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Received October 27, 2017
Accepted February 2, 2018
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Designed synthesis of silver nanoparticles in responsive polymeric system for their thermally tailored catalytic activity towards hydrogenation reaction
Muhammad Shahid1
Zahoor Hussain Farooqi1†
Robina Begum2
Khalida Naseem1
Muhammad Ajmal3
Ahmad Irfan4 5
1Institute of Chemistry, University of the Punjab, New Campus, Lahore 54590, Pakistan 2Center of Undergraduate Studies, University of the Punjab, New Campus, Lahore 54590, Pakistan 3Department of Chemistry, University of Wah, Wah Cantt 47040, Pakistan 4Research Center for Advanced Materials Science, King Khalid University, P. O. Box 9004, Abha 61413, Saudi Arabia 5Department of Chemistry, Faculty of Science, King Khalid University, P. O. Box 9004, Abha 61413, Saudi Arabia
zhfarooqi@gmail.com, zahoor.chem@pu.edu.pk
Korean Journal of Chemical Engineering, May 2018, 35(5), 1099-1107(9), 10.1007/s11814-018-0016-x
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Abstract
Poly(N-isopropylacrylamide-acrylamide-methacrylic acid) [p(NIPa-AAm-Ma)] polymer microgels were prepared by free radical precipitation polymerization method. AgNPs were fabricated in the sieves of polymer network by chemical reduction using AgNO3 salt as a precursor of silver ions. Various techniques like dynamic light scattering (DLS), transmission electron microscopy (TEM), Fourier transform infrared microscopy (FTIR), and UV-Visible spectroscopy were used for characterization of pure and composite microgels. The diameter of AgNPs fabricated in polymeric network was found to be in the range of 10-15 nm. Stimuli responsive behavior of hybrid microgels was same as that of pure microgels. Catalytic efficiency of the hybrid microgels was investigated by reducing 4-Nitroaniline (4-NA) into 4-Aminoaniline (4-AA) using NaBH4 as reducing agent under different conditions of temperature of the medium, concentration of reducing agent, 4-Nitroaniline and hybrid microgels to explore the catalysis process. Kinetic and thermodynamic aspects of reduction of 4-Nitroaniline in the presence of catalyst were also discussed on the basis of values of Arrhenius and Eyring parameters like pre-exponential factor, activation energy, enthalpy of activation and entropy of activation. Catalytic activity of the hybrid microgels was found to be thermally tunable in the temperature range of 25- 70 °C. The value of rate constant (kapp) for reduction of 4-NA was minimum at 55 °C, which can be attributed to volume phase transition of the hybrid microgels.
References
Bhattacharya S, Eckert F, Boyko V, Pich A, Small, 3(4), 650 (2007)
Karg M, Pastoriza-Santos I, Rodriguez-Gonzalez B, von Klitzing R, Wellert S, Hellweg T, Langmuir, 24(12), 6300 (2008)
Begum R, Naseem K, Ahmed E, Sharif A, Farooqi ZH, Colloids Surf. A: Physicochem. Eng. Asp., 511(1), 17 (2016)
Farooqi ZH, Ijaz A, Begum R, Naseem K, Usman M, Ajmal M, Saeed U, Polym. Compos., 39(3), 645 (2016)
Karg M, Lu Y, Carbo-Argibay E, Pastoriza-Santos I, Perez-Juste J, Liz-Marzan LM, Hellweg T, Langmuir, 25(5), 3163 (2009)
Sivakumaran D, Maitland D, Hoare T, Biomacromolecules, 12(11), 4112 (2011)
Bromberg L, Temchenko M, Hatton TA, Langmuir, 18(12), 4944 (2002)
Lopez VC, Hadgraft J, Snowden M, Int. J. Pharm., 292(1), 137 (2005)
Hoare T, Pelton R, Macromolecules, 40(3), 670 (2007)
Xu SQ, Zhang JG, Paquet C, Lin YK, Kumacheva E, Adv. Funct. Mater., 13(6), 468 (2003)
Zhang JG, Xu SQ, Kumacheva E, J. Am. Chem. Soc., 126(25), 7908 (2004)
Dai G, Quan C, Zhang X, Liu J, Song L, Gan N, Water. Res., 46(5), 1482 (2012)
Nilsson P, Hansson P, J. Phys. Chem. B, 109(50), 23843 (2005)
Bromberg L, Temchenko M, Hatton TA, Langmuir, 19(21), 8675 (2003)
Li P, SenGupta AK, React. Funct. Polym., 44(3), 273 (2000)
Farooqi ZH, Naseem K, Ijaz A, Begum R, J. Polym. Eng., 36(1), 87 (2016)
Farooqi ZH, Khan SR, Begum R, Kanwal F, Sharif A, Ahmed E, Majeed S, Ijaz K, Ijaz A, Turk. J. Chem., 39(1), 96 (2015)
Zhang JT, Wei G, Keller TF, Gallagher H, Stotzel C, Muller FA, Gottschaldt M, Schubert US, Jandt KD, Macromol. Mater. Eng., 295(11), 1049 (2010)
Lai JJ, Hoffman JM, Ebara M, Hoffman AS, Estournes C, Wattiaux A, Stayton PS, Langmuir, 23(13), 7385 (2007)
Zhang Y, Liu H, Fang Y, Chin. J. Chem. Eng., 29(1), 33 (2011)
Naseem K, Begum R, Farooqi ZH, Environ. Sci. Pollut. Res., 24(7), 6446 (2017)
Vimala K, Sivudu KS, Mohan YM, Sreedhar B, Raju KM, Carbohydr. Polym., 75(3), 463 (2009)
Begum R, Naseem K, Farooqi ZH, J. Sol-Gel Sci. Technol., 77, 497 (2016)
Pich A, Karak A, Lu Y, Ghosh AK, Adler HJP, Nanosci. Nanotechnol., 6(12), 3763 (2006)
Pich A, Karak A, Lu Y, Ghosh AK, Adler HJP, Macromol. Rapid Commun., 27(5), 344 (2006)
Liu YY, Liu XY, Yang JM, Lin DL, Chen X, Zha LS, Colloids Surf. A: Physicochem. Eng. Asp., 393(1), 105 (2012)
Wu S, Dzubiella J, Kaiser J, Drechsler M, Guo X, Ballauff M, Lu Y, Agew. Chem. Int. Ed., 51(9), 2229 (2012)
Naseem K, Begum R, Farooqi ZH, Polym. Compos. (2016), DOI:10.1002/pc.24212.
Lu Y, Mei Y, Drechsler M, Ballauff M, Angew. Chem.-Int. Edit., 45(5), 813 (2006)
Mei Y, Lu Y, Polzer F, Ballauff M, Drechsler M, Chem. Mater., 19(5), 1062 (2007)
Naseem K, Rehman MAU, Huma R, Int. J. Polym. Mater., 67(5), 322 (2018)
Palioura D, Armes SP, Anastasiadis SH, Vamvakaki M, Langmuir, 23(10), 5761 (2007)
Begum R, Farooqi ZH, Ahmed E, Naseem K, Ashraf S, Sharif A, Rehan R, Appl. Organomet. Chem., 31(2), 3563 (2017)
Khalid A, Arshad M, Crowley DE, Water Res., 43, 1110 (2009)
Pradhan N, Pal A, Pal T, Colloids Surf. A: Physicochem. Eng. Asp., 196(2), 247 (2002)
Abbas M, Torati SR, Kim C, Nanoscale, 7(28), 12192 (2015)
Chiu CY, Chung PJ, Lao KU, Liao CW, Huang MH, J. Phys. Chem. C, 116(44), 23757 (2012)
Reddy V, Torati RS, Oh S, Kim C, Ind. Eng. Chem. Res., 52(2), 556 (2012)
Farooqi ZH, Naseem K, Begum R, Ijaz A, Inorg. Organomet. Polym. Mater., 25(6), 1554 (2015)
Dong Y, Ma Y, Zhai TY, Shen FG, Zeng Y, Fu HB, Yao JN, Macromol. Rapid Commun., 28(24), 2339 (2007)
Amosa MK, Jami MS, Maan F, Waste Biomass Valorization, 71(1), 109 (2016)
Khan SR, Farooqi ZH, Ajmal M, Siddiq M, Khan A, J. Disper. Sci. Technol, 4(10), 1324 (2013)
Follens L, Aerts A, Haouas M, Caremans T, Loppinet B, Goderis B, Vermant J, Taulelle F, Martens J, Kirschhock CE, Phys. Chem. Chem. Phys., 10(36), 5574 (2008)
Vincent T, Peirano F, Guibal E, Appl. Polym. Sci., 94(4), 1634 (2004)
Ajmal M, Farooqi ZH, Siddiq M, Korean J. Chem. Eng., 30(11), 2030 (2013)
Lu Y, Mei Y, Ballauff M, Drechsler M, J. Phys. Chem. B, 110(9), 3930 (2006)
Carregal-Romero S, Buurma NJ, Perez-Juste J, Liz-Marzan LM, Herves P, Chem. Mater., 22(10), 3051 (2010)
Karg M, Pastoriza-Santos I, Rodriguez-Gonzalez B, von Klitzing R, Wellert S, Hellweg T, Langmuir, 24(12), 6300 (2008)
Begum R, Naseem K, Ahmed E, Sharif A, Farooqi ZH, Colloids Surf. A: Physicochem. Eng. Asp., 511(1), 17 (2016)
Farooqi ZH, Ijaz A, Begum R, Naseem K, Usman M, Ajmal M, Saeed U, Polym. Compos., 39(3), 645 (2016)
Karg M, Lu Y, Carbo-Argibay E, Pastoriza-Santos I, Perez-Juste J, Liz-Marzan LM, Hellweg T, Langmuir, 25(5), 3163 (2009)
Sivakumaran D, Maitland D, Hoare T, Biomacromolecules, 12(11), 4112 (2011)
Bromberg L, Temchenko M, Hatton TA, Langmuir, 18(12), 4944 (2002)
Lopez VC, Hadgraft J, Snowden M, Int. J. Pharm., 292(1), 137 (2005)
Hoare T, Pelton R, Macromolecules, 40(3), 670 (2007)
Xu SQ, Zhang JG, Paquet C, Lin YK, Kumacheva E, Adv. Funct. Mater., 13(6), 468 (2003)
Zhang JG, Xu SQ, Kumacheva E, J. Am. Chem. Soc., 126(25), 7908 (2004)
Dai G, Quan C, Zhang X, Liu J, Song L, Gan N, Water. Res., 46(5), 1482 (2012)
Nilsson P, Hansson P, J. Phys. Chem. B, 109(50), 23843 (2005)
Bromberg L, Temchenko M, Hatton TA, Langmuir, 19(21), 8675 (2003)
Li P, SenGupta AK, React. Funct. Polym., 44(3), 273 (2000)
Farooqi ZH, Naseem K, Ijaz A, Begum R, J. Polym. Eng., 36(1), 87 (2016)
Farooqi ZH, Khan SR, Begum R, Kanwal F, Sharif A, Ahmed E, Majeed S, Ijaz K, Ijaz A, Turk. J. Chem., 39(1), 96 (2015)
Zhang JT, Wei G, Keller TF, Gallagher H, Stotzel C, Muller FA, Gottschaldt M, Schubert US, Jandt KD, Macromol. Mater. Eng., 295(11), 1049 (2010)
Lai JJ, Hoffman JM, Ebara M, Hoffman AS, Estournes C, Wattiaux A, Stayton PS, Langmuir, 23(13), 7385 (2007)
Zhang Y, Liu H, Fang Y, Chin. J. Chem. Eng., 29(1), 33 (2011)
Naseem K, Begum R, Farooqi ZH, Environ. Sci. Pollut. Res., 24(7), 6446 (2017)
Vimala K, Sivudu KS, Mohan YM, Sreedhar B, Raju KM, Carbohydr. Polym., 75(3), 463 (2009)
Begum R, Naseem K, Farooqi ZH, J. Sol-Gel Sci. Technol., 77, 497 (2016)
Pich A, Karak A, Lu Y, Ghosh AK, Adler HJP, Nanosci. Nanotechnol., 6(12), 3763 (2006)
Pich A, Karak A, Lu Y, Ghosh AK, Adler HJP, Macromol. Rapid Commun., 27(5), 344 (2006)
Liu YY, Liu XY, Yang JM, Lin DL, Chen X, Zha LS, Colloids Surf. A: Physicochem. Eng. Asp., 393(1), 105 (2012)
Wu S, Dzubiella J, Kaiser J, Drechsler M, Guo X, Ballauff M, Lu Y, Agew. Chem. Int. Ed., 51(9), 2229 (2012)
Naseem K, Begum R, Farooqi ZH, Polym. Compos. (2016), DOI:10.1002/pc.24212.
Lu Y, Mei Y, Drechsler M, Ballauff M, Angew. Chem.-Int. Edit., 45(5), 813 (2006)
Mei Y, Lu Y, Polzer F, Ballauff M, Drechsler M, Chem. Mater., 19(5), 1062 (2007)
Naseem K, Rehman MAU, Huma R, Int. J. Polym. Mater., 67(5), 322 (2018)
Palioura D, Armes SP, Anastasiadis SH, Vamvakaki M, Langmuir, 23(10), 5761 (2007)
Begum R, Farooqi ZH, Ahmed E, Naseem K, Ashraf S, Sharif A, Rehan R, Appl. Organomet. Chem., 31(2), 3563 (2017)
Khalid A, Arshad M, Crowley DE, Water Res., 43, 1110 (2009)
Pradhan N, Pal A, Pal T, Colloids Surf. A: Physicochem. Eng. Asp., 196(2), 247 (2002)
Abbas M, Torati SR, Kim C, Nanoscale, 7(28), 12192 (2015)
Chiu CY, Chung PJ, Lao KU, Liao CW, Huang MH, J. Phys. Chem. C, 116(44), 23757 (2012)
Reddy V, Torati RS, Oh S, Kim C, Ind. Eng. Chem. Res., 52(2), 556 (2012)
Farooqi ZH, Naseem K, Begum R, Ijaz A, Inorg. Organomet. Polym. Mater., 25(6), 1554 (2015)
Dong Y, Ma Y, Zhai TY, Shen FG, Zeng Y, Fu HB, Yao JN, Macromol. Rapid Commun., 28(24), 2339 (2007)
Amosa MK, Jami MS, Maan F, Waste Biomass Valorization, 71(1), 109 (2016)
Khan SR, Farooqi ZH, Ajmal M, Siddiq M, Khan A, J. Disper. Sci. Technol, 4(10), 1324 (2013)
Follens L, Aerts A, Haouas M, Caremans T, Loppinet B, Goderis B, Vermant J, Taulelle F, Martens J, Kirschhock CE, Phys. Chem. Chem. Phys., 10(36), 5574 (2008)
Vincent T, Peirano F, Guibal E, Appl. Polym. Sci., 94(4), 1634 (2004)
Ajmal M, Farooqi ZH, Siddiq M, Korean J. Chem. Eng., 30(11), 2030 (2013)
Lu Y, Mei Y, Ballauff M, Drechsler M, J. Phys. Chem. B, 110(9), 3930 (2006)
Carregal-Romero S, Buurma NJ, Perez-Juste J, Liz-Marzan LM, Herves P, Chem. Mater., 22(10), 3051 (2010)
