Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received August 13, 2017
Accepted September 13, 2017
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
Polymer/graphene oxide (GO) thermoset composites with GO as a crosslinker
Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, MN, 55455-0431, U.S.A., USA
cellison@umn.edu
Korean Journal of Chemical Engineering, February 2018, 35(2), 303-317(15), 10.1007/s11814-017-0250-7
Download PDF
Abstract
Composites have historically been of intense interest due to their potential to replace glass, wood and metal at a fraction of the weight. Of the many choices of fillers, graphene oxide (GO) is generally attractive for its versatility and tunability in terms of surface functionality, size and shape. While the majority of GO has been incorporated into polymers and polymer precursors by physical mixing, this review focuses on research where GO has served as both a property enhancer and multifunctional crosslinker in thermosets. Methods for preparing GO (with and without additional functionalization) and incorporating it appropriately into thermosets are described. A review of characterization techniques, typically applied before and after GO is incorporated into thermosets and analytical methods for confirming important chemical reactions during crosslinking, is also provided. Finally, the resulting composite thermoset properties are surveyed throughout to connect preparation and characterization methods to their potential practical importance.
Keywords
References
Paul DR, Robeson LM, Polymer, 49(15), 3187 (2008)
Kim H, Abdala AA, Macosko CW, Macromolecules, 43(16), 6515 (2010)
Zurutuza A, Marinelli C, Nat. Nanotechnol., 9(10), 730 (2014)
Ji X, Xu Y, Zhang W, Cui L, Liu J, Compos. Pt. A-Appl. Sci. Manuf., 87, 29 (2016)
Novoselov KS, Geim AK, Morozov SV, Jiang D, Zhang Y, Dubonos SV, Grigorieva IV, Firsov AA, Science, 306, 666 (2004)
Geim AK, Novoselov KS, Nat. Mater., 6(3), 183 (2007)
Ferrari AC, Bonaccorso F, Fal’ko V, Novoselov KS, Roche S, Boggild P, Borini S, Koppens FH, Palermo V, Pugno N, et al., Nanoscale, 7, 4598 (2015)
Lee HC, Liu WW, Chai SP, Mohamed AR, Lai CW, Khe CS, Voon CH, Hashim U, Hidayah NMS, Procedia Chem., 19, 916 (2016)
Geng DC, Wang HP, Yu G, Adv. Mater., 27(18), 2821 (2015)
Li XS, Colombo L, Ruoff RS, Adv. Mater., 28(29), 6247 (2016)
Zhu YW, Murali S, Cai WW, Li XS, Suk JW, Potts JR, Ruoff RS, Adv. Mater., 22(35), 3906 (2010)
Chabot V, Higgins D, Yu A, Xiao X, Chen Z, Zhang J, Energy Environ. Sci., 7, 1564 (2014)
Kumar SK, Benicewicz BC, Vaia RA, Winey KI, Macromolecules, 50(3), 714 (2017)
Szabo T, Berkesi O, Forgo O, Josepovits K, Sanakis Y, Petridis D, Dekany I, Chem. Mater., 18, 2740 (2006)
Dreyer DR, Park S, Bielawski CW, Ruoff RS, Chem. Soc. Rev., 39, 228 (2010)
Cai M, Thorpe D, Adamson DH, Schniepp HC, J. Mater. Chem., 22, 24992 (2012)
Compton OC, An Z, Putz KW, Hong BJ, Hauser BG, Brinson LC, Nguyen ST, Carbon, 50, 3399 (2012)
Ogino I, Yokoyama Y, Iwamura S, Mukai SR, Chem. Mater., 26, 3334 (2014)
Stankovich S, Dikin DA, Piner RD, Kohlhaas KA, Kleinhammes A, Jia Y, Wu Y, Nguyen ST, Ruoff RS, Carbon, 45, 1558 (2007)
Li D, Muller MB, Gilje S, Kaner RB, Wallace GG, Nat. Nanotechnol., 3(2), 101 (2008)
Zhang J, Yang H, Shen G, Cheng P, Zhang J, Guo S, Chem. Commun., 46, 1112 (2010)
Pei S, Zhao J, Du J, Ren W, Cheng HM, Carbon, 48, 4466 (2010)
Pham HD, Pham VH, Cuong TV, Nguyen-Phan TD, Chung JS, Shin EW, Kim S, Chem. Commun., 47, 9672 (2011)
Pham HD, Pham VH, Oh ES, Chung JS, Kim S, Korean J. Chem. Eng., 29, 125 (2011)
Bo Z, Shuai X, Mao S, Yang H, Qian J, Chen J, Yan J, Cen K, Sci. Rep., 4, 4684 (2014)
Xu L, Xiao G, Chen C, Li R, Mai Y, Sun G, Yan D, J. Mater. Chem., 3, 7498 (2015)
He D, Peng Z, Gong W, Luo Y, Zhao P, Kong L, RSC Adv., 5, 11966 (2015)
Yang D, Velamakanni A, Bozoklu G, Park S, Stoller M, Piner RD, Stankovich S, Jung I, Field DA, Ventrice CA, Ruoff RS, Carbon, 47, 145 (2009)
Xu YX, Sheng KX, Li C, Shi GQ, ACS Nano, 4, 4324 (2010)
Chen WF, Li SR, Chen CH, Yan LF, Adv. Mater., 23(47), 5679 (2011)
Kang DW, Shin HS, Carbon Lett., 13, 39 (2012)
Loryuenyong V, Totepvimarn K, Eimburanapravat P, Boonchompoo W, Buasri A, Adv. Mater. Sci. Eng., 2013, 1 (2013)
Pham VH, Dang TT, Cuong TV, Hur SH, Kong BS, Kim EJ, Chung JS, Korean J. Chem. Eng., 29(5), 680 (2012)
Mkhoyan KA, Contryman AW, Silcox J, Stewart DA, Eda G, Mattevi C, Miller S, Chhowalla M, Nano Lett., 9, 1058 (2009)
Botas C, Alvarez P, Blanco C, Santamaria R, Granda M, Gutierrez MD, Rodriguez-Reinoso F, Menendez R, Carbon, 52, 476 (2013)
Zhou S, Bongiorno A, Acc. Chem. Res., 47, 3331 (2014)
Ban S, Xie J, Wang Y, Jing B, Liu B, Zhou H, ACS Appl. Mater. Interfaces, 8, 321 (2016)
Kim S, Zhou S, Hu YK, Acik M, Chabal YJ, Berger C, de Heer W, Bongiorno A, Riedo E, Nat. Mater., 11(6), 544 (2012)
He S, Chen W, Nanoscale, 7, 6957 (2015)
Mao S, Lu G, Chen J, Nanoscale, 7, 6924 (2015)
Hong JY, Wie JJ, Xu Y, Park HS, Phys. Chem. Chem. Phys., 17, 30946 (2015)
Jang H, Park YJ, Chen X, Das T, Kim MS, Ahn JH, Adv. Mater., 28(22), 4184 (2016)
Ge J, Zhao HY, Zhu HW, Huang J, Shi LA, Yu SH, Adv. Mater., 28(47), 10459 (2016)
Wang M, Duan X, Xu Y, Duan X, ACS Nano, 10, 7231 (2016)
Swain SS, Unnikrishnan L, Mohanty S, Nayak SK, Korean J. Chem. Eng., 34(8), 2119 (2017)
Park YT, Qian YQ, Chan C, Suh T, Nejhad MG, Macosko CW, Stein A, Adv. Funct. Mater., 25(4), 575 (2015)
Ha H, Park J, Ha K, Freeman BD, Ellison CJ, Polymer, 93, 53 (2016)
Ha H, Shanmuganathan K, Ellison CJ, ACS Appl. Mater. Interfaces, 7, 6220 (2015)
Liao KH, Mittal A, Bose S, Leighton C, Mkhoyan KA, Macosko CW, ACS Nano, 5, 1253 (2011)
He SY, Petkovich ND, Liu KW, Qian YQ, Macosko CW, Stein A, Polymer, 110, 149 (2017)
Zhang Y, Zhu YW, Lin G, Ruoff RS, Hu NP, Schaefer DW, Mark JE, Polymer, 54(14), 3605 (2013)
Shi H, Shi D, Li C, Luan S, Yin J, Li RKY, Mater. Lett., 133, 200 (2014)
Sharp N, Li CY, Strachan A, Adams D, Pipes RB, J. Polym. Sci. B: Polym. Phys., 55(15), 1150 (2017)
Jeong HK, Lee YP, Jin MH, Kim ES, Bae JJ, Lee YH, Chem. Phys. Lett., 470(4-6), 255 (2009)
Park S, Dikin DA, Nguyen ST, Ruoff RS, J. Phys. Chem., 113, 15801 (2009)
Ye S, Feng J, Wu P, J. Mater. Chem., 1, 3495 (2013)
Ha H, Park J, Ando S, Bin Kim C, Nagai K, Freeman BD, Ellison CJ, J. Membr. Sci., 518, 131 (2016)
Vacchi IA, Spinato C, Raya J, Bianco A, Menard-Moyon C, Nanoscale8, 13714, 2016
Hu X, Qi R, Zhu J, Lu J, Luo Y, Jin J, Jiang P, J. Appl. Polym. Sci., 131, 39754 (2014)
Li W, Shang T, Yang W, Yang H, Lin S, Jia X, Cai Q, Yang X, ACS Appl. Mater. Interfaces, 8, 13037 (2016)
Acocella MR, Corcione CE, Giuri A, Maggio M, Maffezzoli A, Guerra G, RSC Adv., 6, 23858 (2016)
Ha H, Ha K, Ellison CJ, J. Polym. Sci. B: Polym. Phys., 55(18), 1406 (2017)
Zhou X, Chen Z, Yan D, Lu H, J. Mater. Chem., 22, 13506 (2012)
Sui ZY, Cui Y, Zhu JH, Han BH, ACS Appl. Mater. Interfaces, 5, 9172 (2013)
Layek RK, Nandi AK, Polymer, 54(19), 5087 (2013)
Xie ZT, Fu X, Wei LY, Luo MC, Liu YH, Ling FW, Huang C, Huang GS, Wu JR, Polymer, 118, 30 (2017)
Song N, Yang JW, Ding P, Tang SF, Liu YM, Shi LY, Ind. Eng. Chem. Res., 53(51), 19951 (2014)
Kaminska I, Das MR, Coffinier Y, Niedziolka-Jonsson J, Sobczak J, Woisel P, Lyskawa J, Opallo M, Boukherroub R, Szunerits S, ACS Appl. Mater. Interfaces, 4, 1016 (2012)
Lo CW, Zhu D, Jiang H, Soft Matter, 7, 5604 (2011)
Zhou L, Liu H, Zhang X, J. Appl. Polym. Sci., 132, 41987 (2015)
Wu LM, Liao SQ, Zhang SJ, Bai XY, Hou X, Chin. J. Polym. Sci., 33, 1058 (2015)
Li W, Wang M, Yue Y, Ji W, Ren R, RSC Adv., 6, 54410 (2016)
Li Q, Chen W, Yan W, Zhang Q, Yi C, Wang X, Xu Z, RSC Adv., 6, 716 (2016)
Sun S, Wu P, J. Mater. Chem., 21, 4095 (2011)
Kumar M, Chung JS, Kong BS, Kim EJ, Hur SH, Mater. Lett., 106, 319 (2013)
McGrail BT, Rodier BJ, Pentzer E, Chem. Mater., 26, 5806 (2014)
Lee S, Lee H, Sim JH, Sohn D, Macromol. Res., 22, 165 (2013)
Graphene: first ‘wonder material’ products hit the market, Accessed 2017 Aug 09, Available from: http://www.physics.manchester.ac.uk/our-research/research-impact/graphene/.
Sanchez VC, Jachak A, Hurt RH, Kane AB, Chem. Res. Toxicol., 25, 15 (2012)
Schinwald A, Murphy FA, Jones A, MacNee W, Donaldson K, ACS Nano, 736 (2012)
Graphene’s global race to market, Accessed 2017 Aug 10, Available from: http://cen.acs.org/articles/94/i15/Graphenes-global-race-market.html.
Kim H, Abdala AA, Macosko CW, Macromolecules, 43(16), 6515 (2010)
Zurutuza A, Marinelli C, Nat. Nanotechnol., 9(10), 730 (2014)
Ji X, Xu Y, Zhang W, Cui L, Liu J, Compos. Pt. A-Appl. Sci. Manuf., 87, 29 (2016)
Novoselov KS, Geim AK, Morozov SV, Jiang D, Zhang Y, Dubonos SV, Grigorieva IV, Firsov AA, Science, 306, 666 (2004)
Geim AK, Novoselov KS, Nat. Mater., 6(3), 183 (2007)
Ferrari AC, Bonaccorso F, Fal’ko V, Novoselov KS, Roche S, Boggild P, Borini S, Koppens FH, Palermo V, Pugno N, et al., Nanoscale, 7, 4598 (2015)
Lee HC, Liu WW, Chai SP, Mohamed AR, Lai CW, Khe CS, Voon CH, Hashim U, Hidayah NMS, Procedia Chem., 19, 916 (2016)
Geng DC, Wang HP, Yu G, Adv. Mater., 27(18), 2821 (2015)
Li XS, Colombo L, Ruoff RS, Adv. Mater., 28(29), 6247 (2016)
Zhu YW, Murali S, Cai WW, Li XS, Suk JW, Potts JR, Ruoff RS, Adv. Mater., 22(35), 3906 (2010)
Chabot V, Higgins D, Yu A, Xiao X, Chen Z, Zhang J, Energy Environ. Sci., 7, 1564 (2014)
Kumar SK, Benicewicz BC, Vaia RA, Winey KI, Macromolecules, 50(3), 714 (2017)
Szabo T, Berkesi O, Forgo O, Josepovits K, Sanakis Y, Petridis D, Dekany I, Chem. Mater., 18, 2740 (2006)
Dreyer DR, Park S, Bielawski CW, Ruoff RS, Chem. Soc. Rev., 39, 228 (2010)
Cai M, Thorpe D, Adamson DH, Schniepp HC, J. Mater. Chem., 22, 24992 (2012)
Compton OC, An Z, Putz KW, Hong BJ, Hauser BG, Brinson LC, Nguyen ST, Carbon, 50, 3399 (2012)
Ogino I, Yokoyama Y, Iwamura S, Mukai SR, Chem. Mater., 26, 3334 (2014)
Stankovich S, Dikin DA, Piner RD, Kohlhaas KA, Kleinhammes A, Jia Y, Wu Y, Nguyen ST, Ruoff RS, Carbon, 45, 1558 (2007)
Li D, Muller MB, Gilje S, Kaner RB, Wallace GG, Nat. Nanotechnol., 3(2), 101 (2008)
Zhang J, Yang H, Shen G, Cheng P, Zhang J, Guo S, Chem. Commun., 46, 1112 (2010)
Pei S, Zhao J, Du J, Ren W, Cheng HM, Carbon, 48, 4466 (2010)
Pham HD, Pham VH, Cuong TV, Nguyen-Phan TD, Chung JS, Shin EW, Kim S, Chem. Commun., 47, 9672 (2011)
Pham HD, Pham VH, Oh ES, Chung JS, Kim S, Korean J. Chem. Eng., 29, 125 (2011)
Bo Z, Shuai X, Mao S, Yang H, Qian J, Chen J, Yan J, Cen K, Sci. Rep., 4, 4684 (2014)
Xu L, Xiao G, Chen C, Li R, Mai Y, Sun G, Yan D, J. Mater. Chem., 3, 7498 (2015)
He D, Peng Z, Gong W, Luo Y, Zhao P, Kong L, RSC Adv., 5, 11966 (2015)
Yang D, Velamakanni A, Bozoklu G, Park S, Stoller M, Piner RD, Stankovich S, Jung I, Field DA, Ventrice CA, Ruoff RS, Carbon, 47, 145 (2009)
Xu YX, Sheng KX, Li C, Shi GQ, ACS Nano, 4, 4324 (2010)
Chen WF, Li SR, Chen CH, Yan LF, Adv. Mater., 23(47), 5679 (2011)
Kang DW, Shin HS, Carbon Lett., 13, 39 (2012)
Loryuenyong V, Totepvimarn K, Eimburanapravat P, Boonchompoo W, Buasri A, Adv. Mater. Sci. Eng., 2013, 1 (2013)
Pham VH, Dang TT, Cuong TV, Hur SH, Kong BS, Kim EJ, Chung JS, Korean J. Chem. Eng., 29(5), 680 (2012)
Mkhoyan KA, Contryman AW, Silcox J, Stewart DA, Eda G, Mattevi C, Miller S, Chhowalla M, Nano Lett., 9, 1058 (2009)
Botas C, Alvarez P, Blanco C, Santamaria R, Granda M, Gutierrez MD, Rodriguez-Reinoso F, Menendez R, Carbon, 52, 476 (2013)
Zhou S, Bongiorno A, Acc. Chem. Res., 47, 3331 (2014)
Ban S, Xie J, Wang Y, Jing B, Liu B, Zhou H, ACS Appl. Mater. Interfaces, 8, 321 (2016)
Kim S, Zhou S, Hu YK, Acik M, Chabal YJ, Berger C, de Heer W, Bongiorno A, Riedo E, Nat. Mater., 11(6), 544 (2012)
He S, Chen W, Nanoscale, 7, 6957 (2015)
Mao S, Lu G, Chen J, Nanoscale, 7, 6924 (2015)
Hong JY, Wie JJ, Xu Y, Park HS, Phys. Chem. Chem. Phys., 17, 30946 (2015)
Jang H, Park YJ, Chen X, Das T, Kim MS, Ahn JH, Adv. Mater., 28(22), 4184 (2016)
Ge J, Zhao HY, Zhu HW, Huang J, Shi LA, Yu SH, Adv. Mater., 28(47), 10459 (2016)
Wang M, Duan X, Xu Y, Duan X, ACS Nano, 10, 7231 (2016)
Swain SS, Unnikrishnan L, Mohanty S, Nayak SK, Korean J. Chem. Eng., 34(8), 2119 (2017)
Park YT, Qian YQ, Chan C, Suh T, Nejhad MG, Macosko CW, Stein A, Adv. Funct. Mater., 25(4), 575 (2015)
Ha H, Park J, Ha K, Freeman BD, Ellison CJ, Polymer, 93, 53 (2016)
Ha H, Shanmuganathan K, Ellison CJ, ACS Appl. Mater. Interfaces, 7, 6220 (2015)
Liao KH, Mittal A, Bose S, Leighton C, Mkhoyan KA, Macosko CW, ACS Nano, 5, 1253 (2011)
He SY, Petkovich ND, Liu KW, Qian YQ, Macosko CW, Stein A, Polymer, 110, 149 (2017)
Zhang Y, Zhu YW, Lin G, Ruoff RS, Hu NP, Schaefer DW, Mark JE, Polymer, 54(14), 3605 (2013)
Shi H, Shi D, Li C, Luan S, Yin J, Li RKY, Mater. Lett., 133, 200 (2014)
Sharp N, Li CY, Strachan A, Adams D, Pipes RB, J. Polym. Sci. B: Polym. Phys., 55(15), 1150 (2017)
Jeong HK, Lee YP, Jin MH, Kim ES, Bae JJ, Lee YH, Chem. Phys. Lett., 470(4-6), 255 (2009)
Park S, Dikin DA, Nguyen ST, Ruoff RS, J. Phys. Chem., 113, 15801 (2009)
Ye S, Feng J, Wu P, J. Mater. Chem., 1, 3495 (2013)
Ha H, Park J, Ando S, Bin Kim C, Nagai K, Freeman BD, Ellison CJ, J. Membr. Sci., 518, 131 (2016)
Vacchi IA, Spinato C, Raya J, Bianco A, Menard-Moyon C, Nanoscale8, 13714, 2016
Hu X, Qi R, Zhu J, Lu J, Luo Y, Jin J, Jiang P, J. Appl. Polym. Sci., 131, 39754 (2014)
Li W, Shang T, Yang W, Yang H, Lin S, Jia X, Cai Q, Yang X, ACS Appl. Mater. Interfaces, 8, 13037 (2016)
Acocella MR, Corcione CE, Giuri A, Maggio M, Maffezzoli A, Guerra G, RSC Adv., 6, 23858 (2016)
Ha H, Ha K, Ellison CJ, J. Polym. Sci. B: Polym. Phys., 55(18), 1406 (2017)
Zhou X, Chen Z, Yan D, Lu H, J. Mater. Chem., 22, 13506 (2012)
Sui ZY, Cui Y, Zhu JH, Han BH, ACS Appl. Mater. Interfaces, 5, 9172 (2013)
Layek RK, Nandi AK, Polymer, 54(19), 5087 (2013)
Xie ZT, Fu X, Wei LY, Luo MC, Liu YH, Ling FW, Huang C, Huang GS, Wu JR, Polymer, 118, 30 (2017)
Song N, Yang JW, Ding P, Tang SF, Liu YM, Shi LY, Ind. Eng. Chem. Res., 53(51), 19951 (2014)
Kaminska I, Das MR, Coffinier Y, Niedziolka-Jonsson J, Sobczak J, Woisel P, Lyskawa J, Opallo M, Boukherroub R, Szunerits S, ACS Appl. Mater. Interfaces, 4, 1016 (2012)
Lo CW, Zhu D, Jiang H, Soft Matter, 7, 5604 (2011)
Zhou L, Liu H, Zhang X, J. Appl. Polym. Sci., 132, 41987 (2015)
Wu LM, Liao SQ, Zhang SJ, Bai XY, Hou X, Chin. J. Polym. Sci., 33, 1058 (2015)
Li W, Wang M, Yue Y, Ji W, Ren R, RSC Adv., 6, 54410 (2016)
Li Q, Chen W, Yan W, Zhang Q, Yi C, Wang X, Xu Z, RSC Adv., 6, 716 (2016)
Sun S, Wu P, J. Mater. Chem., 21, 4095 (2011)
Kumar M, Chung JS, Kong BS, Kim EJ, Hur SH, Mater. Lett., 106, 319 (2013)
McGrail BT, Rodier BJ, Pentzer E, Chem. Mater., 26, 5806 (2014)
Lee S, Lee H, Sim JH, Sohn D, Macromol. Res., 22, 165 (2013)
Graphene: first ‘wonder material’ products hit the market, Accessed 2017 Aug 09, Available from: http://www.physics.manchester.ac.uk/our-research/research-impact/graphene/.
Sanchez VC, Jachak A, Hurt RH, Kane AB, Chem. Res. Toxicol., 25, 15 (2012)
Schinwald A, Murphy FA, Jones A, MacNee W, Donaldson K, ACS Nano, 736 (2012)
Graphene’s global race to market, Accessed 2017 Aug 10, Available from: http://cen.acs.org/articles/94/i15/Graphenes-global-race-market.html.
