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Received February 3, 2017
Accepted November 5, 2017
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Biosorptive removal of arsenite and arsenate from aqueous medium using low-cost adsorbent derived from ‘Pods of green peas’: Exploration of kinetics, thermodynamics and adsorption isotherms
Department of Chemistry, Birla Institute of Technology, Mesra, Ranchi 835215, Jharkhand, India 1Department of Chemistry, University Polytechnic, Birla Institute of Technology, Mesra, Ranchi, 835215, Jharkhand, India
ashishanand8ktr@gmail.com
Korean Journal of Chemical Engineering, February 2018, 35(2), 456-469(14), 10.1007/s11814-017-0303-y
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Abstract
The present work explores the biosorption characteristics of pods of green peas (PGP) for arsenite [As(III)] and arsenate [As(V)] removal from aqueous medium. Optimization of adsorption parameters like contact time, arsenic concentration, temperature, biosorbent dose and pH through batch mode of experiments was studied. Among the different isotherm models, Langmuir for As(III) and Temkin for As(V) provided the best fit for the obtained data of_x000D_
arsenic sorption onto PGP. D-R mean free energy (E) indicates the process is physisorption. Thermodynamics studies were found to be endothermic, feasible and spontaneous. Kinetically, adsorption follows the pseudo-second-order kinetics in sorption of As(III) and As(V) both. The desorption studies of exhausted PGP show 81% of As(III) and 72% of As(V) could be leached out. Reusability of biosorbent up to 7th cycles of incessant operation supports their commercial importance with very little effects of common ions on sorption capacity.
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Ghimire KN, Inoue K, Makino K, Miyajima T, Sep. Sci. Technol., 37(12), 2785 (2002)
Liu X, Ao H, Xiong X, Xiao J, Liu J, Water Air Soil Pollut., 223, 1033 (2012)
Pehlivan E, Tran H, Ouedraogo W, Schmidt C, Zachmann D, Bahadir M, Food Chem., 138, 133 (2013)
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Bhattacharjee S, Chakravarty S, Maity S, Dureja V, Gupta K, Chemosphere, 58, 1203 (2005)
Roy E, Patra S, Madhuri R, Sharma PK, Chem. Eng. J., 304, 259 (2016)
Smedley P, Kinniburgh D, Appl. Geochem., 17, 517 (2002)
Basu A, Saha D, Saha R, Ghosh T, Saha B, Res. Chem. Intermed., 40, 447 (2014)
Mohan D, Pittman CU, J. Hazard. Mater., 142(1-2), 1 (2007)
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Mandal BK, Suzuki KT, Talanta, 58, 201 (2002)
Shakoor MB, Niazi NK, Bibi I, Murtaza G, Kunhikrishnan A, Seshadri B, Shahid M, Ali S, Bolan NS, Ok YS, Crit. Rev. Environ. Sci. Technol., 46, 467 (2016)
Ferguson JF, Gavis J, Water Res., 6, 1259 (1972)
Roy P, Saha A, Current Sci., 82, 38 (2002)
Baidya K, Raj A, Mondal L, Bhaduri G, Todani A, J. Ocular Pharmacol. Therap., 22, 208 (2006)
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Baskan MB, Pala A, Desalination, 281, 396 (2011)
Viraraghavan T, Subramanian K, Aruldoss J, Water Sci. Technol., 40, 69 (1999)
Gholami MM, Mokhtari MA, Aameri A, Fard MRA, Desalination, 200(1-3), 725 (2006)
Ouedraogo IW, Pehlivan E, Tran HT, Pare S, Bonzi-Coulibaly YL, Zachmann D, Bahadir M, Toxicol. Environ. Chem., 98, 736 (2016)
Ashraf A, Bibi I, Niazi NK, Ok YS, Murtaza G, Shahid M, Kunhikrishnan A, Li D, Mahmood T, Int. J. Phytorem., 19, 605 (2017)
Baig JA, Kazi TG, Shah AQ, Kandhro GA, Afridi HI, Khan S, Kolachi NF, J. Hazard. Mater., 178(1-3), 941 (2010)
Shafique U, Ijaz A, Salman M, uz Zaman W, Jamil N, Rehman R, Javaid A, J. Taiwan Ins. Chem. Eng., 43, 256 (2012)
Ranjan D, Talat M, Hasan SH, J. Hazard. Mater., 166(2-3), 1050 (2009)
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Choi WS, Han JH, J. Food Sci., 66, 319 (2001)
Wen Q, Wu Y, Zhao LX, Sun Q, Kong FY, J. Zhejiang Univer Sci. B, 11, 87 (2010)
Yan YG, Tay JH, Water Res., 31, 1573 (1997)
Liu X, Ao H, Xiong X, Xiao J, Liu J, Water Air Soil Pollut., 223, 1033 (2012)
Gupta A, Sankararamakrishnan N, Bioresour. Technol., 101(7), 2173 (2010)
Krishnan KA, Sreejalekshmi KG, Baiju RS, Bioresour. Technol., 102(22), 10239 (2011)
Ali I, Gupta V, Nat. Protocol., 1, 2661 (2006)
Lagergren S, Eur. Polym. J., 9, 525 (1898)
Roy P, Mondal NK, Bhattacharya S, Das B, Das K, Appl. Water Sci., 3, 293 (2013)
Ho YS, McKay G, Process Biochem., 34(5), 451 (1999)
Singh KK, Talat M, Hasan SH, Bioresour. Technol., 97(16), 2124 (2006)
Kuppusamy S, Thavamani P, Megharaj M, Venkateswarlu K, Lee YB, Naidu R, Process Saf. Environ. Protect., 100, 173 (2016)
Jha R, Jha U, Dey R, Mishra S, Swain S, Desalin. Water Treat., 53, 2144 (2015)
Gupta VK, Nayak A, Agarwal S, Environ. Eng. Res., 20, 1 (2015)
Leist M, Casey RJ, Caridi D, J. Hazard. Mater., 76(1), 125 (2000)
Kundu S, Gupta AK, Chem. Eng. J., 122(1-2), 93 (2006)
Singh KK, Rastogi R, Hasan SH, J. Hazard. Mater., 121(1-3), 51 (2005)
Rezaei H, Arabian J. Chem., 9, 846 (2016)
Pandey PK, Choubey S, Verma Y, Pandey M, Chandrashekhar K, Bioresour. Technol., 100(2), 634 (2009)
Karthik R, Meenakshi S, J. Water Proc. Eng., 1, 37 (2014)
Dehghani MH, Zarei A, Mesdaghinia A, Nabizadeh R, Alimohammadi M, Afsharnia M, Korean J. Chem. Eng., 34, 757 (2015)
Namasivayam C, Sureshkumar MV, Bioresour. Technol., 99(7), 2218 (2008)
Maji SK, Pal A, Pal T, J. Hazard. Mater., 151(2-3), 811 (2008)
Mohan D, Pittman CU, J. Hazard. Mater., 137(2), 762 (2006)
Ncibi MC, J. Hazard. Mater., 153(1-2), 207 (2008)
Ho YS, Water Res., 37, 2323 (2003)
Igwe J, Abia A, Glob. J. Environ. Res., 1, 22 (2007)
Okafor P, Okon P, Daniel E, Ebenso E, Int. J. Electrochem. Sci., 7, 12354 (2012)
Shafique U, Ijaz A, Salman M, uz Zaman W, Jamil N, Rehman R, Javaid A, J. Taiwan Inst. Chem. Eng., 43, 256 (2012)
Kamsonlian S, Suresh S, Ramanaiah V, Majumder C, Chand S, Kumar A, Int. J. Environ. Sci. Technol., 9, 565 (2012)
Marin-Rangel VM, Cortes-Martinez R, Villanueva RAC, Garnica-Romo M, Martinez-Flores HE, J. Food Sci., 77, T10 (2012)
Tian Y, Wu M, Lin XB, Huang P, Huang Y, J. Hazard. Mater., 193, 10 (2011)
Ranjan D, Talat M, Hasan SH, J. Hazard. Mater., 166(2-3), 1050 (2009)
Anirudhan T, Unnithan MR, Chemosphere, 66, 60 (2007)
Ghimire KN, Inoue K, Makino K, Miyajima T, Sep. Sci. Technol., 37(12), 2785 (2002)
Liu X, Ao H, Xiong X, Xiao J, Liu J, Water Air Soil Pollut., 223, 1033 (2012)
Pehlivan E, Tran H, Ouedraogo W, Schmidt C, Zachmann D, Bahadir M, Food Chem., 138, 133 (2013)
Bibi S, Farooqi A, Yasmeen A, Kamran MA, Niazi NK, Intern. J. Phytorem. (2017).
