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Received December 10, 2017
Accepted March 27, 2018
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Ultrasonic study on binary liquid mixtures of propiophenone with anilines and alkyl substituted anilines at T=303.15 to 318.15 K
Nanduri Gayatri Devi
Nanduri Veera Naga Bala Srinivasa Rao1
Maganti Radha Sirija
Dittakavi Ramachandran†
Acharya Nagarjuna University, Guntur, India 1D. R. Goenka Govt. Degree College, Tadepalligudem, India
dittakavirc17@gmail.com
Korean Journal of Chemical Engineering, July 2018, 35(7), 1488-1499(12), 10.1007/s11814-018-0053-5
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Abstract
Densities 'ρ', ultrasonic speeds of sound 'u' of binary mixtures of propiophenone (PPH) with aniline, NMethylaniline, N,N-dimethylaniline and N,N-diethylaniline were measured over the entire composition range from 303.15 K to 318.15 K and at atmospheric pressure 0.1MPa. Experimental data of ultrasonic sound were compared and discussed with the computed values of 'u' from various velocity theories like Nomoto's relation (UNOM), impedance relation (UIMP), Van Dael and Vangeel's ideal mix relation (UVDV), Rao's specific velocity relation (URAO), Junjie's theory (UJUN) and Jouyban-Acree's (UJOE) relation for the above binary mixtures over the entire mole fraction range at the studied temperatures. The results are satisfactory and are in agreement between the theoretical and the experimental values. Further, the molecular interaction parameter (α), average percentage error and Chi-square test values were computed by using the values of experimental and theoretical ultrasonic velocities. The Δu values were correlated with Redlich-Kister polynomial equation to compute the coefficients and the standard deviations of the binary mixtures. The results were analyzed in terms of intermolecular interactions.
Keywords
References
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Sharma VK, Solanki S, Bhagour S, Sharma D, J. Mol. Liq., 188, 258 (2013)
Vasundhara P, Rao CN, Venkatramana L, Sivakumar K, Venkateswarlu P, Gardas RL, J. Mol. Liq., 202, 158 (2015)
Sahin M, Ayranci E, J. Chem. Thermodyn., 177, 43 (2011)
Kannappan V, Xavier JRS, Shanthi RJ, Indian J. Pure. Appl. Phys., 41, 690 (2003)
Amalendu, Sureshkumar, J. Ind. Chem. Soc., 81, 101 (2004)
Chauhan MS, Kumar A, Chauhan S, Acoust. Lett., 21, 228 (1998)
Samatha K, Babu VVH, Sreeramamurthy J, Acustica, 84, 169 (1998)
Rita M, Meenakshi, J. Ind. Chem. Soc., 82, 791 (2005)
Oswal SL, et al., Thermochim. Acta, 507-508, 27 (2010)
Narendra K, Sudhamsa B, Srath BM, J. Chem. Sci., Res. J. Chem. Sci., 4(8), 42 (2014)
Investigation of steric effect in the formation of hydrogen-bonded complexes of isomeric chlorophenols with N,N-dimethylaniline; Muhamed RR, Rajesh R, Kannappan V, Arulappan S, Prabaharan A;https://doi.org/10.1016/j.molliq.2017.08.068.
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Gowrisankar M, Venkateswarlu P, Sivakumar K, Sivarambabu S, Arabian J. Chem., 10, S2625 (2015)
Gowrisankar M, Venkateswarlu, Sivakumar K, Sivarambabu S, J. Solution Chem., 42, 916 (2013)
Pandiyan V, Oswal SL, Vasantharani P, Thermochim. Acta, 518(1-2), 36 (2011)
Nomato O, J. Phys. Soc., Jan 13, 1528 (1958).
VanDeel and Vangeel E, Proceeding of first international conference on colorimetry thermodynamics, Warsaw (1969) 555.
VanDeel W, Experimental thermodynamics Vol-II Butterworths, London (1975) Chap XI.
Junjie Z, J. China Univ. Sci. Technol., 14, 298 (1984)
Schaaffs W, Z. phys 114, 110 (1939).
Schaaffs W, Molekularkustik, Springer, Verlag, Heidelberg (1963) chap XI and XII.
Jouyban A, Khoubnasabjafari M, Vaezgharamaleki Z, Fekari Z, Acree WE, Chem. Pharmaceutical Bulletin, 53, 519 (2005)
Bindhani SK, Roy GK, Mohanty YK, Kubendran TR, Russian J. Phys. Chem. A, 89, 1828 (2015)
Vasundhara P, Rao CN, Venkatramana L, Kumar KS, Venkateswarlu P, Gardas RL, J. Mol. Liq., 158, 202 (2015)
Begum Z, Sandhyasri PB, Rambabu C, ISRN Phys. Chem., Article ID 943429, 12 (2012).
Ramarao GV, Triveni M, Ramachandran D, Int. J. Eng. Res, 3 (2015)
Tiwari K, Patra C, Chakravortty V, Acoustics Lett., 19, 53 (1995)
Pal A, Kumar A, Indian J. Physics, 78(12), 1319 (2004)
Reddy Y, Naidu S, Prasad KR, Indian J. Pure Appl. Phys., 32, 958 (1994)
Balakrishnan S, Chem. Sci. Transactions, 4(1), 107 (2015)
Babavali SF, Shakira P, Srinivasu C, Narendra K, Karbala International J. Modern Sci., 1, 172 (2015)
Redlich O, Kister AT, J. Ind. Eng. Chem., 40, 345 (1948)
Alonso I, Alonso V, Mozo I, de la Fuente IG, Gonzalez JA, Cobos JC, J. Chem. Eng. Data, 55(7), 2505 (2010)
Su LY, Wang HJ, J. Chem. Thermodyn., 41(3), 315 (2009)
Nain AK, Fluid Phase Equilib., 259(2), 218 (2007)
Gowrisankar M,Venkateswarlu, Sivakumar K, Sivarambabu S, J. Solution Chem., 42, 916 (2013)
Palepu R, Diver J, Campell D, J. Chem. Eng. Data, 30, 355 (1985)
Oswal SL, Pandiyan V, Krishnakumar B, Vasantharani, Thermochim. Acta, 507, 27 (2010)
Gowrisankar M, Venkateswarlu P, Sivakumar K, Sivarambabu S, J. Mol. Liq., 173, 172 (2012)
Korosi G, Kovats ESZ, J. Chem. Eng. Data, 26, 323 (1981)
Bindhani SK, Roy GK, Mohanty YK, Kubendran TR, Russian J. Phys. Chem. A, 91, 1037 (2017)
Manukonda GS, Venkatalakshami, Rambabu K, Int. J. Phys. Res., 3(4), 5 (2013)
Rao VS, Krishna TV, Mohan TM, Rao PM, J. Chem. Thermodynam., 100, 165 (2016)
Aftabuzzaman M, Islam MM, Nasiruddin, Rima FR, Islam MN, Ali MA, J. Chem. Thermodynam., http://dx.doi.org/10.1016/j.jct.2015.12.030.
Alonso I, Mozo I, de la Fuente I, Gonzalez JA, Cobos JC, J. Chem. Eng. Data, 55(12), 5400 (2010)
Kumar S, Jeevanandham P, J. Mol. Liq., 174, 34 (2012)
Pandiyan V, Oswal SL, Vasantharani, Thermochim. Acta, 518, 36 (2011)
Sharma VK, Solanki S, Bhagour S, Sharma D, J. Mol. Liq., 188, 258 (2013)
Vasundhara P, Rao CN, Venkatramana L, Sivakumar K, Venkateswarlu P, Gardas RL, J. Mol. Liq., 202, 158 (2015)
