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Received June 25, 2018
Accepted October 4, 2018
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Removal of textile dyes in wastewater using polyelectrolytes containing tetrazole groups
Martín Caldera-Villalobos
Alejandra-Alicia Peláez-Cid1
Miriam-Amelia Martins-Alho2
and Ana-María Herrera-González3†
Doctorado en Ciencias de los Materiales, Instituto de Ciencias Básicas e Ingeniería, Universidad Autónoma del Estado de Hidalgo, Carretera Pachuca-Tulancingo Km 4.5 Colonia Carboneras, C.P.42184, Mineral de la Reforma Hidalgo, Hidalgo, México, Mexico 1Facultad de Ingeniería, Benemérita Universidad Autónoma de Puebla, Edificio ING1, Ciudad Universitaria, C.P. 72570, Puebla, México, Mexico 2Cátedra de Química Orgánica, Departamento de Química, Facultad de Ingeniería, Universidad de Buenos Aires, Avenida Paseo Colón 850, CABA, Argentina 3Laboratorio de Polímeros, Instituto de Ciencias Básicas e Ingeniería, Universidad Autónoma del Estado de Hidalgo, Carretera Pachuca-Tulancingo Km 4.5 Colonia Carboneras, C.P.42184, Mineral de la Reforma Hidalgo, Hidalgo, México, Mexico
mherrera@uaeh.edu.mx, anamhg_1@hotmail.com
Korean Journal of Chemical Engineering, December 2018, 35(12), 2394-2402(9), 10.1007/s11814-018-0160-3
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Abstract
Textile dyes are some of the pollutants which have received the most attention because of the large volume of wastewater generated by the textile industry. Removal by means of adsorption is one of the most versatile alternatives to treat these effluents. Even though different adsorbents such as activated carbons and mineral materials have been proposed, polymeric adsorbents are a viable alternative. This work reports for the first time the use of polyelectrolyte PTZ and macroelectrolyte MTZ containing tetrazole groups as adsorbents useful in the textile dyes removal present in aqueous solutions and wastewater. Because of the anionic character of the tetrazole group, MTZ exhibits selective adsorption capabilities for cationic dyes of up to 156.25mㆍg-1. The kinetic study of the process of adsorption shows that PTZ and MTZ fit a pseudo second-order model. MTZ also shows utility as a flocculant agent in the treatment of wastewater containing dyes Indigo Blue and Reactive Black. The results showed that PTZ and MTZ may be used in the treatment of wastewater in a process of coagulation-flocculation followed by the treatment by adsorption. This twostage treatment removed up to 95% of the dye present in the wastewater. As well as removing the dyes, the values for COD, suspended solids, pH, and color of the wastewater decreased, thus significantly improving its quality.
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Zhao Z, Li L, Geleta GS, Ma L, Wang Z, Sci. Rep., 7(1), 7878 (2017)
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Song MK, Li HP, Li JH, Zhao D, Wang JH, Liu ML, Adv. Mater., 26(8), 1277 (2014)
Li JH, Wang JX, Chen XQ, Lv ZP, Chen T, Wang TY, Solid State Ion., 255, 128 (2014)
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Sinirlioglu D, Muftuoglu AE, Bozkurt A, J. Polym. Res., 21(8), 526 (2014)
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Yan SH, Zhao M, Lei GH, Wei YM, J. Appl. Polym. Sci., 125(1), 382 (2012)
Igrunova AV, Sirotinkin NV, Uspenskaya MV, Russ. J. Appl. Chem., 74(5), 818 (2001)
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