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Received November 2, 2017
Accepted February 2, 2018
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Effect of dissolved oxygen/nZVI/persulfate process on the elimination of 4-chlorophenol from aqueous solution: Modeling and optimization study
Mansour Baziar1
Ramin Nabizadeh1 2†
Amir Hossein Mahvi1
Mahmood Alimohammadi1
Kazem Naddafi1
Alireza Mesdaghinia1
Hassan Aslani3
1Department of Environmental Health Engineering, School of Public Health,, Tehran University of Medical Sciences, Tehran, Iran 2Center for Air Pollution Research, Institute for Environmental Research, Tehran University of Medical Sciences, Tehran, Iran 3Department of Environmental Health Engineering, School of Public Health, Tabriz University of Medical Sciences, Tabriz, Iran
rnabizadeh@tums.ac.ir
Korean Journal of Chemical Engineering, May 2018, 35(5), 1128-1136(9), 10.1007/s11814-018-0017-9
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Abstract
4-Chlorophenol (4-CP) is a hazardous and toxic chemical that enters into water bodies mainly through industrial effluents. The present study investigated the effect of under pressure dissolved oxygen on 4-CP degradation in the presence of nanoscale zero-valent iron (nZVI) and sodium persulfate. The impact of oxygen pressure, as a qualitative variable at three levels (1, 1.5 and 2 atm), along with five quantitative variables, including persulfate concentration (0-2mM), nZVI dosage (0-1 g/L), pH (3-11), reaction time (5-90min) and 4-CP concentration (50-500mg/L) on the 4-CP elimination from aqueous solutions, was examined using response surface methodology. There was a direct relationship between the dissolved oxygen under pressure and the 4-CP removal efficiency. Also, the gained R2 and adjusted R2 for three developed models of 1, 1.5 and 2 atm oxygen pressure were 0.971 and 0.9569, 0.9689 and 0.9538, and 0.9642 and 0.9468, respectively. The best removal process conditions for pH 4.2, 1.6mM persulfate, 64.79 min reaction time, 97.89mg/L initial 4-CP and 1 g/L nZVI dosage. The results indicated that dissolved oxygen under pressure-nZVI-persulfate could be considered a promising process for elimination of organic compounds from aqueous solutions.
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References
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Karthikeyan S, Boopathy R, Gupta VK, Sekaran G, J. Mol. Liq., 177, 402 (2013)
Sze MFF, McKay G, Water Res., 46(3), 700 (2012)
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Shinde SS, Bhosale CH, Rajpure KY, J. Mol. Catal. A-Chem., 347(1-2), 65 (2011)
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Karimaei M, Sharafi K, Moradi M, Ghaffari HR, Biglari H, Arfaeinia H, Fattahi N, Anal. Methods, 9(19), 2865 (2017)
Mittal A, Mittal J, Malviya A, Kaur D, Gupta VK, J. Colloid Interface Sci., 343(2), 463 (2010)
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Gupta VK, Jain R, Nayak A, Agarwal S, Shrivastava M, Mater. Sci. Eng. C-Biomimetic Supramol. Syst., 31(5), 1062 (2011)
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Matzek LW, Carter KE, Chemosphere, 151, 178 (2016)
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Zhao J, Zhang Y, Quan X, Chen S, Sep. Purif. Technol., 71(3), 3020 (2010)
Giri S, Bhaumik M, Das R, Gupta VK, Maity A, Appl. Catal. B: Environ., 202, 207 (2017)
Al-Shamsi MA, Thomson NR, Ind. Eng. Chem. Res., 52(38), 13564 (2013)
Mittal A, Ahmad R, Hasan I, Desalination Water Treatment, 57(32), 15133 (2016)
Lin YT, Liang CJ, Yu CW, Ind. Eng. Chem. Res., 55(8), 2302 (2016)
Li X, Zhou MH, Pan YW, Xu LT, Chem. Eng. J., 307, 1092 (2017)
Temiz K, Olmez-Hanci T, Arslan-Alaton I, Environ. Technol., 37(14), 1757 (2016)
Keenan CR, Sedlak DL, Environ. Sci. Technol., 42(4), 1262 (2008)
Noradoun CE, Cheng IF, Environ. Sci. Technol., 39(18), 7158 (2005)
Ghaedi AM, Ghaedi M, Vafaei A, Iravani N, Keshavarz M, Rad M, Tyagi I, Agarwal S, Gupta VK, J. Mol. Liq., 206, 195 (2015)
Fakhri A, Rashidi S, Tyagi I, Agarwal S, Gupta VK, J. Mol. Liq., 214, 378 (2016)
Asfaram A, Ghaedi M, Ghezelbash GR, Dil EA, Tyagi I, Agarwal S, Gupta VK, J. Mol. Liq., 214, 249 (2016)
Maran JP, Priya B, Ultrason. Sonochem., 23, 192 (2015)
Shams M, Dehghani MH, Nabizadeh R, Mesdaghinia A, Alimohammadi M, Najafpoor AA, J. Mol. Liq., 224, 151 (2016)
Englehardt JD, Meeroff DE, Echegoyen L, Deng Y, Raymo FM, Shibata T, Environ. Sci. Technol., 41(1), 270 (2007)
Leupin OX, Hug SJ, Water Res., 39(9), 1729 (2005)
Hussain I, Zhang Y, Huang S, RSC Adv., 4(7), 3502 (2014)
Xu XR, Li XZ, Sep. Purif. Technol., 72(1), 105 (2010)
Hussain I, Zhang YQ, Huang SB, Du XZ, Chem. Eng. J., 203, 269 (2012)
