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Received January 10, 2018
Accepted March 15, 2018
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Comparative study of CHA- and AEI-type zeolytic catalysts for the conversion of chloromethane into light olefins
CO2 Energy Vector Research Group, Carbon Resources Institute, Korea Research Institute of Chemical Technology, Daejeon 34114, Korea 1Innovation Center for Chemical Engineering, Department of Energy and Chemical Engineering, Incheon National University, Incheon 22012, Korea
mbpark@inu.ac.kr
Korean Journal of Chemical Engineering, July 2018, 35(7), 1433-1440(8), 10.1007/s11814-018-0050-8
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Abstract
Three pairs of CHA- and AEI-type zeolytic materials with similar crystallite size but with different framework atoms, i.e., silicoaluminophosphate SAPO-34 and SAPO-18, aluminosilicate SSZ-13 and SSZ-39, and titaniumincorporated TiAPSO-34 and TiAPO-18, were prepared and their catalytic activities of chloromethane into light olefins were compared according to the structure types, as well as acidic properties. The AEI-type catalysts were found to have lower ethene/propene ratios, indicating relatively higher propene selectivity, because their aei-cage was larger compared to the cha-cage. However, all the CHA-type catalysts exhibited better activity and higher selectivity to light olefins. Both H-SAPO-34 and H-TiAPSO-34 showed good catalytic stability over all the reaction times studied here. When compared to H-SAPO-34, however, H-TiAPSO-34 exhibited ca. 20mol% higher selectivity to ethene and propene, despite a similar total density of acid site. This performance may be due to the higher strength of medium acid sites.
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References
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Man PP, Briend M, Peltre MJ, Lamy A, Beaunier P, Barthomeuf D, ZKG Int., 11, 563 (1991)
