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Received January 29, 2018
Accepted March 27, 2018
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Flocculation of gelatinized starch: Flocculation performance and floc characterization
School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China 1College of Mechanical Engineering, Tianjin University of Science and Technology, Tianjin 300222, China
Korean Journal of Chemical Engineering, July 2018, 35(7), 1500-1508(9), 10.1007/s11814-018-0055-3
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Abstract
The removal of single macromolecules impurity is the basis study for the promotion of flocculation technology application in the Chinese herbal medicine solution purification. We applied the flocculation process to remove gelatinized starch in solution. Three types of cationic polyacrylamide (CPAM) with different charge density were used for flocculation of gelatinized starch solution. The flocculation performance was evaluated in terms of the amylose removal ratio (AMRR), the amylopectin removal ratio (APRR), total starch removal ratio (TSRR) and supernatant turbidity (ST). The flocs were characterized by sedimentation performance, Fourier transform infrared (FTIR), scanning electron microscope (SEM) and X-ray photoelectric spectroscopy (XPS) method. The experimental results show that the flocculant CN15 has the best performance for gelatinized starch flocculation among three flocculants. According to the characterization analysis, the flocs exhibited an obvious network structure, and it is concluded that hydrogen bonding between N-H in CPAM and C-O in the starch and bridging flocculation played the essential roles in flocculation of the gelatinized starch.
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Fu Z, Chen J, Luo SJ, Liu CM, Liu W, Starch-Starke, 67, 69 (2015)
Zakrajsek N, Fuente E, Blanco A, Golob J, Chem. Eng. Technol., 32(8), 1259 (2009)
Ma X, Bruckard WJ, Int. J. Miner. Process., 94(3-4), 111 (2010)
Abro MI, Pathan AG, Memon AR, Sirajuddin, Powder Technol., 25, 281 (2013)
Teh CY, Wu TY, Juan JC, Ecol. Eng., 71, 509 (2014)
Wang JP, Yuan SJ, Wang Y, Yu HQ, Water Res., 47, 2643 (2013)
Mishra S, Mukul A, Sen G, Jha U, Int. J. Biol. Macromol., 48, 106 (2011)
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Razali MAA, Ariffin A, Appl. Surf. Sci., 351, 89 (2015)
Wang JP, Yuan SJ, Wang Y, Yu HQ, Water Res., 47, 2643 (2013)
Jarvis CE, Walker JRL, J. Sci. Food Agric., 63, 53 (1993)
Mcgrance SJ, Cornell HJ, Rix CJ, Starch-Starke, 50, 158 (1998)
Hovenkamp-Hermelink JHM, Vries JND, Adamse P, Jacobsen E, Witholt B, Feenstra WJ, Potato Res., 31, 241 (1988)
Oosten BBJ, Starch-Starke, 42, 327 (1990)
Ma X, Colloids Surf. A: Physicochem. Eng. Asp., 320, 36 (2008)
Chen J, Jane J, Cereal Chem., 71, 623 (1994)
Bertuzzi MA, Armada M, Gottifredi JC, J. Food Eng., 82(1), 17 (2007)
Kizil R, Irudayaraj J, Seetharaman K, J. Agric. Food Chem., 50, 3912 (2002)
Huang BC, Jeng R, Sain M, Saville BA, Hubbes M, BioRes., 1, 693 (2006)
Liu Y, Lu X, Hu X, Shan Z, Zhu P, Carbohydr. Polym., 81, 911 (2010)
Wei B, Xu X, Jin Z, Tian Y, PLoS One, 9, e86024 (2014)
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