Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received August 21, 2017
Accepted October 25, 2017
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
Simple modification with amine- and hydroxyl- group rich biopolymer on ordered mesoporous carbon/sulfur composite for lithium-sulfur batteries
1Department of Chemical Engineering, Pohang University of Science & Technology, 77 Cheongam-ro, Nam-gu, Pohang, Gyeongbuk 37673, Korea 2School of Environmental Science and Engineering and Division of Interdisciplinary Bioscience and Bioengineering, Pohang University of Science & Technology, 77 Cheongam-ro, Nam-gu, Pohang, Gyeongbuk 37673, Korea 3**School of Environmental Science and Engineering and Division of Interdisciplinary Bioscience and Bioengineering, Pohang University of Science & Technology, 77 Cheongam-ro, Nam-gu, Pohang, Gyeongbuk 37673, Korea 4Ocean Science and Technology Institute, Pohang University of Science and Technology, 77 Cheongam-ro, Nam-gu, Pohang, Gyeongbuk 37673, Korea
jinwoo03@postech.ac.kr
Korean Journal of Chemical Engineering, February 2018, 35(2), 579-586(8), 10.1007/s11814-017-0302-z
Download PDF
Abstract
Lithium-sulfur (Li-S) batteries are promising next generation batteries, and numerous porous carbons have been considered as the support materials for sulfur to address dissolution of poylsulfide. However, the weak binding energy of carbon with sulfur species causes poor cycle performance. We report that amine- and hydroxyl-rich biopolymer (chitosan) coated on ordered mesoporous carbon (OMC) can effectively capture soluble polysulfide. The strong binding of chitosan’s amine- and hydroxyl-group with the polysulfides prevents dissolution of soluble intermediates and assists dispersion of insulating final products. In addition, as chitosan is insoluble in the electrolyte, chitosan coating on the cathode sustainably increases cycle stability and coulombic efficiency of Li-S batteries. Initial coulombic efficiency of chitosan modified OMC/S composite was 81.7% and specific capacities of chitosan modified OMC/S composite were 32.4% and 51.6% higher than those of bare OMC/S composite at 100th and 140th cycle, respectively.
Keywords
References
Arico AS, Bruce P, Scrosati B, Tarascon JM, Van Schalkwijk W, Nat. Mater., 4(5), 366 (2005)
Park H, Yeom DH, Kim J, Lee JK, Korean J. Chem. Eng., 32(1), 178 (2015)
Tarascon JM, Armand M, Nature, 414, 359 (2001)
Venugopal N, Kim WS, Yu T, Korean J. Chem. Eng., 33(4), 1500 (2016)
Armstrong AR, Bruce PG, Nature, 381(6582), 499 (1996)
Cho J, Kim YJ, Park B, Chem. Mater., 12, 3788 (2000)
Jiao F, Shaju KM, Bruce PG, Angew. Chem.-Int. Edit., 44, 6550 (2005)
Kang KM, Kim HW, Kwak HY, Korean J. Chem. Eng., 33(2), 688 (2016)
Mizushima K, Jones P, Wiseman P, Goodenough J, Mater. Res. Bull., 15, 783 (1980)
Vu DL, Lee JW, Korean J. Chem. Eng., 33(2), 514 (2016)
Xu G, Ding B, Pan J, Nie P, Shen L, Zhang X, J. Mater. Chem., 2, 12662 (2014)
Bruce PG, Freunberger SA, Hardwick LJ, Tarascon JM, Nat. Mater., 11(1), 19 (2012)
Yeon SH, Ahn W, Shin KH, Jin CS, Jung KN, Jeon JD, Lim S, Kim Y, Korean J. Chem. Eng., 32(5), 867 (2015)
Hofmann AF, Fronczek DN, Bessler WG, J. Power Sources, 259, 300 (2014)
Ji X, Nazar LF, J. Mater. Chem., 20, 9821 (2010)
Manthiram A, Fu Y, Su YS, Acc. Chem. Res., 46, 1125 (2012)
Yin YX, Xin S, Guo YG, Wan LJ, Angew. Chem.-Int. Edit., 52, 13186 (2013)
Lee J, Kim J, Hyeon T, Adv. Mater., 18(16), 2073 (2006)
Ye Y, Jo C, Jeong I, Lee J, Nanoscale, 5, 4584 (2013)
Ji XL, Lee KT, Nazar LF, Nat. Mater., 8(6), 500 (2009)
Li X, Cao Y, Qi W, Saraf LV, Xiao J, Nie Z, Mietek J, Zhang JG, Schwenzer B, Liu J, J. Mater. Chem., 21, 16603 (2011)
Werner JG, Johnson SS, Vijay V, Wiesner U, Chem. Mater., 27, 3349 (2015)
Jayaprakash N, Shen J, Moganty SS, Corona A, Archer LA, Angew. Chem.-Int. Edit., 123, 6026 (2011)
Zhou W, Xiao X, Cai M, Yang L, Nano Lett., 14, 5250 (2014)
He G, Ji X, Nazar L, Energy Environ. Sci., 4, 2878 (2011)
Xin S, Gu L, Zhao NH, Yin YX, Zhou LJ, Guo YG, Wan LJ, J. Am. Chem. Soc., 134(45), 18510 (2012)
Yang Y, Zheng GY, Misra S, Nelson J, Toney MF, Gui Y, J. Am. Chem. Soc., 134(37), 15387 (2012)
Kim JH, Kim T, Jeong YC, Lee K, Park KT, Yang SJ, Park CR, Adv. Eng. Mater., 5, 150026 (2015)
Li GC, Li GR, Ye SH, Gao XP, Adv. Eng. Mater., 2, 1238 (2012)
Ma L, Zhuang HL, Wei S, Hendrickson KE, Kim MS, Cohn G, Hennig RG, Archer LA, ACS Nano, 10, 1050 (2015)
Yang Y, Yu G, Cha JJ, Wu H, Vosgueritchian M, Yao Y, Bao Z, Cui Y, ACS Nano, 5, 9187 (2011)
Zheng G, Zhang Q, Cha JJ, Yang Y, Li W, Seh ZW, Cui Y, Nano Lett., 13, 1265 (2013)
Zhou G, Yin LC, Wang DW, Li L, Pei S, Gentle IR, Li F, Cheng HM, ACS Nano, 7, 5367 (2013)
Zu C, Manthiram A, Adv. Eng. Mater., 3, 1008 (2013)
Khor E, Lim LY, Biomaterials, 24, 2339 (2003)
Klemm D, Heublein B, Fink HP, Bohn A, Angew. Chem.-Int. Edit., 44, 3358 (2005)
Raymundo-Pinero E, Leroux F, Beguin F, Adv. Mater., 18(14), 1877 (2006)
Fanous J, Wegner M, Grimminger J, Andresen AN, Buchmeiser MR, Chem. Mater., 23, 5024 (2011)
Fu Y, Manthiram A, Chem. Mater., 24, 3081 (2012)
Wang L, He X, Li J, Gao J, Guo J, Jiang C, Wan C, J. Mater. Chem., 22, 22077 (2012)
Wu F, Chen J, Li L, Zhao T, Chen R, J. Phys. Chem., 115, 24411 (2011)
Zhou W, Yu Y, Chen H, DiSalvo FJ, Abruna HCD, J. Am. Ceram. Soc., 135, 16736 (2013)
Lee DW, Lim C, Israelachvili JN, Hwang DS, Langmuir, 29, 14222 (2013)
Lim C, Lee DW, Israelachvili JN, Jho Y, Hwang DS, Carbohydr. Polym., 117, 887 (2015)
Zu C, Manthiram A, Adv. Eng. Mater., 3, 1008 (2013)
Jun S, Joo SH, Ryoo R, Kruk M, Jaroniec M, Liu Z, Ohsuna T, Terasaki O, J. Am. Chem. Soc., 122(43), 10712 (2000)
Liang X, Hart C, Pang Q, Garsuch A, Weiss T, Nazar LF, Nat. Commun., 6, 5682 (2015)
Zhang SS, Electrochim. Acta, 70, 344 (2012)
Wang C, Wan W, Chen JT, Zhou HH, Zhang XX, Yuan LX, Huang YH, J. Mater. Chem., 1, 1716 (2013)
Kim HJ, Bae IS, Cho SJ, Boo JH, Lee BC, Heo J, Chung I, Hong B, Nanoscale Res. Lett., 7, 1 (2012)
Pang Q, Tang JT, Huang H, Liang X, Hart C, Tam KC, Nazar LF, Adv. Mater., 27(39), 6021 (2015)
Fu Y, Su YS, Manthiram A, ACS Appl. Mater. Interfaces, 4, 6046 (2012)
Park H, Yeom DH, Kim J, Lee JK, Korean J. Chem. Eng., 32(1), 178 (2015)
Tarascon JM, Armand M, Nature, 414, 359 (2001)
Venugopal N, Kim WS, Yu T, Korean J. Chem. Eng., 33(4), 1500 (2016)
Armstrong AR, Bruce PG, Nature, 381(6582), 499 (1996)
Cho J, Kim YJ, Park B, Chem. Mater., 12, 3788 (2000)
Jiao F, Shaju KM, Bruce PG, Angew. Chem.-Int. Edit., 44, 6550 (2005)
Kang KM, Kim HW, Kwak HY, Korean J. Chem. Eng., 33(2), 688 (2016)
Mizushima K, Jones P, Wiseman P, Goodenough J, Mater. Res. Bull., 15, 783 (1980)
Vu DL, Lee JW, Korean J. Chem. Eng., 33(2), 514 (2016)
Xu G, Ding B, Pan J, Nie P, Shen L, Zhang X, J. Mater. Chem., 2, 12662 (2014)
Bruce PG, Freunberger SA, Hardwick LJ, Tarascon JM, Nat. Mater., 11(1), 19 (2012)
Yeon SH, Ahn W, Shin KH, Jin CS, Jung KN, Jeon JD, Lim S, Kim Y, Korean J. Chem. Eng., 32(5), 867 (2015)
Hofmann AF, Fronczek DN, Bessler WG, J. Power Sources, 259, 300 (2014)
Ji X, Nazar LF, J. Mater. Chem., 20, 9821 (2010)
Manthiram A, Fu Y, Su YS, Acc. Chem. Res., 46, 1125 (2012)
Yin YX, Xin S, Guo YG, Wan LJ, Angew. Chem.-Int. Edit., 52, 13186 (2013)
Lee J, Kim J, Hyeon T, Adv. Mater., 18(16), 2073 (2006)
Ye Y, Jo C, Jeong I, Lee J, Nanoscale, 5, 4584 (2013)
Ji XL, Lee KT, Nazar LF, Nat. Mater., 8(6), 500 (2009)
Li X, Cao Y, Qi W, Saraf LV, Xiao J, Nie Z, Mietek J, Zhang JG, Schwenzer B, Liu J, J. Mater. Chem., 21, 16603 (2011)
Werner JG, Johnson SS, Vijay V, Wiesner U, Chem. Mater., 27, 3349 (2015)
Jayaprakash N, Shen J, Moganty SS, Corona A, Archer LA, Angew. Chem.-Int. Edit., 123, 6026 (2011)
Zhou W, Xiao X, Cai M, Yang L, Nano Lett., 14, 5250 (2014)
He G, Ji X, Nazar L, Energy Environ. Sci., 4, 2878 (2011)
Xin S, Gu L, Zhao NH, Yin YX, Zhou LJ, Guo YG, Wan LJ, J. Am. Chem. Soc., 134(45), 18510 (2012)
Yang Y, Zheng GY, Misra S, Nelson J, Toney MF, Gui Y, J. Am. Chem. Soc., 134(37), 15387 (2012)
Kim JH, Kim T, Jeong YC, Lee K, Park KT, Yang SJ, Park CR, Adv. Eng. Mater., 5, 150026 (2015)
Li GC, Li GR, Ye SH, Gao XP, Adv. Eng. Mater., 2, 1238 (2012)
Ma L, Zhuang HL, Wei S, Hendrickson KE, Kim MS, Cohn G, Hennig RG, Archer LA, ACS Nano, 10, 1050 (2015)
Yang Y, Yu G, Cha JJ, Wu H, Vosgueritchian M, Yao Y, Bao Z, Cui Y, ACS Nano, 5, 9187 (2011)
Zheng G, Zhang Q, Cha JJ, Yang Y, Li W, Seh ZW, Cui Y, Nano Lett., 13, 1265 (2013)
Zhou G, Yin LC, Wang DW, Li L, Pei S, Gentle IR, Li F, Cheng HM, ACS Nano, 7, 5367 (2013)
Zu C, Manthiram A, Adv. Eng. Mater., 3, 1008 (2013)
Khor E, Lim LY, Biomaterials, 24, 2339 (2003)
Klemm D, Heublein B, Fink HP, Bohn A, Angew. Chem.-Int. Edit., 44, 3358 (2005)
Raymundo-Pinero E, Leroux F, Beguin F, Adv. Mater., 18(14), 1877 (2006)
Fanous J, Wegner M, Grimminger J, Andresen AN, Buchmeiser MR, Chem. Mater., 23, 5024 (2011)
Fu Y, Manthiram A, Chem. Mater., 24, 3081 (2012)
Wang L, He X, Li J, Gao J, Guo J, Jiang C, Wan C, J. Mater. Chem., 22, 22077 (2012)
Wu F, Chen J, Li L, Zhao T, Chen R, J. Phys. Chem., 115, 24411 (2011)
Zhou W, Yu Y, Chen H, DiSalvo FJ, Abruna HCD, J. Am. Ceram. Soc., 135, 16736 (2013)
Lee DW, Lim C, Israelachvili JN, Hwang DS, Langmuir, 29, 14222 (2013)
Lim C, Lee DW, Israelachvili JN, Jho Y, Hwang DS, Carbohydr. Polym., 117, 887 (2015)
Zu C, Manthiram A, Adv. Eng. Mater., 3, 1008 (2013)
Jun S, Joo SH, Ryoo R, Kruk M, Jaroniec M, Liu Z, Ohsuna T, Terasaki O, J. Am. Chem. Soc., 122(43), 10712 (2000)
Liang X, Hart C, Pang Q, Garsuch A, Weiss T, Nazar LF, Nat. Commun., 6, 5682 (2015)
Zhang SS, Electrochim. Acta, 70, 344 (2012)
Wang C, Wan W, Chen JT, Zhou HH, Zhang XX, Yuan LX, Huang YH, J. Mater. Chem., 1, 1716 (2013)
Kim HJ, Bae IS, Cho SJ, Boo JH, Lee BC, Heo J, Chung I, Hong B, Nanoscale Res. Lett., 7, 1 (2012)
Pang Q, Tang JT, Huang H, Liang X, Hart C, Tam KC, Nazar LF, Adv. Mater., 27(39), 6021 (2015)
Fu Y, Su YS, Manthiram A, ACS Appl. Mater. Interfaces, 4, 6046 (2012)
