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Received January 21, 2018
Accepted April 30, 2018
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Anion-exchange-membrane-based electrochemical synthesis of ammonia as a carrier of hydrogen energy
Jong Hyun Park1 2
Hyung Chul Yoon1
Jong-Nam Kim1
Chan-Hee Jeong1
Eun-Young Jeong1
Dae Sik Yun1
Hana Yoon1
Sang Hyun Park1
Moon-Hee Han2†
Chung-Yul Yoo1†
1Korea Institute of Energy Research, 152 Gajeong-ro, Yuseong-gu, Daejeon 34129, Korea 2Graduate School of Energy Science and Technology, Chungnam National University, 99 Daehak-ro, Yuseong-gu, Daejeon 34134, Korea
mhhan@cnu.ac.kr
Korean Journal of Chemical Engineering, August 2018, 35(8), 1620-1625(6), 10.1007/s11814-018-0071-3
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Abstract
With a 17.6 wt% hydrogen content, ammonia is a non-carbon-emitting, easy to store and transport, carrier of hydrogen energy. In this study, an anion-exchange-membrane-based (AEM-based) electrochemical cell was used to electrochemically synthesize ammonia from water and nitrogen under ambient conditions. The electrochemical cell was fabricated by attaching Pt/C to both sides of the AEM, and ammonia was generated by supplying nitrogen gas to the cathodic chamber of the cell. AC impedance and current-voltage (I-V) properties were analyzed in relation to the externally applied voltage, and ammonia-formation rates and faradaic efficiencies were determined. The maximum ammonia-formation rate was 1.96X10 -11 molㆍs-1ㆍcm-2 at an applied voltage of 2V, with a faradaic efficiency of 0.18%.
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Giddey S, Badwal SPS, Kulkarni A, Int. J. Hydrog. Energy, 38(34), 14576 (2013)
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Skodra A, Stoukides M, Solid State Ion., 180(23-25), 1332 (2009)
Yoo CY, Park JH, Kim K, Han JI, Jeong EY, Jeong CH, Yoon HC, Kim JN, ACS Sustainable Chem. Eng., 5, 7972 (2017)
Jeoung H, Kim JN, Yoo CY, Joo JH, Yu JH, Song KC, Sharma M, Yoon HC, Korean Chem. Eng. Res., 52(1), 58 (2014)
Kim K, Yoo CY, Kim JN, Yoon HC, Han JI, Korean J. Chem. Eng., 33(6), 1777 (2016)
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Xu G, Liu R, Wang J, Sci. China Chem., 52, 1171 (2009)
Liu R, Chin. J. Chem., 28, 139 (2010)
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Lan R, Irvine JTS, Tao S, Sci. Rep., 3, 1145 (2013)
Lan R, Tao S, RSC Adv., 3, 18016 (2013)
Chen S, Perathoner S, Ampelli C, Mebrahtu C, Su D, Centi G, Angew. Chem.-Int. Edit., 56, 2699 (2017)
Chen S, Perathoner S, Ampelli C, Mebrahtu C, Su D, Centi G, ACS Sustainable Chem. Eng., 5, 7393 (2017)
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Suzuki S, Muroyama H, Matsui T, Eguchi K, J. Power Sources, 208, 257 (2012)
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Ivancic I, Water Res., 18, 1143 (1984)
Aminot A, Kirkwood DS, Kerouel R, Marine Chem., 56, 59 (1997)
Felix EP, Cardoso AA, Instrument. Sci. Technol., 31, 283 (2003)
Crosby NT, Analyst, 93, 406 (1968)
Afkhami A, Zarei AR, Talanta, 62, 559 (2004)
Yoo CY, Yun DS, Park SY, Park J, Joo JH, Park H, Kwak M, Yu JH, Electrocatal., 7, 280 (2016)
Dale NV, Mann MD, Salehfar H, Dhirde AM, Han T, J. Fuel Cell Sci. Technol., 7, 31010 (2010)
Kishira S, Qing G, Suzu S, Kikuchi R, Takagaki A, Oyama ST, Int. J. Hydrog. Energy, 42(43), 26843 (2017)
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Sclafani A, Augugliaro V, Schiavello M, J. Electrochem. Soc., 130, 734 (1983)
