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Received September 29, 2017
Accepted November 20, 2017
- This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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High Selectivity and removal efficiency of lotus root-based activated carbon towards Fe(III) in La(III) solution
Chemical Department, North University of China, Taiyuan 030051, Shanxi, P. R. China
anfuqiang@nuc.edu.cn
Korean Journal of Chemical Engineering, March 2018, 35(3), 757-763(7), 10.1007/s11814-017-0322-8
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Abstract
Rare earth elements are an important strategic resource. However, a trace of Fe(III) impurity has serious adverse impact on the performance of rare earth materials. We synthesized a novel nitrogen-containing carbon material, ACLR-400, using lotus root as raw materials. The ACLR-400 was characterized by surface area analyzer, elemental analysis and FT-IR. The selectivity and removal efficiency of ACLR-400 towards Fe(III) were also investigated. The BET specific surface area of ACLR-400 was 68.44m2·g-1, and the average pore diameter was 12.54 nm. With abundant nitrogen- containing functional groups and well-developed internal pore structure, ACLR-400 possesses strong adsorption affinity, excellent selectivity and removal efficiency for Fe(III). The adsorption capacity of ACLR-400 towards Fe(III) could reach to 0.46mmol·g-1, selectivity coefficient with respect to La(III) was 8.9, and removal efficiency was 99.61%. The adsorption isotherm data greatly obey the Freundlich isotherm. In addition, ACLR-400 can be regenerated easily and possesses better regeneration ability and reusability.
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Freundlich HMF, Z. Phys. Chem., 57, 385 (1906)