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Received November 17, 2017
Accepted February 2, 2018
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Separation of heavy metal and protein from wastewater by sulfonated polyphenylsulfone ultrafiltration membrane process prepared by glycine betaine enriched coagulation bath
Irfana Moideen Kolangare
Arun Mohan Isloor†
Asif Ali Qaiser1
Ahmed Fauzi Ismail2
Mohd Sohaimi Abdullah2
Membrane Technology Laboratory, Department of Chemistry, National Institute of Technology Karnataka, Surathkal, Mangalore-575 025, India 1Department of Polymer and Process Engineering, University of Engineering and Technology Lahore, 54890, Lahore, Pakistan 2Advanced Membrane Technology Research Center (AMTEC), Universiti Teknologi Malaysia, 81310 Skudai, Johor Bahru, Malaysia
Korean Journal of Chemical Engineering, June 2018, 35(6), 1281-1289(9),
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Abstract
This work deals with a simple and eco-friendly approach for the development of ultrafiltration membranes for the separation of environmentally hazardous substances from the water source. Polysulfone and sulfonated polyphenylsulfone blend ultrafiltration membranes were fabricated by the non-solvent induced phase inversion technique. Prepared membranes were characterized for their morphology, hydrophilicity, porosity, filtration and antifouling properties. The blend membranes with 15 wt% of sPPSU demonstrated the best performance with water flux of 190.33 Lm-2h-1 and flux recovery ratio of 86.56%. The effect of aq. glycine betaine (GB) coagulation bath on the membrane property and performance was studied and compared with commonly used additives such as NaCl and NMP. The GB in coagulation bath exhibited better flux and performance with protein rejection of 66.3%, 74.0% and 91.2% for trypsin, pepsin, and bovine serum albumin, respectively, and heavy metal rejection of 75.2% and 87.6% for polymer enhanced ultrafiltration of Cd2+ and Pb2+ ions, respectively.
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References
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Anbalagan S, Ponnusamy SK, Selvam SRP, Sankaranarayan A, Dutta A, Korean J. Chem. Eng., 33(9), 2716 (2016)
Kanagaraj P, Neelakandan S, Nagendran A, Korean J. Chem. Eng., 31(6), 1057 (2014)
Ghosh R, Silva SS, Cui Z, Biochem. Eng. J., 6, 19 (2000)
Ingole PG, Ingole NP, Korean J. Chem. Eng., 31(12), 2109 (2014)
Mbareck C, Nguyen QT, Alaoui OT, Barillier D, J. Hazard. Mater., 171(1-3), 93 (2009)
Kumar M, Lawler J, Sep. Purif. Technol., 130, 112 (2014)
Shukla AK, Alam J, Alhoshan M, Dass LA, Muthumareeswaran M, Scientific Reports, 7, 41976 (2017)
Rahimpour A, Madaeni SS, J. Membr. Sci., 305(1-2), 299 (2007)
Nakao S, Osada H, Kurata H, Tsuru T, Kimura S, Desalination, 70, 191 (1988)
Shen LQ, Xu ZK, Liu ZM, Xu YY, J. Membr. Sci., 128, 279 (2003)
Liu Y, Yue XG, Zhang SL, Ren JN, Yang LL, Wang QH, Wang GB, Sep. Purif. Technol., 98, 298 (2012)
Thurmer MB, Poletto p, Marcolin M, Duarte J, Zeni M, Mater. Res., 15, 884 (2012)
Zhao S, Wang Z, Wang JX, Wang SC, J. Membr. Sci., 469, 316 (2014)
Shang MX, Matsuyama H, Teramoto M, Lloyd DR, Kubota N, Sep. Purif. Technol., 45(3), 208 (2005)
Saljoughi E, Amirilargani M, Mohammadi T, J. Appl. Polym. Sci., 111(5), 2537 (2009)
Chun KY, Jang SH, Kim HS, Kim YW, Han HS, Joe YI, J. Membr. Sci., 169(2), 197 (2000)
Yang S, Liu ZZ, J. Membr. Sci., 222(1-2), 87 (2003)
Yam-Cervantes M, Santiago-Garcia J, Loria-Bastarrachea M, Duarte-Aranda S, Ruiz-Trevino FA, Aguilar-Vega M, J. Appl. Polym. Sci., 134, 4450 (2017)
Madaeni S, Rahimpour A, Polym. Adv. Technol., 16, 717 (2005)
Xu J, Tang YY, Wang YH, Shan BT, Yu LM, Gao CJ, J. Membr. Sci., 455, 121 (2014)
Yao C, Burford R, Fane A, Fell C, J. Membr. Sci., 38, 113 (1988)
White A, Jiang S, J. Phys. Chem. B, 115, 660 (2010)
Di Vona ML, Sgreccia E, Tamilvanan M, Khadhraoui M, Chassigneux C, Knauth P, J. Membr. Sci., 354(1-2), 134 (2010)
Gil M, Ji XL, Li XF, Na H, Hampsey JE, Lu YF, J. Membr. Sci., 234(1-2), 75 (2004)
Shenvi S, Ismail AF, Isloor AM, Ind. Eng. Chem. Res., 53(35), 13820 (2014)
Hebbar RS, Isloor AM, Ananda K, Ismail A, J. Mater. Chem. A, 4, 764 (2016)
Moideen IK, Isloor AM, Ismail A, Obaid A, Fun HK, Desalin. Water Treat., 57, 19810 (2015)
Pereira VR, Isloor AM, Al Ahmed A, Ismail A, New J. Chem., 39, 703 (2015)
Hebbar RS, Isloor AM, Ismail A, Shilton SJ, Obaid A, Fun HK, New J. Chem., 39, 6141 (2015)
Kumar R, Isloor AM, Ismail A, Rashid SA, Matsuura T, RSC Adv., 3, 7855 (2013)
Yunos MZ, Harun Z, Basri H, Ismail AF, Desalination, 333(1), 36 (2014)
Lai GS, Yusob MHM, Lau WJ, Gohari RJ, Emadzadeh D, Ismail AF, Goh PS, Isloor AM, Arzhandi MRD, Sep. Purif. Technol., 178, 113 (2017)
Moideen IK, Isloor AM, Garudachari B, Ismail A, Desalin. Water Treat., 57, 24788 (2016)
Kim JD, Donnadio A, Jun MS, Di Vona ML, Int. J. Hydrog. Energy, 38(3), 1517 (2013)
Strathmann H, Kock K, Desalination, 21, 241 (1977)
Lutchmiah K, Lauber L, Roest K, Harmsen DJH, Post JW, Rietveld LC, van Lier JB, Cornelissen ER, J. Membr. Sci., 460, 82 (2014)
Buonomenna M, Macchi P, Davoli M, Drioli E, Eur. Polym. J., 43, 1557 (2007)
Cao XC, Ma J, Shi XH, Ren ZJ, Appl. Surf. Sci., 253(4), 2003 (2006)
Daraei P, Madaeni SS, Ghaemi N, Salehi E, Khadivi MA, Moradian R, Astinchap B, J. Membr. Sci., 415-416, 250 (2012)
Razmjou A, Mansouri J, Chen V, J. Membr. Sci., 378(1-2), 73 (2011)
Takagishi T, Okuda S, Kuroki N, Kozuka H, J. Polym. Sci. A: Polym. Chem., 23, 2109 (1985)
Kochkodan OD, Kochkodan VM, Sharma VK, J. Environ. Sci. Health Part A-Toxic/Hazard. Subst. Environ. Eng., 53, 33 (2017)
Liu G, Zhang L, Mao S, Rohani S, Ching C, Lu J, Sep. Purif. Technol., 15, 55 (2015)
Zhu LP, Xu L, Zhu BK, Feng YX, Xu YY, J. Membr. Sci., 294(1-2), 196 (2007)
Razmjou A, Mansouri J, Chen V, J. Membr. Sci., 378(1-2), 73 (2011)
