Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received June 19, 2017
Accepted October 7, 2017
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
Aminosilane grafted Matrimid 5218/nano-silica mixed matrix membrane for CO2/light gases separation
Elham Nezhadmoghadam
Mahdi Pourafshari Chenar
Mohammdreza Omidkhah1
Amir Nezhadmoghadam
Reza Abedini2†
Department of Chemical Engineering, Faculty of Engineering, Ferdowsi University of Mashhad, Mashhad, Iran 1Faculty of Chemical Engineering, Tarbiat Modares University, Tehran, Iran 2Faculty of Chemical Engineering, Babol Noshirvani University of Technology, Babol, Iran
abedini@nit.ac.ir
Korean Journal of Chemical Engineering, February 2018, 35(2), 526-534(9), 10.1007/s11814-017-0282-z
Download PDF
Abstract
The influence of amino-grafted nano-silica particles on the CO2/light gases separation performance of Matrimid mixed matrix membrane was evaluated. The aminosilane grafting reaction was performed using (3-aminopropyl) terimethoxysilane (APTMOS) as a silane coupling agent. Prepared membranes were studied through various methods including FTIR, SEM and TGA. To evaluate the gas separation performance, pure CO2, CH4, N2 and O2 permeation tests were conducted using constant volume-varying pressure set-up with various upstream pressures. Characterization results demonstrated the appropriate dispersion of silica particles within the Matrimid matrix as well as a suitable interaction between polymer/filler phases. Results from the gas permeation study confirmed that the permeability of all gases except CO2, decreased as silica content increased in Matrimid matrix. Nevertheless, the CO2 permeability increased from 4.20 Barrer in neat Matrimid to about 9.59 Barrer at 20 wt% loading of silica. The selectivity of O2/N2, CO2/N2 and CO2/CH4 pair gases was enhanced by increasing the nano-silica content. The selectivity of CO2/N2 and CO2/CH4 was increased from 18.27 to 50.74, and 20.01 to 70.51, respectively.
References
Dorosti F, Omidkhah M, Abedini R, J. Nat. Gas. Sci. Eng., 25, 88 (2015)
Naghsh M, Sadeghi M, Moheb A, Chenar MP, Mohagheghian M, J. Membr. Sci., 423, 97 (2012)
Zhang Y, Sunarsoc J, Liud S, Wang R, Int. J. Greenhouse Gas Cont., 12, 84 (2013)
Abedini R, Omidkhah M, Dorosti F, RSC Adv., 4, 36522 (2014)
Jamshidi M, Pirouzfar V, Abedini R, Pedram MZ, Korean J. Chem. Eng., 34(3), 829 (2017)
Sadeghi M, Semsarzadeh MA, Barikani M, Chenar MP, J. Membr. Sci., 376(1-2), 188 (2011)
Abedini R, Mousavi SM, Aminzadeh R, Desalination, 277(1-3), 40 (2011)
Ahn JY, Chung WJ, Pinnau I, Guiver MD, J. Membr. Sci., 314(1-2), 123 (2008)
Suzuki T, Yamada Y, Polym. Bull., 53(2), 139 (2005)
Sadeghi M, Khanbabaei G, Dehaghani AHS, Sadeghi M, Aravand MA, Akbarzade M, Khatti S, J. Membr. Sci., 322(2), 423 (2008)
Hassanajili S, Khademi M, Keshavarz P, J. Membr. Sci., 453, 369 (2014)
Ghadimi A, Mohammadi T, Kasiri N, Ind. Eng. Chem. Res., 53(44), 17476 (2014)
Bernardo P, Drioli E, Golemme G, Ind. Eng. Chem. Res., 48(10), 4638 (2009)
Beiragh HH, Omidkhah M, Abedini R, Khosravi T, Pakseresht S, Asia-Pac. J. Chem. Eng., 11, 522 (2016)
Amooghin AE, Omidkhah M, Kargari A, RSC Adv., 5, 8552 (2015)
Moghadam F, Omidkhah MR, Vasheghani-Farahani E, Pedram MZ, Dorosti F, Sep. Purif. Technol., 77(1), 128 (2011)
Dorosti F, Omidkhah M, Abedini R, Chem. Eng. Res. Des., 92(11), 2439 (2014)
Inagaki M, Ohta N, Hishiyama Y, Carbon, 61, 1 (2013)
Mohagheghian M, Sadeghi M, Chenar MP, Naghsh M, Korean J. Chem. Eng., 31(11), 2041 (2014)
Japip S, Wang H, Xiao YC, Chung TS, J. Membr. Sci., 467, 162 (2014)
Anjum MW, de Clippel F, Didden J, Khan AL, Couck S, Baron GV, Denayer JFM, Sels BF, Vankelecom IFJ, J. Membr. Sci., 495, 121 (2015)
Pechar TW, Tsapatsis M, Marand E, Davis R, Desalination, 146(1-3), 3 (2002)
Guiver MD, Robertson GP, Dai Y, Bilodeau F, Kang YS, Lee KJ, Jho JY, Won J, J. Polym. Sci. A: Polym. Chem., 40(23), 4193 (2002)
Abedini R, Mousavi SM, Aminzadeh R, Chem. Ind. Chem. Eng. Q., 18, 385 (2012)
Sadeghi M, Talakesh MM, Ghalei B, Shafiei M, J. Membr. Sci., 427, 21 (2013)
Semsarzadeh MA, Ghalei B, J. Membr. Sci., 432, 115 (2013)
Sadeghi M, Semsarzadeh MA, Moadel H, J. Membr. Sci., 331(1-2), 21 (2009)
Nematollahi MH, Dehaghani AHS, Abedini R, Korean J. Chem. Eng., 33(2), 657 (2016)
Wu L, Sun J, Chen Y, Mater. Des., 92, 610 (2016)
Abedini R, Omidkhah M, Dorosti F, Int. J. Hydrog. Energy, 39(15), 7897 (2014)
Naghsh M, Sadeghi M, Moheb A, Chenar MP, Mohagheghian M, J. Membr. Sci., 423, 97 (2012)
Zhang Y, Sunarsoc J, Liud S, Wang R, Int. J. Greenhouse Gas Cont., 12, 84 (2013)
Abedini R, Omidkhah M, Dorosti F, RSC Adv., 4, 36522 (2014)
Jamshidi M, Pirouzfar V, Abedini R, Pedram MZ, Korean J. Chem. Eng., 34(3), 829 (2017)
Sadeghi M, Semsarzadeh MA, Barikani M, Chenar MP, J. Membr. Sci., 376(1-2), 188 (2011)
Abedini R, Mousavi SM, Aminzadeh R, Desalination, 277(1-3), 40 (2011)
Ahn JY, Chung WJ, Pinnau I, Guiver MD, J. Membr. Sci., 314(1-2), 123 (2008)
Suzuki T, Yamada Y, Polym. Bull., 53(2), 139 (2005)
Sadeghi M, Khanbabaei G, Dehaghani AHS, Sadeghi M, Aravand MA, Akbarzade M, Khatti S, J. Membr. Sci., 322(2), 423 (2008)
Hassanajili S, Khademi M, Keshavarz P, J. Membr. Sci., 453, 369 (2014)
Ghadimi A, Mohammadi T, Kasiri N, Ind. Eng. Chem. Res., 53(44), 17476 (2014)
Bernardo P, Drioli E, Golemme G, Ind. Eng. Chem. Res., 48(10), 4638 (2009)
Beiragh HH, Omidkhah M, Abedini R, Khosravi T, Pakseresht S, Asia-Pac. J. Chem. Eng., 11, 522 (2016)
Amooghin AE, Omidkhah M, Kargari A, RSC Adv., 5, 8552 (2015)
Moghadam F, Omidkhah MR, Vasheghani-Farahani E, Pedram MZ, Dorosti F, Sep. Purif. Technol., 77(1), 128 (2011)
Dorosti F, Omidkhah M, Abedini R, Chem. Eng. Res. Des., 92(11), 2439 (2014)
Inagaki M, Ohta N, Hishiyama Y, Carbon, 61, 1 (2013)
Mohagheghian M, Sadeghi M, Chenar MP, Naghsh M, Korean J. Chem. Eng., 31(11), 2041 (2014)
Japip S, Wang H, Xiao YC, Chung TS, J. Membr. Sci., 467, 162 (2014)
Anjum MW, de Clippel F, Didden J, Khan AL, Couck S, Baron GV, Denayer JFM, Sels BF, Vankelecom IFJ, J. Membr. Sci., 495, 121 (2015)
Pechar TW, Tsapatsis M, Marand E, Davis R, Desalination, 146(1-3), 3 (2002)
Guiver MD, Robertson GP, Dai Y, Bilodeau F, Kang YS, Lee KJ, Jho JY, Won J, J. Polym. Sci. A: Polym. Chem., 40(23), 4193 (2002)
Abedini R, Mousavi SM, Aminzadeh R, Chem. Ind. Chem. Eng. Q., 18, 385 (2012)
Sadeghi M, Talakesh MM, Ghalei B, Shafiei M, J. Membr. Sci., 427, 21 (2013)
Semsarzadeh MA, Ghalei B, J. Membr. Sci., 432, 115 (2013)
Sadeghi M, Semsarzadeh MA, Moadel H, J. Membr. Sci., 331(1-2), 21 (2009)
Nematollahi MH, Dehaghani AHS, Abedini R, Korean J. Chem. Eng., 33(2), 657 (2016)
Wu L, Sun J, Chen Y, Mater. Des., 92, 610 (2016)
Abedini R, Omidkhah M, Dorosti F, Int. J. Hydrog. Energy, 39(15), 7897 (2014)
