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Received November 10, 2017
Accepted February 6, 2018
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Efficient conversion of fructose to 5-[(formyloxy)methyl]furfural by reactive extraction and in-situ esterification
Xiamen Key Laboratory of High-valued Conversion Technology of Agricultural Biomass, College of Energy, Xiamen University, Xiamen 361102, China
Korean Journal of Chemical Engineering, June 2018, 35(6), 1312-1318(7), 10.1007/s11814-018-0025-9
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Abstract
5-[(Formyloxy)methyl]furfural (FMF), an analogue of 5-(hydroxymethyl)furfural (HMF) is becoming more attractive due to its superior stability and hydrophobicity, which make it easier to refineand store. In the present study, FMF was produced from fructose by one-pot approach in pure formic acid media or by a two-step approach via HMF in choline chloride (ChCl)/fructose deep eutectic solvents (DES) system. A favorable FMF yield of 63.22% was reached by two-step approach. In addition, the effects of reaction parameters, such as temperature and acidity, on preparation of FMF from fructose were systematically investigated. The dehydration of fructose into HMF was confirmed as the rate-controlling step in the consecutive reaction. Ultimately, the separation and purification procedures of FMF were put forward. The FMF with a purity of 98.8% was obtained finally. Meanwhile, the FMF purified by saturated sodium bicarbonate solution showed an excelled storage stability.
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References
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Sun Y, Lin L, J. Agric. Food Chem., 58, 2253 (2010)
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Girisuta B, Janssen L, Heeres HJ, Green Chem., 8, 701 (2006)
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Asghari FS, Yoshida H, Ind. Eng. Chem. Res., 46(23), 7703 (2007)
Zuo M, Le K, Li Z, Jiang Y, Zeng X, Tang X, Sun Y, Lin L, Ind. Crop. Prod., 99, 1 (2017)
