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Received July 24, 2017
Accepted February 5, 2018
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Viscometric and FTIR studies of molecular interactions in 2-propanol+hydrocarbons mixtures at 298.15 and 308.15 K
Department of Chemistry, Deenbandhu Chhotu Ram University of Science and Technology, Murthal-131 039, India 1Department of Chemical Engineering, Deenbandhu Chhotu Ram University of Science and Technology, Murthal-131 039, India
sanjeevmakin@gmail.com
Korean Journal of Chemical Engineering, May 2018, 35(5), 1167-1173(7), 10.1007/s11814-018-0020-1
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Abstract
The deviation in viscosity was coupled with respective excess molar volume data to study the molecular interaction in binary mixtures with one associated component. This approach was applied to the experimentally measured viscosity and excess molar volume data of the 2-propanol+hydrocarbons at 298.15 K and 308.15 K. It was suggested that depolymerization power of aromatic hydrocarbon toward 2-propanol as well as strength of intermolecular interactions (electron-donor-acceptor type) between monomer of 2-propanol and aromatics depend on π-electron density of the aromatic hydrocarbon. These interactions were further confirmed by FTIR spectroscopy. The viscosity of these binary mixtures was best predicted by Gruenberg-Nissan correlation among the four correlations applied.
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Katti PK, Chaudhri MM, J. Chem. Eng. Data, 9, 442 (1964)
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Gahlyan S, Verma S, Ranin M, Maken S, J. Mol. Liq. (2017), DOI:10.1016/j.molliq.2018.03.003.
