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Received August 5, 2017
Accepted December 26, 2017
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Ultrasonic velocity measurements in isobutyric acid - water binary mixtures over the temperature range from 300.15 to 313.15 K
1Laboratoire de Physique des Liquides Critiques, Département de Physique, Faculté des Sciences de Bizerte, Zarzouna 7021 Bizerte, Université de Carthage, Tunisia 2Unité de Recherche de Physique des Liquides et d’Optique Non Linéaire, Département de Physique, Faculté des Sciences de Tunis, Campus Universitaire, El Manar 2092 Tunis, Université de Tunis El Manar, Tunisia
Adel.TToumi@fst.rnu.tn
Korean Journal of Chemical Engineering, August 2018, 35(8), 1687-1699(13), 10.1007/s11814-017-0352-2
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Abstract
We measured the ultrasonic velocity, U, density, ρ, and viscosity, η in Isobutyric acid - water binary liquid mixtures over the entire composition range at temperatures ranging from 300.15 to 313.15 K under atmospheric pressure. The experimental data values were analyzed to determine, various acoustical parameters: adiabatic compressibility, β, acoustic impedance, Z, free length, Lf, free volume, Vf, molar volume, Vm, relaxation time, τ, absorption coefficient, α/f2, internal pressure, π i, Gibb…s free energy, ΔG, cohesive energy, CE, Wada…s constant, W, Rao…s constant, Rm and relative association, RA. The variation of these parameters versus the mixture composition was explained on the basis of the intermolecular interactions between the components of the mixture.
Keywords
References
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Bouanz M, Quim. Anal., 15, 530 (1996)
Bouanz M, Beysens D, J. Chem. Phys. Lett., 231, 105 (1994)
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Beebi S, Nayeem SM, Sri PBS, Satyanarayana GR, Begum Z, Rambabu C, J. Therm. Anal. Calorim., 129(2), 1121 (2017)
Resa JM, Goenaga JM, Concha RG, Iglesias M, Korean J. Chem. Eng., 23(6), 977 (2006)
Nithya R, Mullainathan S, Rajasekaran R, E J. Chem., 6(1), 138 (2009)
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Rajagopal K, Chenthilnath S, Thermochim. Acta, 498(1-2), 45 (2010)
Gowrisankar M, Venkateswarlu P, Sivakumar K, Sivarambabu S, Arab. J. Chem., 10, S2625 (2017)
Nayeem SM, Kondaiah M, Sreekanth K, Rao DK, J. Mol. Liq., 207, 286 (2015)
Godhani DR, Dobariya PB, Sanghani AM, Jogel AA, Mehta JP, J. Chem. Thermodyn., 70, 73 (2014)
Pal A, Saini M, Kumar B, Fluid Phase Equilib., 411, 66 (2016)
Tangeda SJ, Nallani S, J. Chem. Eng. Data, 50(1), 899 (2005)
Gayathri A, Venugopal T, Venkatramanan K, Phys. Procedia, 70, 241 (2015)
Umapathi R, Ramjugernath D, Venkatesu P, J. Mol. Liq., 242, 375 (2017)
Dunker H, Woermann D, Bhattacharjee JK, Ber. Bunsenges. Phys. Chem., 87, 591 (1983)
Belkoura L, Calenbuhr V, Muller-Kirs.chbaum T, Woermann D, Ber. Bunsenges. Phys. Chem., 94, 1471 (1990)
Kaatze U, Schreiber U, J. Phys. Chem., 93, 4955 (1989)
Bulavin LA, Belous OI, Svechnikova OS, Ukr. J. Phys., 61(5), 375 (2016)
Lemmon EW, McLinden MO, Friend DG
Wagner W, Pruss A, J. Phys. Chem. Ref., 31, 387 (2002)
Nikam PS, Shirsat LN, Hassan M, J. Chem. Eng., 43, 732 (1998)
IAPWS, Erlangen, Germany, 15 (1997).
Beyer RT, Latcher SV, Physical Ultrasonics. Academic Press, N Y (1969).
Rajulu AV, Sab PM, J. Bull. Mater. Sci., 18, 247 (1995)
Pund DA, Tayade DT, Naik AB, Proc. Technol., 24, 677 (2016)
Pal A, Kumar H, Arbad BR, Tekale AB, India J. Pure Appl. Phys., 41, 113 (2003)
Hassun SK, Acoustics Letters, 11(10), 195 (1988)
Heitz MP, J. Chem. Thermodyn., 108, 143 (2017)
Suryanarayana CV, Kuppusamy J, J. Acoust. Soc. Ind., 4, 75 (1976)
Rajulu AV, Sreenivasulu G, Raghuraman KS, Ind. J. Chem. Technol., 1, 302 (1994)
Kuppusami J, Suryanarayana CV, Indian J. Acoust. Soc., 5, 102 (1977)
Alisha SB, Rao KC, J. Pure Appl. Ultrason., 23, 26 (2001)
Nomoto O, J. Chem. Phys., 21, 950 (1953)
Ekka PAK, Reddy GV, Singh RP, Acustica, 46(3), 341 (1980)
Jayakumar S, Kannappan V, JASI, XXV (1997).
Davies M, Sherwood JN, Caglioti G, Corchia M, Rizzi G, et al. General Discussion, Discussions Faraday Soc., 43, 128 (1967).
Beysens D, Bourgou A, Calmettes P, Phys. Rev. A, 26, 3589 (1982)
Beysens D, Bourgou A, Paladin G, Phys. Rev. A, 30, 2686 (1984)
Toumi A, Bouanz M, Gharbi A, Chem. Phys. Lett., 362(5-6), 567 (2002)
Sengers JV, Shanks JG, J. Stat. Phys., 137, 857 (2009)
Toumi A, Hafaiedh N, Bouanz M, Fluid Phase Equilib., 278(1-2), 68 (2009)
Oswal SL, Oswal P, Pathak RP, J. Sol. Chem., 27, 507 (1998)
Fort RJ, Moore WR, Trans. Faraday Soc., 61, 2102 (1965)
Varma RP, Kumar S, Indian J. Pure. Appl. Phys., 38, 96 (2000)
Nithiyanantham S, Palaniappan L, Acta. Cienc. Indica., 37, 392 (2006)
Naik RR, Bawankar SV, Russ. J. Phys. Chem. A, 89, 2388 (2015)
