polym. Sci., 266, 455 (1988)
Moroi Y, Micelles: Theoretical and applied aspects, Plenium Press, New York (1992).
Rub MA, Asiri AM, Khan JM, Khan RH, Kabir-ud-Din, J. Mol. Struct., 1050, 35 (2013)
Soldi V, Keiper J, Romsted LS, Cuccovia IM, Chaimovich H, Langmuir, 16(1), 59 (2000)
Zana R, J. Colloid Interface Sci., 78, 330 (1980)
Gorski N, Kalus J, Langmuir, 17(14), 4211 (2001)
Rubingh DN, Mixed micelle solution, (Ed.), Solution Chemistry of Surfactants, vol. 1, Plenum, New York (1979).
Motomura K, Yamanaka M, Arat M, Colloid Polym. Sci., 262, 948 (1984)
Rodenas E, Valiente M, Villafruela MD, J. Phys. Chem. B, 103(21), 4549 (1999)
Lange H, Beck KH, Kolloid Z. Z. Polym., 251, 424 (1973).
Hoque MA, Patoary MOF, Rashid MM, Molla MR, Rub MA, J. Solution Chem., 46, 682 (2017)
Joshi T, Bharatiya B, Kuperkar K, J. Dispersion Sci. Technol., 29, 351 (2008)
Moroi Y, J. Colloid Interface Sci., 122, 308 (1988)
van Os NM, Smit B, Karaborni S, Red. Trav. Chim. Pays-Bas, 113, 181 (1994)
Tanford C, Proceedings of the National Academy of Science, 71, 1811 (1974)..
Ali A, Uzair S, Malik NA, Ali M, J. Mol. Liq., 196, 395 (2014)
Nusselder JJH, Engberts JBFN, J. Colloid Interface Sci., 148, 353 (1992)
Kumar D, Rub MA, Tenside Surf. Deterg., 52, 464 (2015)
Ren ZH, Luo Y, Shi DP, Colloids Surf. A: Physicochem. Eng. Asp., 428, 18 (2013)
Ren ZH, Luo Y, Zheng YC, Shi DP, Mei P, Li FS, J. Solution Chem., 43, 853 (2014)
Ren ZH, J. Ind. Eng. Chem., 20(5), 3649 (2014)
Clint JH, Walker TJ, J. Chem. Soc.-Faraday Trans., 71, 946 (1975)
Azum N, Rub MA, Asiri AM, J. Dispersion Sci. Technol., 38, 96 (2017)
Azum N, Rub MA, Asiri AM, J. Dispersion Sci. Technol., 38, 1785 (2017)
Rub MA, Azum N, Asiri AM, Zayed MEM, Al-Youbi AO, J. Phys. Org. Chem., 29, 476 (2016)
