Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received August 31, 2018
Accepted October 8, 2018
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
One-pot synthesis of PdAu bimetallic composite nanoparticles and their catalytic activities for hydrogen peroxide generation
Xiangyun Xiao1
Tae-Uook Kang2 3
Hyobin Nam4 5
Suk Ho Bhang6
Seung Yong Lee4 5†
Jae-Pyung Ahn3†
Taekyung Yu1†
1Department of Chemical Engineering, Kyung Hee University, Yongin 17104, Korea 2Department of Material Science & engineering, Korea University, Seoul 02841, Korea 3Advanced Analysis Center, Korea Institute of Science and Technology, Seoul 02792, Korea 4Materials Architecturing Research Center, Korea Institute of Science and Technology, Seoul 02792, Korea 5Department of Nanomaterials Science and Engineering, Korea University of Science and Technology, Daejeon 34113, Korea 6School of Chemical Engineering, Sungkyunkwan University, Suwon 16419, Korea
patra@kist.re.kr
Korean Journal of Chemical Engineering, December 2018, 35(12), 2379-2383(5), 10.1007/s11814-018-0164-z
Download PDF
Abstract
We report a facile one-pot aqueous-phase synthesis of PdAu bimetallic nanoparticles with different Pd/Au ratio. The synthesis was conducted by co-reduction of Pd and Au precursor using ascorbic acid as a reducing agent and in the presence of polyallylamine hydrochloride (PAH). By high-angle annular dark field scanning transmission electron microscopy (HAADF-STEM) and energy-dispersive X-ray spectrometry (EDS) analyses, we found that the synthesized nanoparticles had an onion-like core/shell/shell/shell structure with Au-rich core, Pd-rich shell, Au-rich shell, and Pd shell, respectively. We also investigated the catalytic performance of the synthesized PdAu nanoparticles toward hydrogen peroxide generation reaction.
References
Prasanna D, Selvaraj V, Korean J. Chem. Eng., 33(4), 1489 (2016)
Lee WJ, Jeong SM, Lee H, Kim BJJ, An KH, Park YK, Jung SC, Korean J. Chem. Eng., 34(11), 2993 (2017)
Dou J, Zhang Q, Ma M, Gu J, J. Magn. Magn. Mater., 324, 3078 (2012)
Gu J, Wang L, Liang C, Zhuang Q, Kong J, J. Alloy. Compd., 745, 430 (2018)
Sun SH, Jung SC, Korean J. Chem. Eng., 33(3), 1075 (2016)
Zhang Z, Zhang J, Liu G, Xue M, Wang Z, Bu X, Wu Q, Zhao X, Korean J. Chem. Eng., 34(9), 2471 (2017)
Gu JW, Yang XT, Li CM, Kou KC, Ind. Eng. Chem. Res., 55(41), 10941 (2016)
Weng XL, Guo MY, Luo F, Chen ZL, Chem. Eng. J., 308, 904 (2017)
Suo ZH, Ma CY, Liao WP, Jin MS, Lv HY, Fuel Process. Technol., 92(8), 1549 (2011)
Liu K, Yan X, Zou P, Wang Y, Dai L, Catal. Commun., 58, 132 (2015)
Flaherty DW, ACS Catal., 8, 1520 (2018)
Wang HW, Wang CL, Yan H, Yi H, Lu JL, J. Catal., 324, 59 (2015)
Liu Q, Xu YR, Wang AJ, Feng JJ, Int. J. Hydrog. Energy, 41(4), 2547 (2016)
Hsu SC, Chuang YC, Sneed BT, Cullen DA, Chiu TW, Kuo CH, Nano Lett., 16, 5514 (2016)
Akbarzadeh H, Mehrjouei E, Sherafati M, Shamkhali AN, Inorg. Chem. Front., 4, 1551 (2017)
Lee C, Kim NR, Koo J, Lee YJ, Lee HM, Nanotechnology, 26, 455 (2015)
Gawande MB, Goswami A, Asefa T, Guo H, Biradar AV, Peng DL, Zboril R, Varma RS, Chem. Soc. Rev., 44, 7540 (2015)
Zhang H, Kawashima K, Okumura M, Toshima N, J. Mater. Chem. A, 2, 13498 (2014)
Park Y, Lee YW, Kang SW, Han SW, Nanoscale, 6, 9798 (2014)
Ferrer D, Torres-Castro A, Gao X, Sepulveda-Guzman S, Ortiz-Mendez U, Jose-Yacaman M, Nano Lett., 7, 1701 (2007)
Kosaka K, Yamada H, Matsui S, Echigo S, Shishida K, Environ. Sci. Technol., 32, 3821 (1998)
Fu G, Ding L, Chen Y, Lin J, Tang Y, Lu T, Cryst. Eng. Comm., 16, 1606 (2014)
Lee WJ, Jeong SM, Lee H, Kim BJJ, An KH, Park YK, Jung SC, Korean J. Chem. Eng., 34(11), 2993 (2017)
Dou J, Zhang Q, Ma M, Gu J, J. Magn. Magn. Mater., 324, 3078 (2012)
Gu J, Wang L, Liang C, Zhuang Q, Kong J, J. Alloy. Compd., 745, 430 (2018)
Sun SH, Jung SC, Korean J. Chem. Eng., 33(3), 1075 (2016)
Zhang Z, Zhang J, Liu G, Xue M, Wang Z, Bu X, Wu Q, Zhao X, Korean J. Chem. Eng., 34(9), 2471 (2017)
Gu JW, Yang XT, Li CM, Kou KC, Ind. Eng. Chem. Res., 55(41), 10941 (2016)
Weng XL, Guo MY, Luo F, Chen ZL, Chem. Eng. J., 308, 904 (2017)
Suo ZH, Ma CY, Liao WP, Jin MS, Lv HY, Fuel Process. Technol., 92(8), 1549 (2011)
Liu K, Yan X, Zou P, Wang Y, Dai L, Catal. Commun., 58, 132 (2015)
Flaherty DW, ACS Catal., 8, 1520 (2018)
Wang HW, Wang CL, Yan H, Yi H, Lu JL, J. Catal., 324, 59 (2015)
Liu Q, Xu YR, Wang AJ, Feng JJ, Int. J. Hydrog. Energy, 41(4), 2547 (2016)
Hsu SC, Chuang YC, Sneed BT, Cullen DA, Chiu TW, Kuo CH, Nano Lett., 16, 5514 (2016)
Akbarzadeh H, Mehrjouei E, Sherafati M, Shamkhali AN, Inorg. Chem. Front., 4, 1551 (2017)
Lee C, Kim NR, Koo J, Lee YJ, Lee HM, Nanotechnology, 26, 455 (2015)
Gawande MB, Goswami A, Asefa T, Guo H, Biradar AV, Peng DL, Zboril R, Varma RS, Chem. Soc. Rev., 44, 7540 (2015)
Zhang H, Kawashima K, Okumura M, Toshima N, J. Mater. Chem. A, 2, 13498 (2014)
Park Y, Lee YW, Kang SW, Han SW, Nanoscale, 6, 9798 (2014)
Ferrer D, Torres-Castro A, Gao X, Sepulveda-Guzman S, Ortiz-Mendez U, Jose-Yacaman M, Nano Lett., 7, 1701 (2007)
Kosaka K, Yamada H, Matsui S, Echigo S, Shishida K, Environ. Sci. Technol., 32, 3821 (1998)
Fu G, Ding L, Chen Y, Lin J, Tang Y, Lu T, Cryst. Eng. Comm., 16, 1606 (2014)
