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Received December 19, 2018
Accepted August 8, 2019
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Removal of crystal violet dye by an efficient and low cost adsorbent: Modeling, kinetic, equilibrium and thermodynamic studies
Department of Physical Chemistry, Faculty of Chemistry, University of Kashan, Kashan, Iran 1Department of Applied Chemistry, Faculty of Chemistry, University of Kashan, Kashan, Iran
Korean Journal of Chemical Engineering, October 2019, 36(10), 1575-1586(12), 10.1007/s11814-019-0356-1
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Abstract
Natural zeolite as a low cost clay was tested for removal of crystal violet known as a noxious dye. Five characterization techniques were used for this study. Optimizing and modeling of adsorption were performed at minimum time by an applicable technique named as response surface methodology (RSM). Three effective variables (pH, temperature (T) and adsorbate-to-adsorbent ratio (a/A)) were monitored to obtain the dye removal efficiencies. The maximum removal of dye was obtained at pH=10, T=25 °C and a/A=0.1 g/g. For natural zeolite, the Fractal-Langmuir model was selected as an appropriate model for kinetic studies and the Freundlich isotherm was the best isotherm for equilibrium studies. Thermodynamic investigations showed that the adsorption of dye on natural zeolite is endothermic process and a spontaneous reaction. The maximum dye adsorption capacity of natural zeolite and Merck activated carbon on the surface of each adsorbent was obtained at 177.75 and 84.11mg/g, respectively. In comparison with the maximum adsorption capacity of activated carbon obtained from Merck Company, we can conclude that natural zeolite possesses a higher adsorption capacity. These results reveal that, natural zeolite is an excellent and affordable adsorbent for removal of crystal violet from wastewater as compared to activated carbon.
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Guz L, Curutchet G, Sanchez RMT, Candal R, J. Environ. Chem. Eng., 2, 2344 (2014)
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Zhu R, Chen Q, Liu H, Ge F, Zhu L, Zhu J, He H, Appl. Clay Sci., 88, 33 (2014)
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Banerjee K, Cheremisinoff PN, Cheng SL, Water Res., 31, 249 (1997)
Hor KY, Chee JMC, Chong MN, Jin B, Saint C, Poh PE, Aryal R, J. Clean Prod., 118, 197 (2016)
Sismanoglu T, Kismir Y, Karakus S, J. Hazard. Mater., 184(1-3), 164 (2010)
Humelnicu I, Baiceanu A, Ignat ME, Dulman V, Process Saf. Environ. Protect., 105, 274 (2017)
Qiu MQ, Qian C, Xu J, Wu JM, Wang GX, Desalination, 243(1-3), 286 (2009)
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Pereira PM, Ferreira BF, Oliveira NP, Nassar EJ, Ciuffi KJ, Vicente MA, Trujillano R, Rives V, Gil A, Korili S, De Faria EH, Appl. Sci., 8, 608 (2018)
Awala H, Leite E, Saint-Marcel L, Clet G, Retoux R, Naydenova I, Mintova S, New J. Chem., 40, 4277 (2016)
Campbell L, Chimedtsogzol A, Dyer A, Mineralogical Magazine, 70, 361 (2006)
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Pelaez-Cid AA, Herrera-Gonzalez AM, Salazar-Villanueva M, Bautista-Hernandez A, J. Environ. Manage., 181, 269 (2016)
Azizian S, Haerifar M, Bashiri H, Chem. Eng. J., 146(1), 36 (2009)
Djilani C, Zaghdoudi R, Djazi F, Bouchekima B, Lallam A, Modarressi A, Rogalski M, J. Taiwan Inst. Chem. Engineers, 53, 112 (2015)
Belaid KD, Kacha S, Kameche M, Derriche Z, J. Environ. Chem. Eng., 1, 496 (2013)
Giannakoudakis DA, Kyzas GZ, Avranas A, Lazaridis NK, J. Mol. Liq., 213, 381 (2016)
Yavuz O, Aydin AH, Polish J. Environ. Studies, 15, 155 (2006)
Mousavi SM, Salari D, Niaei A, Panahi PN, Shafiei S, Environ. Technol., 35, 581 (2014)
Mousavi SM, Panahi PN, J. Taiwan Inst. Chem. Eng., 69, 68 (2016)
Karimifard S, Moghaddam MRA, Process Saf. Environ. Protect., 99, 20 (2016)
Satapathy MK, Das P, J. Environ. Chem. Eng., 2, 708 (2014)
Asfaram A, Ghaedi M, Goudarzi A, Rajabi M, Dalton Trans., 44, 14707 (2015)
Hernandez-Montoya V, Perez-Cruz MA, Mendoza-Castillo DI, Moreno-Virgen MR, Bonilla-Petriciolet A, J. Environ. Manage., 116, 213 (2013)
Flores-Lopez NA, Castro-Rosas J, Ramirez-Bon R, Mendoza-Cordova A, Larios-Rodriguez E, Flores-Acosta M, J. Mol. Struct., 1028, 110 (2012)
Dila EA, Ghaedi M, Asfaram A, Ultrason. Sonochem., 34, 792 (2017)
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Langmuir I, J. Am. Chem. Soc., 38, 2221 (1916)
Freundlich H, Zeitschrift fur Physikalische Chemie, 57U, 385 (1907)
Temkin MJ, Pyzhev V, Acta Physicochimica U.R.S.S., 12, 327 (1940)
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Alberti G, Amendola V, Pesavento M, Biesuz R, Coord. Chem. Rev., 256, 28 (2012)
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Singh AMKP, Sinha S, Ojha P, J. Hazard. Mater., 150, 626 (2008)
Bertolini TCR, Izidoro JC, Magdalena CP, Fungaro DA, Orbital: Electron. J. Chem., 5, 179 (2013)
Dila EA, Ghaedi M, Ghaedi A, Asfaram A, Jamshidi M, Purkai MK, J. Taiwan Inst. Chem. Eng., 59, 210 (2015)
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Senthilkumaar S, Kalaamani P, Subburaam CV, J. Hazard. Mater., 136(3), 800 (2006)
Nandi BK, Goswami A, Das AK, Mondal B, Purkait MK, Sep. Sci. Technol., 43(6), 1382 (2008)
Yang H, Zhou D, Chang Z, Zhang L, Desalin. Water Treat., 52, 6113 (2014)
Anirudhan TS, Suchithra PS, Radhakrishnan PG, Appl. Clay Sci., 43, 336 (2009)
Chen ZX, Wang T, Jin XY, Chen ZL, Megharaj M, Naidu R, J. Colloid Interface Sci., 398, 59 (2013)
Hamidzadeh S, Torabbeigi M, Shahtaheri SJ, J. Environ. Health Sci. Eng., 13, 8 (2015)
Rai P, Gautam RK, Banerjee S, Rawat V, Chattopadhyaya MC, J. Environ. Chem. Eng., 3, 2281 (2015)
Simonin JP, Chem. Eng. J., 300, 254 (2016)
Lagergren S, Kungliga Svenska Vetenskapsakademiens. Handlingar, 24, 1 (1898).
Kang YL, Toh SKS, Monash P, Ibrahim S, Saravanan P, Asia-Pacific J. Chem. Eng., 8, 811 (2013)
Coruh S, Geyikci F, Ergun ON, Environ. Technol., 32, 1183 (2011)
Yang XY, Al-Duri B, J. Colloid Interface Sci., 287(1), 25 (2005)
Azizian S, Bashiri H, Langmuir, 24(20), 11669 (2008)
Azizian S, J. Colloid Interface Sci., 276(1), 47 (2004)
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Bashiri H, Chem. Phys. Lett., 575, 101 (2013)
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Tran HN, You SJ, Chao HP, J. Environ. Chem. Eng., 4, 2671 (2016)
Tagami L, Santos O, Sousa-Aguiar EF, Arroyo PA, Barros M, Acta Scientiarum, 23, 1351 (2001)
Ishaq M, Javed F, Amad I, Ullah H, J. Chem. Chem. Eng., 35, 97 (2016)
