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Received October 23, 2017
Accepted February 9, 2018
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Organosilicon resin-based carbon/ceramic polygranular composites with improved oxidation resistance
Department of Biomaterials and Composites, Faculty of Materials Science and Ceramics, AGH, University of Science and Technology, Al. Mickiewicza 30, 30-059 Cracow, Poland 1SGL Carbon Polska S.A., ul. Piastowska 29 47-400 Raciborz, Poland
blazew@agh.edu.pl
Korean Journal of Chemical Engineering, June 2018, 35(6), 1354-1364(11), 10.1007/s11814-018-0029-5
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Abstract
We examined the thermo-mechanical properties of carbon materials modified with silicon oxycarbide (Si- O-C) and silicon carbide (Si-C). These compounds were obtained by the impregnation of carbon components with a silicon-containing polymer resin. Graphite and anthracite powders were used as carbon components, and poly[methyl(phenyl) siloxane] resin (P) was used as the ceramic precursor. Carbon/polymer compositions (C/P) were subjected to twostage annealing, first to 1,000 °C and next to 2,000 °C in an inert atmosphere, leading to the formation of C/Si-O-C and C/Si-C composite samples, respectively. The materials were then examined under conditions of isothermal oxidation to determine their oxidation resistance and the mechanical properties before and after oxidation tests. The structure of the samples before and after oxidation was studied. C/Si-C composites, despite their high porosity, proved to have enhanced resistance to oxidation at 600 °C, although they had lower mechanical properties in comparison to C/Si-O-C samples.
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Schiavon MA, Radovanovic E, Yoshida IVP, Powder Technol., 123(2-3), 232 (2002)
Kolar F, Machovic V, Svitilova J, Borecka L, Mater. Chem. Phys., 86(1), 88 (2004)
Kwon OS, Hong SH, Kim H, J. European Ceram. Soc., 23, 3119 (2003)
Schiavon MA, Redondo SUA, Pina SRO, Yoshida IVP, J. Non-Cryst. Solids, 304, 92 (2002)
Duan L, Ma Q, Chen Z, J. European Ceram. Soc., 33, 841 (2013)
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Wu Q, Zhang Q, Zhao L, Li SN, Wu LB, Jiang JX, Tang LC, J. Hazard. Mater., 336, 222 (2017)
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