Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received March 8, 2018
Accepted May 27, 2018
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
Preparation of PEDOT-ordered mesoporous carbon hybrid material using vapor phase polymerization
Division of Advanced Materials Engineering, Kongju National University, 1223-24 Cheoandaero, Cheonan, Chungnam 31080, Korea 1Department of Chemical Engineering, Kongju National University, 1223-24 Cheoandaero, Cheonan, Chungnam 31080, Korea
Korean Journal of Chemical Engineering, September 2018, 35(9), 1941-1947(7), 10.1007/s11814-018-0088-7
Download PDF
Abstract
A hybrid composite was prepared by the formation of poly (3,4-ethylenedioxythiophene) (PEDOT) layer on two types of ordered mesoporous carbon (OMC) by vapor phase polymerization. The morphology, chemical composition, pore structure, and electrical properties of the normal type ordered mesoporous carbon (NTOMC) and rod type ordered mesoporous carbon (RTOMC) composites were compared and analyzed. The surface morphology of the PEDOT-OMC composite did not change, due to the uniform coating of PEDOT layer on the OMC. The content of PEDOT in the composite and the thickness of the coating layer both increased with the amount of the oxidizing agent, Iron (III) p-toluenesulfonate (FTS) used in VPP. Pore size, porosity, and surface area of PEDOT-OMC composite decreased with coating of PEDOT layer on the outer surface of the OMC, and the mesopore inner wall. Electrical resistance decreased with an increase in the thickness of the PEDOT layer coated on the OMC. The PEDOT-RTOMC composite had lower electrical resistivity than the PEDOT-NTOMC composite, suggesting that rod-type morphology is advantageous for electron transport. The capacitance was also higher for the PEDOT-RTOMC than for the PEDOTNTOMC, which is thought to be proportional to the surface area of the composite determined by the external and internal structure of the material.
Keywords
References
Wakabayashi K, Pierre C, Dikin DA, Ruoff RS, Ramanathan T, Brinson LC, Torkelson JM, Macromolecules, 41(6), 1905 (2008)
Balberg I, Carbon, 40(2), 139 (2002)
Kuilla T, Bhadra S, Yao D, Kim NH, Bose S, Lee JH, Prog. Polym. Sci, 35(11), 1350 (2010)
Hussain SN, Roberts EPL, Asghar HMA, Campen AK, Brown NW, Electrochim. Acta, 92, 20 (2013)
Gong JL, Wang B, Zeng GM, Yang CP, Niu CG, Niu QY, Zhou WJ, Liang Y, J. Hazard. Mater., 164(2-3), 1517 (2009)
Liang Y, Dai HB, Ma LP, Wang P, Cheng HM, Int. J. Hydrog. Energy, 35(7), 3023 (2010)
Li YF, Guo MQ, Yin SF, Chen L, Zhou YB, Qiu RH, Au CT, Carbon, 55, 269 (2013)
Bessel CA, Laubernds K, Rodriguez NM, Baker RTK, J. Phys. Chem. B, 105(6), 1115 (2001)
Nie M, Chalasani D, Abraham DP, Chen Y, Bose A, Luch BL, J. Phys. Chem. C, 117(3), 1257 (2013)
Ji J, Zhang LL, Ji H, Li Y, Zhao X, Bai X, Fan X, Zhang F, Ruoff RS, ACS Nano, 7(7), 6237 (2013)
Kresge CT, Leonowicz ME, Roth WJ, Vartuli JC, Beck JS, Nature, 359, 710 (1992)
Zhao DY, Feng JL, Huo QS, Melosh N, Fredrickson GH, Chmelka BF, Stucky GD, Science, 279(5350), 548 (1998)
Tanev PT, Pinnavaia TJ, Science, 267(5199), 865 (1995)
Liu Y, Zhang W, Pinnavaia TJ, Angew. Chem.-Int. Edit., 40(7), 1255 (2001)
Ryoo R, Kim JM, Ko CH, Shin CH, J. Phys. Chem., 100(45), 17718 (1996)
Joo SH, Choi SJ, Oh I, Kwak J, Liu Z, Terasaki O, Ryoo R, Nature, 412, 169 (2001)
Lee J, Sohn K, Hyeon T, J. Am. Chem. Soc., 123(21), 5146 (2001)
Lee J, Kim J, Hyeon T, Adv. Mater., 18(16), 2073 (2006)
Lee HI, Kim JH, Stucky GD, Shi Y, Pak C, Kim JM, J. Mater. Chem., 20, 8483 (2010)
Lee HI, Kim JH, You DJ, Lee JE, Kim JM, Ahn WS, Pak C, Joo SH, Chang H, Seung D, Adv. Mater., 20(4), 757 (2008)
Chae C, Kim JH, Kim JM, Sun YK, Lee JK, J. Mater. Chem., 22, 17870 (2012)
Yu CZ, Fan J, Tian BZ, Zhao DY, Stucky GD, Adv. Mater., 14(23), 1742 (2002)
Xiao Y, Dong H, Lei B, Qiu H, Liu Y, Zheng M, Mater. Lett., 138, 37 (2015)
Ching CK, Fincher CR, Park YW, Heeger AJ, Shirakawa H, Louis EJ, Gau SC, MacDiarmid AG, Phys. Rev. Lett., 39, 1098 (1977)
Wang J, Yu X, Li Y, Liu Q, J. Phys. Chem. C, 111(49), 18073 (2007)
Tintula KK, Sahu AK, Shahid A, Pitchumani S, Sridhar P, Shukla AK, J. Electrochem. Soc., 157(11), B1679 (2010)
Ma GQ, Wen ZY, Jin J, Lu Y, Rui K, Wu XW, Wu MF, Zhang JC, J. Power Sources, 254, 353 (2014)
Wei Y, Yeh JM, Jin D, Jia X, Wang J, Jang GW, Chen C, Gumbs RW, Chem. Mater., 7, 969 (1995)
Sommers AG, World Patent, WO 99/58464 (1998).
Han YH, Travas-Sejdic J, Wright B, Yim JH, Macromol. Chem. Phys., 212, 521 (2011)
Yim JH, Compos. Sci. Technol., 86, 45 (2013)
Khadka R, Yim JH, Macromol. Res., 23(6), 559 (2015)
Ko YS, Yim JH, Polymer, 93, 167 (2016)
Kim SW, Lee SW, Kim J, Yim JH, Cho KY, Polymer, 102, 127 (2016)
Choi JS, Park JS, Kim B, Lee BT, Yim JH, Polymer, 120, 95 (2017)
Lock JP, Im SG, Gleason KK, Macromolecules, 39(16), 5326 (2006)
Im SG, Gleason KK, Macromolecules, 40(18), 6552 (2007)
Asatekin A, Barr MC, Baxamura SH, Lau KKS, Tenhaeff W, Xu J, Gleason KK, Mater. Today, 13(5), 26 (2010)
Ahn J, Yoon S, Jung SG, Yim JH, Cho KY, J. Mater. Chem. A, 5, 21214 (2017)
Balberg I, Carbon, 40(2), 139 (2002)
Kuilla T, Bhadra S, Yao D, Kim NH, Bose S, Lee JH, Prog. Polym. Sci, 35(11), 1350 (2010)
Hussain SN, Roberts EPL, Asghar HMA, Campen AK, Brown NW, Electrochim. Acta, 92, 20 (2013)
Gong JL, Wang B, Zeng GM, Yang CP, Niu CG, Niu QY, Zhou WJ, Liang Y, J. Hazard. Mater., 164(2-3), 1517 (2009)
Liang Y, Dai HB, Ma LP, Wang P, Cheng HM, Int. J. Hydrog. Energy, 35(7), 3023 (2010)
Li YF, Guo MQ, Yin SF, Chen L, Zhou YB, Qiu RH, Au CT, Carbon, 55, 269 (2013)
Bessel CA, Laubernds K, Rodriguez NM, Baker RTK, J. Phys. Chem. B, 105(6), 1115 (2001)
Nie M, Chalasani D, Abraham DP, Chen Y, Bose A, Luch BL, J. Phys. Chem. C, 117(3), 1257 (2013)
Ji J, Zhang LL, Ji H, Li Y, Zhao X, Bai X, Fan X, Zhang F, Ruoff RS, ACS Nano, 7(7), 6237 (2013)
Kresge CT, Leonowicz ME, Roth WJ, Vartuli JC, Beck JS, Nature, 359, 710 (1992)
Zhao DY, Feng JL, Huo QS, Melosh N, Fredrickson GH, Chmelka BF, Stucky GD, Science, 279(5350), 548 (1998)
Tanev PT, Pinnavaia TJ, Science, 267(5199), 865 (1995)
Liu Y, Zhang W, Pinnavaia TJ, Angew. Chem.-Int. Edit., 40(7), 1255 (2001)
Ryoo R, Kim JM, Ko CH, Shin CH, J. Phys. Chem., 100(45), 17718 (1996)
Joo SH, Choi SJ, Oh I, Kwak J, Liu Z, Terasaki O, Ryoo R, Nature, 412, 169 (2001)
Lee J, Sohn K, Hyeon T, J. Am. Chem. Soc., 123(21), 5146 (2001)
Lee J, Kim J, Hyeon T, Adv. Mater., 18(16), 2073 (2006)
Lee HI, Kim JH, Stucky GD, Shi Y, Pak C, Kim JM, J. Mater. Chem., 20, 8483 (2010)
Lee HI, Kim JH, You DJ, Lee JE, Kim JM, Ahn WS, Pak C, Joo SH, Chang H, Seung D, Adv. Mater., 20(4), 757 (2008)
Chae C, Kim JH, Kim JM, Sun YK, Lee JK, J. Mater. Chem., 22, 17870 (2012)
Yu CZ, Fan J, Tian BZ, Zhao DY, Stucky GD, Adv. Mater., 14(23), 1742 (2002)
Xiao Y, Dong H, Lei B, Qiu H, Liu Y, Zheng M, Mater. Lett., 138, 37 (2015)
Ching CK, Fincher CR, Park YW, Heeger AJ, Shirakawa H, Louis EJ, Gau SC, MacDiarmid AG, Phys. Rev. Lett., 39, 1098 (1977)
Wang J, Yu X, Li Y, Liu Q, J. Phys. Chem. C, 111(49), 18073 (2007)
Tintula KK, Sahu AK, Shahid A, Pitchumani S, Sridhar P, Shukla AK, J. Electrochem. Soc., 157(11), B1679 (2010)
Ma GQ, Wen ZY, Jin J, Lu Y, Rui K, Wu XW, Wu MF, Zhang JC, J. Power Sources, 254, 353 (2014)
Wei Y, Yeh JM, Jin D, Jia X, Wang J, Jang GW, Chen C, Gumbs RW, Chem. Mater., 7, 969 (1995)
Sommers AG, World Patent, WO 99/58464 (1998).
Han YH, Travas-Sejdic J, Wright B, Yim JH, Macromol. Chem. Phys., 212, 521 (2011)
Yim JH, Compos. Sci. Technol., 86, 45 (2013)
Khadka R, Yim JH, Macromol. Res., 23(6), 559 (2015)
Ko YS, Yim JH, Polymer, 93, 167 (2016)
Kim SW, Lee SW, Kim J, Yim JH, Cho KY, Polymer, 102, 127 (2016)
Choi JS, Park JS, Kim B, Lee BT, Yim JH, Polymer, 120, 95 (2017)
Lock JP, Im SG, Gleason KK, Macromolecules, 39(16), 5326 (2006)
Im SG, Gleason KK, Macromolecules, 40(18), 6552 (2007)
Asatekin A, Barr MC, Baxamura SH, Lau KKS, Tenhaeff W, Xu J, Gleason KK, Mater. Today, 13(5), 26 (2010)
Ahn J, Yoon S, Jung SG, Yim JH, Cho KY, J. Mater. Chem. A, 5, 21214 (2017)
