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Received November 20, 2017
Accepted February 23, 2018
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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A Hydrogel-coated membrane for highly efficient separation of microalgal bio-lipid
Jihye Shin1
Hogi Kim1
Heeyeon Moon1
Moo Jin Kwak1
Seula Oh1
Youngmin Yoo1
Eunjung Lee1
Yong Keun Chang1 2†
Sung Gap Im1†
1Department of Chemical and Biomolecular Engineering, KAIST, Daejeon 34141, Korea 2Advanced Biomass R&D Center, Daejeon 34141, Korea
Korean Journal of Chemical Engineering, June 2018, 35(6), 1319-1327(9),
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Abstract
A cross-linked hydrogel-coated membrane was fabricated to achieve simple but highly efficient separation of bio-lipids directly from an aqueous microalgal culture medium. The membrane is composed of a stainless steel membrane coated conformally with a cross-linked hydrogel, poly(2-hydroxyethyl methacrylate) (pHEMA), synthesized by a photo-initiated chemical vapor deposition (piCVD) process. The pHEMA-coated membrane has hydrophilicity and underwater-oleophobicity for efficient separation of a bio-lipid-in-hexane/water mixture by gravity. The conformal pHEMA film-coated membrane enables extremely high oil rejection performance with intrusion pressure of 6.1 kPa and water permeation flux of 6.5 x103 L m-2 h-1, with excellent separation efficiency greater than 98.0%.
Keywords
References
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Lin L, Zhou CS, Vittayapadung S, Shen XQ, Dong MD, Appl. Energy, 88(4), 1020 (2011)
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Chisti Y, Biotechnol. Adv., 25, 294 (2007)
Wu S, Song LR, Sommerfeld M, Hu Q, Chen W, Fuel, 197, 467 (2017)
Lardon L, Helias A, Sialve B, Steyer JP, Bernard O, Environ. Sci. Technol., 43, 6475 (2009)
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Choy SY, Algal Res. (2017), DOI:10.1016/j.algal.2017.1011.1012.
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Yoo G, Park WK, Kim CW, Choi YE, Yang JW, Bioresour. Technol., 123, 717 (2012)
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Xue ZX, Wang ST, Lin L, Chen L, Liu MJ, Feng L, Jiang L, Adv. Mater., 23(37), 4270 (2011)
Rohrbach K, Li Y, Zhu H, Liu Z, Dai J, Andreasen J, Hu L, Chem. Commun., 50, 13296 (2014)
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Li J, Yang L, Li H, Li J, Zha F, Lei Z, RSC Adv., 5, 53802 (2015)
Kwak MJ, Yoo Y, Lee HS, Kim J, Yang JW, Hang JI, Im SG, Kwon JH, ACS Appl. Mater. Inter., 8, 600 (2016)
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Zhang W, Cao Y, Liu N, Chen Y, Feng L, RSC Adv., 4, 51404 (2014)
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Baxamusa SH, Montero L, Dubach JM, Clark HA, Borros S, Gleason KK, Biomacromolecules, 9(10), 2857 (2008)
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Kwak MJ, Oh MS, Yoo Y, You JB, Kim J, Yu SJ, Im SG, Chem. Mater., 27, 3441 (2015)
Kim BJ, Han D, Yoo S, Im SG, Korean J. Chem. Eng., 34(3), 892 (2017)
Zhang F, Zhang WB, Shi Z, Wang D, Jin J, Jiang L, Adv. Mater., 25(30), 4192 (2013)
Zhao X, Su Y, Liu Y, Li Y, Jiang Z, ACS Appl. Mater. Inter., 8, 8247 (2016)
Liu L, Chen C, Yang S, Xie H, Gong M, Xu X, Phys. Chem. Chem. Phys., 18, 1317 (2016)
Gallina A, Stocco N, Mutinelli F, Food Control, 21, 942 (2010)
Abrahamson E, Littler J, Vo KP, J. Chem. Phys., 44, 4082 (1966)
Chan K, Gleason KK, Langmuir, 21(19), 8930 (2005)
Jeong GM Seong H, Kim YS, Im SG, Jeong KJ, Polym. Chem., 5, 4459 (2014)
Zheng X, Guo Z, Tian D, Zhang X, Li W, Jiang L, ACS Appl. Mater. Inter., 7, 4336 (2015)
Chen PC, Xu ZK, Sci. Rep., 3, 2776 (2013)
Lee J, Aoai T, Kondo S, Miyagawa N, Takahara S, Yamaoka T, J. Polym. Sci. A: Polym. Chem., 40(11), 1858 (2002)
Vasilopoulou M, Boyatzis S, Raptis I, Dimotikalli D, Argitis P, J. Mater. Chem., 14, 3312 (2004)
Lau KKS, Gleason KK, Macromolecules, 39(10), 3688 (2006)
Lee S, Seong H, Im SG, Moon H, Yoo S, Nat. Commun., 8, 725 (2017)
Lee YI, Jeon NJ, Kim BJ, Shim H, Yang TY, SeoK SI, Seo J, Im SG, Adv. Energy Mater., 1701928 (Online Version) (2017).
Bakker R, Verlaan V, Van der Werf C, Rath J, Gleason K, Schropp R, Surf. Coat. Technol., 201, 9422 (2007)
Corkhill PH, Jolly AM, Ng CO, Tighe BJ, Polymer, 28, 1758 (1987)
Tao MM, Xue LX, Liu F, Jiang L, Adv. Mater., 26(18), 2943 (2014)
Gao SJ, Shi Z, Zhang WB, Zhang F, Lin J, ACS Nano, 8, 6344 (2014)
