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Received November 28, 2017
Accepted April 10, 2018
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Developing homogeneous ion exchange membranes derived from sulfonated polyethersulfone/N-phthaloyl-chitosan for improved hydrophilic and controllable porosity
College of Chemical and Environmental Engineering, Shandong University of Science and Technology, Qingdao 266590, P. R. China 1The Institute of Seawater Desalination and Multipurpose Utilization, SOA, Tianjin 300192, P. R. China 2Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266100, P. R. China
Korean Journal of Chemical Engineering, August 2018, 35(8), 1716-1725(10), 10.1007/s11814-018-0064-2
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Abstract
Ion exchange membranes (IEMs) composed of sulfonated poly (ether sulfone) (SPES) and N-phthaloyl chitosan (NPHCs) were synthesized. NPHCs was employed in membrane fabrication to improve the porosity and hydrophilicity of membranes. The effect of blend ratio of sulfonation (DS) and NPHCs content on physico-chemical characteristics of home-made membranes was investigated. The morphology of prepared membranes was investigated by Fourier transform infrared spectroscopy (FTIR), X-ray diffractometer (XRD) and scanning electron microscopy (SEM). SEM images revealed the formation of a more porous membrane structure and smoother surface. The electrochemical and physical properties of CEMs were characterized comprising water content, contact angle, ion exchange capacity (IEC) and thermal stability. Membrane water content, surface hydrophilicity and IEC were enhanced with increase of DS and NPHCs blend ratios in casting solution. Furthermore, the diffusion coefficient was also improved slightly with increase of DS and NPHCs blend ratios in prepared membranes. Membrane potential, permselectivity, transport number and areal membrane resistance all showed decreasing trends by the increase in NPHCs blend ratio in casting solution. These results indicated that the prepared membrane has good prospective and great potential for desalination in electrodialysis applications.
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Hosseini SM, Gholami A, Madaeni SS, Moghadassi AR, Hamidi AR, Desalination, 306, 51 (2012)
Guan R, Zou H, Lu D, Gong C, Liu Y, Eur. Polym. J., 41, 1554 (2005)
Sata T, Funakoshi T, Akai K, Macromolecules, 29(11), 4029 (1996)
Sata T, Ishii Y, Kawamura K, Matsusaki K, J. Electrochem. Soc., 146(2), 585 (1999)
Vogel C, Meier-Haack J, Desalination, 342, 156 (2014)
Choi KH, Jeoung TY, Korean J. Chem. Eng., 19(1), 107 (2002)
Baker RW, Membrane Technology and Applications, 2nd Ed. England, Wiley (2004).
Hosseini S, Hamidi A, Moghadassi A, Parvizian F, Madaeni SS, Korean J. Chem. Eng., 32(9), 1827 (2015)
Schauer J, Brozova L, J. Membr. Sci., 250(1-2), 151 (2005)
Ghasemi M, Daud WRW, Alam J, Ilbeygi H, Sedighi M, Ismail AF, Yazdi MH, Aljlil SA, Energy, 96, 303 (2016)
Chakrabarty T, Rajesh AM, Jasti A, Thakur AK, Singh AK, Prakash S, Kulshrestha V, Shahi VK, Desalination, 282, 2 (2011)
Zarrinkhameh M, Zendehnam A, Hosseini SM, Korean J. Chem. Eng., 31(7), 1187 (2014)
Reig M, Farrokhzad H, Van der Bruggen B, Gibert O, Cortina JL, Desalination, 375, 1 (2015)
Farrokhzad H, Darvishmanesh S, Genduso G, Van Gerven T, Van der Bruggen B, Electrochim. Acta, 158, 64 (2015)
Mir FQ, Shukla A, Desalination, 372, 1 (2015)
Choi EY, Moon SH, Korean J. Chem. Eng., 25(5), 1151 (2008)
Chakrabarty T, Rajesh AM, Jasti A, Thakur AK, Singh AK, Prakash S, Kulshrestha V, Shahi VK, Desalination, 282, 2 (2011)
Li Y, Zhang X, He G, Zhang F, Int. J. Hydrog. Energy, 42, 2360 (2016)
Cassady HJ, Cimino EC, Kumar M, Hickner MA, J. Membr. Sci., 508, 146 (2016)
Lei LF, Zhu XY, Xu JF, Qian HD, Zou ZQ, Yang H, J. Power Sources, 350, 41 (2017)
Saleem A, Frormann L, Iqbal A, Polym. Compos., 28, 785 (2007)
Mabrouk W, Ogier L, Vidal S, Sollogoub C, Matoussi F, Fauvarque JF, J. Membr. Sci., 452, 263 (2014)
Amado FDR, Gondran E, Ferreira JZ, Rodrigues MAS, Ferreira CA, J. Membr. Sci., 234(1-2), 139 (2004)
Klaysom C, Marschall R, Moon S, Ladewig BP, Lu GQM, Wang L, J. Mater. Chem., 21, 7401 (2011)
Ma J, Sahai Y, Carbohydr. Polym., 92, 955 (2013)
Mansourpanah Y, Kakanejadifard A, Dehrizi FG, Tabatabaei M, Afarani HS, Korean J. Chem. Eng., 32(1), 149 (2015)
Srinophakun P, Thanapimmetha A, Plangsri S, Vetchayakunchai S, Saisriyoot M, J. Clean Prod., 142, 1274 (2017)
Mukoma P, Jooste BR, Vosloo HCM, J. Power Sources, 136(1), 16 (2004)
Kumar R, Isloor AM, Ismail AF, Desalination, 350, 102 (2014)
Shenvi SS, Rashid SA, Ismail AF, Kassim MA, Isloor AM, Desalination, 315, 135 (2013)
Tsai HS, Wang YZ, Polym. Bull., 60(1), 103 (2008)
Yuan NY, Tsai RY, Ho MH, Wang DM, Lai JY, Hsieh HJ, Desalination, 234(1-3), 166 (2008)
Tangpasuthadol V, Pongchaisirikul N, Hoven VP, Carbohydr. Res., 338, 937 (2003)
Muthumeenal A, Neelakandan S, Kanagaraj P, Nagendran A, Renew. Energy, 86, 922 (2016)
Padaki M, Isloor AM, Wanichapichart P, Desalination, 279(1-3), 409 (2011)
Klaysom C, Moon SH, Ladewig BP, Lu GQM, Wang LZ, J. Membr. Sci., 371(1-2), 37 (2011)
Klaysom C, Ladewig BP, Lu GQM, Wang LZ, J. Membr. Sci., 368(1-2), 48 (2011)
Yoksan R, Chirachanchai S, Bioorg. Med. Chem., 16, 2687 (2008)
Zhou ML, Chen X, Pan JF, Yang SS, Han B, Xue LX, Shen JN, Gao CJ, Van der Bruggen B, Desalination, 415, 29 (2017)
Yeager HL, Steck A, J. Electrochem. Soc., 128, 1880 (1981)
Wang M, Jia YX, Yao TT, Wang KK, J. Membr. Sci., 442, 39 (2013)
Hosseini SM, Madaeni SS, Khodabakhshi AR, Sep. Sci. Technol., 46(5), 794 (2011)
Hosseini SM, Madaeni SS, Heidari AR, Amirimehr A, Desalination, 284, 191 (2012)
Gohil GS, Binsu VV, Shahi VK, J. Membr. Sci., 280(1-2), 210 (2006)
Zhao W, Mou Q, Zhang X, Shi J, Sun S, Zhao C, Eur. Polym. J., 49, 738 (2013)
Sahebi S, Phuntsho S, Woo YC, Park MJ, Tijing LD, Hong S, Shon HK, Desalination, 389, 129 (2016)
Zhu A, Chen T, Yuan L, Wu H, Lu P, Carbohydr. Polym., 66, 274 (2006)
Samuels RJ, J. Polym. Sci. B: Polym. Phys., 19, 1081 (1981)
Kurita K, Ikeda H, Yoshida Y, Shimojoh M, Harata M, Biomacromolecules, 3(1), 1 (2002)
Behboudi A, Jafarzadeh Y, Yegani R, J. Membr. Sci., 534, 18 (2017)
Alsalhy QF, Desalination, 294, 44 (2012)
Wang F, Hickner M, Kim YS, Zawodzinski TA, McGrath JE, J. Membr. Sci., 197(1-2), 231 (2002)
Orler EB, Yontz DJ, Moore RB, Macromolecules, 26, 5157 (1993)
Kanagaraj P, Nagendran A, Rana D, Matsuura T, Neelakandana S, Karthikkumar T, Muthumeenal A, Appl. Surf. Sci., 329, 165 (2015)
Heidary F, Khodabakhshi AR, Kharat AN, Korean J. Chem. Eng., 33(4), 1380 (2016)
Tong B, Hossain MM, Yang Z, Cheng C, Wang Y, Jiang C, Xu T, J. Taiwan Inst. Chem. E., 67, 435 (2016)
Hosseini SM, Gholami A, Madaeni SS, Moghadassi AR, Hamidi AR, Desalination, 306, 51 (2012)
Guan R, Zou H, Lu D, Gong C, Liu Y, Eur. Polym. J., 41, 1554 (2005)
Sata T, Funakoshi T, Akai K, Macromolecules, 29(11), 4029 (1996)
Sata T, Ishii Y, Kawamura K, Matsusaki K, J. Electrochem. Soc., 146(2), 585 (1999)
