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Received September 21, 2017
Accepted November 23, 2017
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Fully organic CO2 absorbent obtained by a Schiff base reaction between branched poly(ethyleneimine) and glutaraldehyde
Korea Institute of Industrial Technology, 89 Yangdaegiro-gil, Ipjang-myeon, Seobuk-gu, Cheonan-si, Chungcheongnam-do 31056, Korea 1Department of Chemical Engineering, Yonsei University, 134 Shinchon-dong, Seodaemoon-gu, Seoul 03722, Korea
Korean Journal of Chemical Engineering, March 2018, 35(3), 798-804(7), 10.1007/s11814-017-0330-8
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Abstract
We used a water-in-oil emulsification method to prepare particulate CO2 absorbents from branched poly(ethyleneimine) (PEI), utilizing 13C nuclear magnetic resonance spectroscopy to determine the amount of free PEI NH2 groups and thus calculate the required cross-linker amount. The functional groups and reactivity of branched PEI particles were characterized by Fourier transform infrared spectroscopy, and their CO2 absorption capacity was determined by thermogravimetric analysis. Dynamic light scattering measurements showed that the synthesized particles exhibited sizes of 0.2-2 μm and high surface areas, which resulted in high CO2 absorption capacities of up to 2.18 mmol CO2 per gram sorbent at 75 °C.
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Lee MS, Lee SY, Park SJ, Int. J. Hydrog. Energy, 40(8), 3415 (2015)
Liu HJ, Zhong S, Striba SE, Chen Y, Zhang WQ, Wei LH, J. Polym. Sci. A: Polym. Chem., 44(13), 4165 (2006)
Park MR, Han KO, Han IK, Cho MH, Nah JW, Choi YJ, Cho CS, J. Control. Release, 105, 367 (2005)
Petersen H, Fechner PM, Fischer D, Kissel T, Macromolecules, 35(18), 6867 (2002)
Qiu LY, Bae YH, Biomaterials, 28, 4132 (2007)
Pertersen H, Merdan T, Kunath K, Fucher D, Kissel T, Bioconjugate Chem., 13, 812 (2002)
Allcock HR, Austin PE, Macromolecules, 41, 1616 (1981)
Kramer M, Stumbe JF, Grimm G, Kaufmann B, Kruger U, Keber U, Haag R, Chembiochem, 5, 1081 (2004)
Kunath K, J. Control. Release, 89, 113 (2003)
Xia B, Dong C, Lu Y, Rong M, Lv YZ, Shi JS, Thin Solid Films, 520(3), 1120 (2011)
Bhunia MK, Das SK, Pachfule P, Banerjee R, Bhaumik A, Dalton Trans., 41, 1304 (2012)
Pestov AV, Mehaev AV, Kodess MI, Ezhikova MA, Azarova YA, Bratskaya SY, Carbohydr. Polym., 138, 252 (2016)
Rubianes MD, Strumia MC, Electroanalysis, 22, 1200 (2010)
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Elnashar MMM, Yassin MA, Kahil T, J. Appl. Polym. Sci., 109(6), 4105 (2008)
Wang F, Liu P, Nie T, Wei H, Cui Z, Int. J. Mol. Sci., 14, 17 (2012)
